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Fractionation of yttrium (Y) and the rare earth elements (REEs) begins in riverine systems and continues in estuaries and the ocean. Models of yttrium and rare earth (YREE) distributions in seawater must therefore consider the fractionation of these elements in both marine and riverine systems. In this work we develop a coupled riverine/marine fractionation model for dissolved rare earths and yttrium, and apply this model to calculations of marine YREE fractionation for a simple two-box (riverine/marine) geochemical system. Shale-normalized YREE concentrations in seawater can be expressed in terms of fractionation factors (
ij
) appropriate to riverine environments (
) and seawater (
):
where
and
are input-normalized total metal concentrations in seawater and
is the ratio of total dissolved Y in riverwater before
and after
commencement of riverine metal scavenging processes. The fractionation factors (
ij
) are calculated relative to the reference element, yttrium, and reflect a balance between solution and surface complexation of the rare earths and yttrium. 相似文献
44.
南京伏牛山铜矿脉状矽卡岩稀土元素地球化学特征 总被引：2，自引：0，他引：2
介绍了南京伏牛山铜矿与成矿有关的花岗闪长斑岩及脉状矽卡岩的稀土元素组成模式及稀土元素地球化学特征。并据两者的相似性及变异性特征,探讨了脉状矽卡岩的成因。 相似文献
45.
The magnetosphere dynamics shows fast relaxation events following power-law distribution for many observable quantities during magnetic substorms. The emergence of such power-law distributions has been widely discussed in the framework of self-organized criticality and/or turbulence. Here, a different approach to the statistical features of these impulsive dynamical events is proposed in the framework of the thermodynamics of rare events [Lavenda, B.H., Florio, A., 1992. Thermodynamics of rare events, Int. J. Theor. Phys. 31, 1455–1475; Lavenda, B.H., 1995. Thermodynamics of Extremes. Albion]. In detail, an application of such a novel approach to the magnetospheric substorm avalanching dynamics as monitored by the auroral electroject index is discussed. 相似文献
46.
利用2009-2010年四个季度月用底栖生物抓斗式采样器捕获的文昌鱼样品,从其资源分布、年龄结构、生物学和生态学特征等方面对厦门国家级珍稀海洋物种自然保护区文昌鱼的种群健康状况进行评价研究.结果表明:(1)文昌鱼种群资源分布衰减趋势明显,只在黄厝—前埔海区、小嶝岛—角屿海区和南线—十八线海区3个核心区还有分布,但资源密度低,分布范围狭小,而在鳄鱼屿实验区未能发现.(2)文昌鱼体重与体长之间关系:W=6.6895×10-4L3.1818;体长与体质量生长方程分别为:厶=65.63[1-e-0.68(t+032)],Wt=404.62[1-e-0.68(t+032)]3.1818;夏季、冬季航次的优势体长组分别为25-35mm和35-45mm,优势体重组分别为25-50mg和50-100mg;秋季低龄鱼较多,而冬季高龄鱼比例较高.(3)采用ELEFAN Ⅰ技术分析了厦门文昌鱼的Von Bertalanffy生长参数K、L∞、总死亡系数Z、自然死亡系数M和开发率E,发现其生长参数K值较大,自然死亡系数较高,开发率较大(0.69).综之,厦门自然保护区内的文昌鱼种群健康状况整体不佳,应注意资源保护,加强保护文昌鱼栖息地的底质和水质以及防止过度捕捞以实现其资源可持续利用. 相似文献
47.
The Central Asian Orogenic Belt (CAOB) was produced as a consequence of the successive closure of the Paleoasian Ocean and the accretion of structures formed within it (island arcs, oceanic islands, and backarc basins) to the Siberian continent. The belt started developing in the latest Late Neoproterozoic, and this process terminated in the latest Permian in response to the collision of the Siberian and North China continents that resulted in closure of the Paleoasian ocean (Metcalfe, 2006; Li et al., 2014; Liu et al., 2009; Xiao et al., 2010; Didenko et al., 2010). Throughout the whole evolutionary history of this Orogenic Belt, a leading role in its evolution was played by convergent processes. Along with these processes, an important contribution to the evolution of the composition and structure of the crust in the belt was made by deep geodynamic processes related to the activity of mantle plumes.Indicator complexes of the activity of mantle plumes are identified, and their major distribution patterns in CAOB structures are determined. A number of epochs and areas of intraplate magmatism are distinguished, including the Neoproterozoic one (Rodinia breakup and the origin of alkaline rock belt in the marginal part of the Siberian craton); Neoproterozoic–Early Cambrian (origin of oceanic islands in the Paleoasian Ocean); Late Cambrian–Early Ordovician (origin of LIP within the region of Early Caledonian structures in CAOB); Middle Paleozoic (origin of LIP in the Altai–Sayan rift system); Late Paleozoic–Early Mesozoic (origin of the Tarim flood-basalt province, Central Asian rift system, and a number of related zonal magmatic areas); Late Mesozoic–Cenozoic (origin of continental volcanic areas in Central Asia).Geochemical and isotopic characteristics are determined for magmatic complexes that are indicator complexes for areas of intraplate magmatism of various age, and their major evolutionary trends are discussed. Available data indicate that mantle plumes practically did not cease to affect crustal growth and transformations in CAOB in relation to the migration of the Siberian continent throughout the whole time span when the belt was formed above a cluster of hotspots, which is compared with the African superplume. 相似文献
48.
我国南方地区,特别是四川盆地震旦系灯影组是我国当前高演化天然气勘探的热点,以黔中隆起为例,新揭示了其中发育的热液白云岩化现象,并探讨了其对储层形成的影响。研究区灯影组白云岩溶蚀孔洞或裂缝中见有白云石、石英、沥青充填,其中一种充填的粗晶白云石具有弯曲晶面、波状消光特征,在岩石学特征上初步反映热液成因。地球化学特征进一步揭示了这种热液成因。不同采样位置热液白云石样品中流体包裹体均一温度平均为157.5 ℃～205.8 ℃,最高为253.5 ℃。热液白云石具有较轻的氧同位素组成,δ18OPDB 位于 -15.3‰～-8.6‰之间,平均值为 -11.2‰;较高的87Sr/86 Sr比值（0.709 445～0.713 131）,其平均值为0.710 843,在稀土元素组成上,热液白云石具有典型的Eu正异常的特点,δEu值为1.11～7.46,平均值为2.37。因此,灯影组热液白云石发育。热液活动对储层形成具有积极影响,主要体现在对充填在早期岩溶孔洞和构造裂缝中的白云石产生了溶蚀作用,溶蚀孔中见沥青充填,反映为油气运移通道和聚集空间。因此,热液溶蚀改造作用对我国南方地区震旦系灯影组及下古生界碳酸盐岩储层发育可能具有重要意义,值得加强探索研究。 相似文献
49.
Mohamed Abdallah Gad DARWISH 《《地质学报》英文版》2014,88(1):196-212
The SEM-EDX technique was applied to investigate Au, and Cu＋Sn alloyed grains in the mineralization of the Um Shashoba mine for achieving further understanding of occurrences, internal structures and microchemistry of Au and Cu alloys and associated minerals, and mineralization type. This study is aiming at the genetic history of ore-bearing fluid events, geochemical evaluation and exploration significance. The results showed that the mineralization could be considered as a single major episode generated by metamorphic mesothermal solution rich in sulfides and unsaturated respect to Au. It was differentiated into many stages; started with formation of auriferous pyrite that was pseudomorphed by secondary hematite, limonite and goethite. Three phases of Au alloy were precipitated, and Cu＋Sn and Ag-rich alloys were produced respectively and followed by deposition of two generations of barren pyrite. Calcite and ankerite were crystalized, surrounded and partially replaced some of early formed minerals. Finally, barren muscovite recrystallized around and inside both later formed carbonate minerals that were free of any sign of Au in their structures. The processes of deformation, recrystallization, annealing, dissolution, remobilization and re-precipitation played the most important roles in the genetic history of the mineralization. 相似文献
50.