TRPO萃取-固体荧光法测定土壤和空气尘埃中的铀     

王功鹏  赵法  周小民 《铀矿地质》1987,(2)

本文在研究了影响萃取的各种因素后,给出了用TRPO-OK萃取-固体荧光法测定土壤和空气尘埃中铀的方法。土壤和空气尘埃样品全程回收率分别为(89.6±11.8)％和(85.5±5.6)％,方法灵敏对土壤和空气尘埃样品分别为0.03μg·g~(-1)和0.02Pg·1~(-1)。样品中的常量离子对分析不产生明显干扰。操作简便、快速,适用于常规监测和本底调查。  相似文献   

地电提取测量法在北衙寻找隐伏矿的可行性   总被引：4，自引：0，他引：4  

李晓勇 《云南地质》2002,21(1):83-89

地电化学提取测量法是应生产需要而发展起来的一种轻便，快捷的寻找隐伏矿床的方法，在云南鹤庆县北衙地区进行实验研究，取得较好的效果，并在末知矿区圈定了远景规划区，为进一步探矿提供科学依据。  相似文献   

Two Experimental Methods to Determine the Speciation of Cadmium in Sediment from the River Neckar     

N. Martin  I. Schuster  St. Peiffer 《洁净——土壤、空气、水》1996,24(2):68-76

The binding forms of Cd to an anaerobic sediment of low sulfide content from Lauffen reservoir (River Neckar, Germany) were studied using two different approaches, i. e. sequential extraction (modified from published protocols) and titrimetric study of the pH-dependent Cd release. Thermodynamic equilibrium calculations were applied to calculate both the release pattern of Cd during the titrations and the speciation of Cd within the single fractions of the extraction protocol. The calculations were based on measured sediment parameters such as hydrous ferric oxide (HFO), acid volatile sulfide, carbonate content and total Cd content, and the extractants (oxalate, acid etc.) used. The results of the two independent approaches coincided well in that they both assigned more than two thirds of the total Cd content to be adsorbed to organic matter. Cd bound as CdS is of little importance. Sequential extraction after a 3-month oxidation period at pH 7 revealed a shift of Cd from being mainly bound in stronger surface complexes with organic matter to being mainly bound in weaker surface complexes with organic matter and HFO, and thus becoming more bioavailable. This study suggests that the use of sequential extraction although being frequently criticized due to its operational character can be used to determine binding forms of metal ions if they are accompanied by 1) careful supporting experiments, 2) analysis of important sediment parameters, and 3) the use of thermodynamic equlibrium models which can help to understand Cd speciation within the extraction fractions.  相似文献   

花岗岩中痕量钍同位素的液—液萃取分离法     

涂国荣  张利兴 《铀矿地质》1992,8(2):123-127

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APDC-MIBK萃取石墨炉原子吸收法测定地质样品中痕量钯   总被引：1，自引：0，他引：1       下载免费PDF全文

伊丽莹  张海政 《地质科学》1995,30(2):190-194

近年来金矿源岩研究引起国内外地质学家的极大关注。贵金属元素把具有双重特性,在超镁铁质岩浆结晶过程中性状与金相近,表现出强烈亲硫的特点,新鲜的没有发生过任何金流失的岩石,二者比值近似为一常数。把在成岩乃至于变质作用过程中呈惰性,保持其原始含量不变而又与金性状完全不同,这种双重性特征有可能借助于常数K=Au(原)/Pd(原),推算出没有发生过任何金流失时的岩石原始金含量(王建安,1986)。即通过样品中把的分析值求得原始金含量,借此对金矿源岩进行研究与判定。  相似文献   

Matlab对基于HDF格式的MODIS 1B数据的提取方法与实现   总被引：4，自引：1，他引：4  

陈林  牛生杰  仲凌志 《气象科学》2006,26(6):676-681

基于HDF文件格式的MODIS数据的应用越来越广泛,MODIS数据开发应用的前提是对MODIS 1B数据的提取。本文详细介绍了利用Matlab对HDF文件进行读写操作的过程,在此基础上给出了提取MODIS 1B数据的流程图,实现了对MODIS 1B数据的提取,为MODIS二级产品的开发打下了基础。  相似文献   

基于SVM遥感矿化蚀变信息提取研究   总被引：1，自引：0，他引：1  

傅文杰  洪金益  朱谷昌 《国土资源遥感》2006,(2):16-19,i0002

提出一种基于支持向量机(SVM)遥感数据矿化蚀变信息提取的新方法。该方法首先根据蚀变岩及矿体围岩的实测光谱数据,利用光谱角度制图法(SAM)提取训练样本,应用交叉比对(cross-validation)算法确定最优SVM模型参数,选择径向基(RBF)核函数,训练SVM分类器模型;然后,用训练好的SVM模型进行遥感矿化蚀变信息提取;最后,选择青海芒崖地区的ETM数据进行遥感矿化蚀变信息提取试验。试验结果经野外检查和验证,效果良好。  相似文献   

Influence of alcohols on the extraction of cerium(IV) by Aliquat-336 in kerosene     

Y.A. El-Nadi 《International Journal of Mineral Processing》2007

Tricaprylmethylammonium chloride (Aliquat-336) diluted with kerosene was used to extract cerium(IV) from nitric acid medium. Various alcohols were used as modifiers to overcome the third phase problem. The different parameters affecting the extraction process including nitric, nitrate, hydrogen ion, extractant and metal concentrations as well as the temperature were separately investigated. The effect of the investigated alcohols on the extraction process was also studied in detail at two different concentrations and correlated to their physical constants. Based on the obtained results, the extraction equilibrium was deduced and the optimum conditions for the extraction of cerium(IV) were proposed. The method was tested and applied to the separation of cerium from the hydrous oxide cake resulting from monazite sand.  相似文献   

Analytical perspective on trace element species of interest in exploration   总被引：1，自引：0，他引：1  

Gwendy E. M. Hall 《Journal of Geochemical Exploration》1998,61(1-3)

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.  相似文献   

萃取分离—石墨炉原子吸收光谱法测定铅锌矿中的铟     

赵星  张代云  刘锐 《云南地质》2014,33(3):417-420

样品经硝酸、氢氟酸分解除硅,加热硫酸冒烟除尽硝酸、氢氟酸,利用铟与氢溴酸能生成稳定的络合物并被乙酸丁酯萃取的性质,将铟与其它干扰离子分离并富集.使用MOLAARM6（Thermo Electron Corporation）石墨炉原子吸收分光光度计,以钒为机体改进剂,测定铅锌矿中的铟.方法检出限为LD=0.012ug/ml.实验结果令人满意.  相似文献