陕西洛川黄土沉积物中稀土元素及其它微量元素的化学淋滤研究   总被引：35，自引：0，他引：35  

陈骏  鹿化煜 《地质学报》1996,70(1):61-72

本文采用化学淋滤的方法对洛川黄土沉积物的酸溶和酸不溶相中稀土元素以及其它微量元素的分布分配特征进行了系统的分析。  相似文献   

Behaviours of REE and Other Trace Elements During Pedological Weathering-Evidence from Chemical Leaching of Loess and Palaeosol from the Luochuan Section in Central China     

Chen Jun  Wan Hongtao  Department of Earth Sciences  Nanjing University  Nanjing  Jiangsuand Lu HuayuKey Lab. of Loess  Quaternary Geology  Chinese Academy of Sciences  Xi an  Shaanxi Liu Xinzhu 《《地质学报》英文版》1996,70(3):290-302

The chemical leaching method is used for a systematic analysis of distribution characteristics of acid-soluble and acid-insoluble REE and other trace elements from the Luochuan loess deposits. The study shows that the acid-insoluble phase in loess and palaeosol is a stable component of old aeolian dusts and is characteristic of the provenance; the acid-soluble phase is the unstable component in the weathering pedogenic process and reflects rock-forming features after accumulation of aeolian dusts. The acid-insoluble REE and acid-soluble Sr and Pb can be used as geochemical indicators respectively to trace the provenance characteristics and the weathering pedogenic process.  相似文献   

Geochemistry of the Rare Earth Elements in Natural Terrestrial Waters：A Review of What Is Currently Knows   总被引：3，自引：0，他引：3  

KEVIN  H  JOHANNESSON ZHOUXIAOPING 《中国地球化学学报》1997,16(1):20-42

The range of observed chemical compositions of natural terrestrial waters varies greatly especially when compared to the essentially constant global composition of the oceans.The concentrations of the REEs in natural terrestrial waters also exhibit more variation than what was reported in seawater,In terrestrial waters ,pH values span the range from acid up to alkaline,In addition,terrestrial waters can range from very dilute waters through to highly concentrated brines.The REE concentrations and their behavior in natural terrestrial waters reflect these compositional ranges,Chemical weathering of rocks represents the source of the REEs to natural terrestrial waters and ,consequently,the REE signature of rocks can impart their REE signature to associated waters,In addition,Because of the typical low solubilities of the REEs both surface and solution complexation can be important in fractionating REEs in aqueous solution.Both of these processes are important in all natural terrestrial waters,however,their relative importance varies as a function of the overall solution composition,In alkaline waters,for example,Solution complexation of the REEs with carbonate ions appears to control their aqueous distributions whereas in acid waters,the REE signature of the labile fraction of the REEs is readily leached from the rocks.In circumneutral pH waters,both processes appear to be important and their relative significance has not yet been determined.  相似文献   

湘中南二叠系孤峰组硅质岩的成因属性及其地球动力学指示意义   总被引：5，自引：0，他引：5  

付伟  周永章  杨志军  何俊国  张澄博  杨海生 《矿物岩石地球化学通报》2004,23(4):292-300

华南二叠系底部的硅质岩及同一层位对应于华南重要的地幔强活动期和成矿期，有非常重要的动力学指示意义。研究表明，孤峰组剖面的岩性可划分为三段：泥页岩段、厚层状硅质岩段和薄层状硅质岩段。沿剖面自下而上，Al2O3、K2O和TiO2含量逐渐降低，MnO、TFe等组分逐渐升高；稀土元素显示出一定的铈负异常，∑REE偏低，且向上∑REE逐渐减少而HREE／LREE逐渐增高；一些热水沉积诊断性微量元素如As、Sb、Hg等也显示出一定程度的异常。这些特征均表明硅质岩的成岩过程中包含有正常沉积和热水沉积的共同作用，且自下而上热水沉积作用逐渐增强的趋势。这种成岩作用的演化特征，代表了下扬子地台拉张裂陷盆地对晚古生代伸展背景的沉积响应，对于探讨裂谷盆地阶段性发育的动力学特征有一定的指示意义。  相似文献   

REE and (э)Nd of clay fractions in sediments from the eastern Pacific Ocean: Evidence for clay sources     

LIU Jihua  SHI Xuefa  Chen Lirong  HUANG Yongyang  Wang Yinxi  Cui Yingchun  BU Wenrui 《中国科学D辑(英文版)》2005,48(5)

Clay fractions in the non-calcareous surface sediments from the eastern Pacific were analyzed for clay minerals, REE and 143Nd/144Nd. Montmorillonite/illite ratio (M/I ratio), total REE contents ((REE), LREE/HREE ratio and cerium anomaly (бCe) may effectively indicate the genesis of clay minerals. Clay fractions with M/I ratio >1, бCe (0.85, (REE (400 μg/g, LREE/HREE ratio (4, and REE patterns similar to those of pelagic sediments are terrigenous and autogenetic mixed clay fractions and contain more autogenetic montmorillonite. Clay fractions with M/I ratio <1, бCe=0.86 to 1.5, ΣREE=200 to 350 μg/g, LREE/HREE ratio (6 and REE distribution patterns similar to that of China loess are identified as terrigenous clay fraction. The 143Nd/144Nd ratios or (э)Nd values of clay fractions inherit the features of terrigenous sources of clay minerals. Clay fractions are divided into 4 types according to (э)Nd values. Terrigenous clay minerals of type I with the (э)Nd values of -8 to -6 originate mainly from North American fluvial deposits. Those of type II with the (э)Nd values of -9 to -7 are mainly from the East Asia and North American fluvial deposits. Those of type III with (э)Nd values of -6 to -3 could come from the central and eastern Pacific volcanic islands. Those of type IV with (э)Nd values of -13 to -12 may be from East Asia eolian. The terrigenous and autogenetic mixed clay fractions show patchy distributions, indicating that there are volcanic or hot-spot activities in the eastern Pacific plate, while the terrigenous clay fractions cover a large part of the study area, proving that the terrigenous clay minerals are dominant in the eastern Pacific.  相似文献   

鄂尔多斯盆地北部砂岩型铀矿铀矿物地质地球化学特征及其成因意义   总被引：3，自引：0，他引：3  

吴柏林  张婉莹  宋子升  寸小妮  孙莉  罗晶晶  李艳青  程相虎  孙斌 《地质学报》2016,90(12):3393-3407

鄂尔多斯盆地北部已发现系列砂岩型铀矿,由东往西依次有东胜铀矿、杭锦旗(纳岭沟)铀矿、大营铀矿等大型、特大型矿床,成为我国目前砂岩型铀矿发现规模最大、最具远景的地区。研究表明,它们具有相似的矿床地质特征和形成环境。在矿床成矿作用研究中,铀的存在形式及铀矿物特征对砂岩铀矿来说是一项重要的内容,其认识对铀的地浸开采可提供重要依据,也是了解砂岩型铀矿形成机制或矿床形成环境及成因的重要信息。本文主要从三个方面对鄂尔多斯盆地北部大营铀矿、纳岭沟铀矿等主要砂岩型铀矿中铀矿物地质地球化学特征和成因进行了研究和探讨。通过电子探针测试,高分辨率扫描电镜观察等手段,认为盆地北部铀矿的铀矿物类型主要为铀石,含少量的沥青铀矿、钛铀矿、水硅铀石、钍铀石等;铀矿物常与黄铁矿、有机质(煤屑)及方解石相伴生。采用逐级化学提取等方法定量地分析了铀矿物占矿石中铀配分的比例关系,认为其中铀矿物和吸附态约各占铀存在形式的50%。首次对砂岩型铀矿的铀矿物进行微区原位LA-ICP-MS稀土元素分析,认为ΣREE在铀矿物铀石中高度富集,是矿石中稀土元素的主要载体;稀土元素是铀矿石中可综合利用的有益组份,其标准化曲线表现为明显的右倾型,轻稀土富集,轻重稀土分馏强烈,δEu和δCe具较弱的负异常,说明总体上铀矿化形成于外生后成环境。从上述铀矿物特征,初步探讨了铀矿化形成的环境与成因,认为铀矿化形成经历了至少为低温流体作用的环境;铀矿化形成于浅部地壳即外生后成环境而与深源作用无关。  相似文献   

滇东富乐铅锌矿区地层稀土元素地球化学     

念红良  贾福聚  郑荣华  李珍立  杨树祥  孙柱兵  杨卓 《矿产与地质》2016,(6):927-933

通过对罗平富乐铅锌矿区地层及矿石进行了稀土元素地球化学特征对比研究.结果显示,梁山组样品 ΣREE值25.91×10-6~108.40×10-6,δEu值0.35~0.73,δCe值0.64~1.35.具Eu负异常和Ce弱正异常;阳新组碳酸盐岩样品 ΣREE值0.82×10-6~6.75×10-6,δEu值0.15~0.97,δCe值0.22~0.62,具Eu负异常和Ce负异常;玄武岩样品 ΣREE值204.17×10-6~290.57×10-6,δEu值变化范围0.91~0.97,δCe值1.02~1.03,Eu异常和Ce异常不明显.峨眉山玄武岩、阳新组、梁山组岩石与矿石REE配分模式比较区别明显,暗示成矿物质并非这些地层提供另有其它来源;梁山组及含矿地层阳新组样品为轻稀土富集型,并具有Eu负异常,暗示地层可能形成于被动大陆边缘还原环境.  相似文献   

Tracing the source of metals in Geogas from metal deposits in a loess-covered region北大核心CSCD     

Wan W.  Wang M.-Q.  Gao Y.-Y.  Fan I.-H. 《矿物岩石地球化学通报》2016,(6):1290-1297

In order to test the distribution characteristics of metallogenic elements and the application effectiveness of the traee elements and REE for tracing the source of Geogas anomaly, the distribution characteristics of metallogenetic elements .trace elements and REE in different media of the Jiaolongzhang Pb-Zn deposit underneath the loess have been studied in this paper. Results indicate that the distribution characteristics of Geogas anomalous elements over the concealed orebodies are coincided with those of the enriched elements of ores, while the distribution characteristics of trace elements and REE in background Geogas samples are distinctly different from those of other media, indicating that the source of background Geogas materials is influenced by various factors( geological bodies, lab environment and blank reagent). The similar distribution characteristics of the trace elements in the Geogas samples of anomalous areas and in the ores suggested that Geogas anomaly is affected by concealed orebodies in depth. The difference between REE patterns of the Geogas samples of the anomalous area and those of other solid media might be caused by inadequate analytical precision and low collecting efficiency of the instrument. It is believed that the REE tracing method can provide the information on the source of Geogas anomaly if the analytical precision and collecting efficiency of REE could be constantly increased.  相似文献   

Origin of natural sulfur-metal chimney in the Tangyin hydrothermal field,Okinawa Trough: constraints from rare earth element and sulfur isotopic compositions     

《China Geology》2018,1(2):225-235

For the first time, we present the rare earth element (REE) and sulfur isotopic composition of hydrothermal precipitates recovered from the Tangyin hydrothermal field (THF), Okinawa Trough at a water depth of 1206 m. The natural sulfur samples exhibit the lowest ΣREE concentrations (ΣREE= 0.65×10^–6–4.580×10^–6) followed by metal sulfides (ΣREE=1.71×10^–6–11.63×10^–6). By contrast, the natural sulfur-sediment samples have maximum ΣREE concentrations (ΣREE=11.54×10^–6–33.06×10^–6), significantly lower than those of the volcanic and sediment samples. Nevertheless, the δEu, δCe, (La/Yb)_N, La/Sm, (Gd/Yb)_N and normalized patterns of the natural sulfur and metal sulfide show the most similarity to the sediment. Most hydrothermal precipitate samples are characterized by enrichments of LREE (LREE/HREE=10.09–24.53) and slightly negative Eu anomalies or no anomaly (δEu=0.48–0.99), which are different from the hydrothermal fluid from sediment-free mid-oceanic ridges and back-arc basins, but identical to the sulfides from the Jade hydrothermal field. The lower temperature and more oxidizing conditions produced by the mixing between seawater and hydrothermal fluids further attenuate the leaching ability of hydrothermal fluid, inducing lower REE concentrations for natural sulfur compared with metal sulfide; meanwhile, the negative Eu anomaly is also weakened or almost absent. The sulfur isotopic compositions of the natural sulfur (δ³⁴S=3.20‰–5.01‰, mean 4.23‰) and metal sulfide samples (δ³⁴S=0.82‰–0.89‰, mean 0.85‰) reveal that the sulfur of the chimney is sourced from magmatic degassing.  相似文献   

滇西盈江地区新泡山离子吸附型稀土矿床成矿条件及找矿前景     

陈曹军 《地质与勘探》2021,57(4):751-761

滇西盈江地区是近年来离子吸附型稀土矿床找矿突破较大的地区,典型代表为腾冲岩浆弧内新发现的新泡山稀土矿床,为一中型离子吸附型稀土矿床,是滇西高海拔地区新发现的典型矿床。新泡山稀土矿床的发现对今后高海拔地区的找矿工作具有重要的示范意义。通过对新泡山稀土矿床的地质特征、风化壳结构特征、矿体垂向变化特征进行研究,认为新泡山稀土矿床类型为富钕轻稀土离子吸附型稀土矿床,并伴生有重稀土钇。滇西盈江地区与花岗岩有关的离子吸附型稀土矿主要受控于母岩稀土元素丰度、气候以及地形地貌。"沟-谷-盆"地貌两侧及周缘低缓山丘和平缓山坡、山脊是有利的成矿部位。结合区域找矿成果,认为研究区稀土矿找矿潜力较大,可达超大型远景规模,在后续的找矿工作中应加强对重稀土元素钇的评价。  相似文献