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91.
新近取得的深反射与全球地震层析成像资料,为地球内部结构和流体通道的研究提供了一些依据.通过研究这些地震资料,可以了解地球内部物质分布状态的几何模式.综合研究表明,地球内存在流体通道网,它连通地球外核、中幔圈、软流圈和岩石圈,是固体地球系统的重要组成部分.这种通道网络象“动脉”那样把地球外核中的流体和热量向外传送,但与热羽说不同的是,不见得有对应的“静脉”存在以保持地幔质量平衡.固体地球作为多层次多要素的巨型复杂系统,其动力学过程要用浑沌理论去解释.研究地球流体活动的轨迹和吸引子,将有助于深入了解地球活动的规律性. 相似文献
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93.
膜蒸馏处理糠醛废水的实验研究 总被引:2,自引:1,他引:1
采用中空纤维膜蒸馏技术研究了糠醛废水的膜蒸馏处理效果,考察了料液相的温度、醋酸浓度、流速、吸收液浓度等因素对处理效果的影响。结果表明:在温差为15℃、料液的浓度为0.306 mol/mL时,速度为8 mL/min;吸收液的质量浓度为25 g/L时,速度为3 mL/min。运行12 h后,料液的pH值由开始的1.9升高为5.1,醋酸的去除率为76.3%,糠醛的去除率为40.1%。此过程可降低料液中糠醛和醋酸的含量,减小了低分子量有机酸对微生物危害的影响,为后续生物处理奠定了基础。 相似文献
94.
大气冰核观测是研究自然冷云降水和人工影响天气的一项基础性工作,滤膜—扩散云室法是观测冰核浓度的主要方法之一。为检测分析两种滤膜采集方法对冰核观测结果的影响,2011—2015年用自制的大气颗粒物采样器和FA-3型撞击式9级采样器开展了平行采样试验,采集的滤膜样本均在同一静力扩散云室中进行冰核活化显现分析。结果表明:自制采样器较9级采样器观测的冰核浓度高数倍甚至数十倍,但两者随季节和不同气象条件的变化表现出一致的起伏特征。自制采样器适用于对大气中总的冰核浓度分布及理化特征研究;9级采样器适用于对PM10中不同粒径段大气冰核浓度和尺度分布以及理化特征的研究。滤膜法对冰核数量的低估与采样体积成正比,改变采样器气泵的抽气流量和控制采样体积对改进“体积效应”影响均有明显效果。 相似文献
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Even carbon numbered n-alk-1-enes, trapped inside organic geomacromolecules such as kerogen, asphaltene and solid bitumen, can survive geologic time because of the effective protection provided by the complex matrix structures of geomacromolecules. These alkenes are presumed to be derived from esters which are commonly present in various organisms. Subjected to either normal maturation increase or the impact of drastic thermal events, these trapped n-alk-1-enes gradually decrease in concentration and eventually disappear. 相似文献
97.
A series of synthetic Ca-Tschermak–diopside (CaAlAlSiO6–CaMgSi2O6) clinopyroxenes were investigated by powder infrared spectroscopy at room temperature in the wavenumber range 80–2,000 cm−1. Measurable local structural heterogeneities in the crystals are suggested by the line broadening parameter, Δcorr that are
observed for intermediate solid-solution compositions. The broadening is most pronounced in the high wavenumber region of
the IR spectra that contains stretching modes involving the TO4 polyhedra. The effective line widths for three selected wavenumber regions deviate positively from linear behavior. This
is also observed for the enthalpy of mixing of this solid solution. The relationship between “excess Δcorr”, δΔcorr, and heat
of mixing, ΔH
mix, behavior was investigated for this clinopyroxene series and for several other binary silicate solid solutions. The ΔH
mix versus δΔcorr slope values show a linear relationship with respect to the integrated excess volume of the various solid solutions. 相似文献
98.
99.
A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics,
kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of
trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving
solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and
a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special
reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication,
the influence of several trace elements on the ΔG
f
o, ΔG
r
o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of
IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found
to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important
for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals.
Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions
higher than 0.003.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
Luigi MariniEmail: |
100.