贵州夜郎湖表层水体地球化学昼夜变化及其影响因素     

王家录  任娟  王勇  李维杰  娄昭  陈佳 《热带地理》2020,40(2):335-345

为探究岩溶水库水文地球化学行为过程,对贵州普定夜郎湖表层水体进行了为期3 d的高分辨率昼夜监测。结果表明：1）多变的天气和水文条件叠加导致水体离子指标昼夜变化不显著,规律性较差。而水温、DO、pH值、SpC、SIc、pCO₂等常规理化指标受水温变化和生物作用表现出明显的昼夜波动。2）利用亨利常数和主成分分析,得到温度变化、生物作用、人类活动、水库的蓄水与放水对夜郎湖水库水文地球化学特征变化的贡献率分别为21.66%、17.28%、14.08%和10.22%,说明作用于水库水文地球化学行为的因子具有多元性。3）δ ¹⁸O表现出与DO一致的波动趋势,即白天上升,晚上下降,反映在短时间尺度上,氢氧稳定同位素变化受控于生物过程（主要是呼吸作用过程）;而对比水库水体和大气降水的d-excess（d值）发现,水库水体的d值（8.21‰）显著偏低于当地大气降水的d值（9.64‰）,说明在长时间尺度上,主要受蒸发效应引起的不平衡分馏影响。  相似文献   

察尔汗盐湖西北部典型采区地下卤水赋存状态的地面核磁探测与数值模拟研究          下载免费PDF全文

张光武  易磊  高泽永  韩凤清  陈富洪  马喆  卢晓航  刘小宝  韩光  袁文虎  刘溪溪 《盐湖研究》2020,28(1)

察尔汗盐湖地下晶间卤水蕴藏了宝贵的盐湖矿产资源,如何确定地下卤水的赋存规律以制定科学合理的卤水开采和补给方案,正成为盐湖资源大规模可持续利用亟需解决的重要问题。本文以察尔汗盐湖西北部的典型采卤区作为研究区域,1)利用新型的地面核磁共振找水仪,通过在研究区布设两条十字交叉的测线,探测并反演解译测区地下60米深度内的卤水静态赋存形式,2)结合OpenGeoSys(OGS)多物理场耦合地下水数值模拟软件,对测区地下卤水的动态运移形式进行数值模拟计算。地面核磁探测结果表明研究区含水量整体偏低,最大含水量约0.8%,平均含水量约0.4%。测点结果给出的含水层位分界面与邻近钻孔的地层层位分界面的一致性较高,浅部的层位误差在10%以下,达到了0.5米的精度。考虑到测区南北两边均有采卤渠正在汲取地下卤水,且在测区中心存在两条废弃的采卤渠,OGS地下水数值模拟研究结果表明采卤渠造成测区浅部卤水较大空缺,与研究区浅部含水量总体偏低的探测特征一致。研究结果表明地面核磁共振技术能准确探测卤水当前的赋存状态,地下水运移模拟技术可以深入认识采补活动引起卤水赋存状态的变化规律。探测和模拟结合的联合研究是确定卤水赋存规律的重要手段,研究成果可为盐湖资源合理开采高效利用提供基础资料和相关科学支撑。  相似文献   

A modified numerical model for moisture-salt transport in unsaturated sandy soil under evaporation     

Wei Wen  YuanMing Lai  ZheMin You 《寒旱区科学》2020,12(3):125-133

Soil salinization, caused by salt migration and accumulation underneath the soil surface, will corrode structures. To analyze the moisture-salt migration and salt precipitation in soil under evaporation conditions, a mathematical model consisting of a series of theoretical equations is briefly presented. The filling effect of precipitated salts on tortuosity factor and evaporation rate are taken into account in relevant equations. Besides, a transition equation to link the solute transport equation before and after salt precipitation is proposed. Meanwhile, a new relative humidity equation deduced from Pitzer ions model is used to modify the vapor transport flux equation. The results show that the calculated values are in good agreement with the published experimental data, especially for the simulation of volume water content and evaporation rate of Toyoura sand, which confirm the reliability and applicability of the proposed model.  相似文献   

Muon density measurements with the KASCADE central detector     

《Astroparticle Physics》2002,16(4):183-386

Frequency distributions of local muon densities in high-energy extensive air showers (EAS) are presented as signature of the primary cosmic ray energy spectrum in the knee region. Together with the gross shower variables like shower core position, angle of incidence, and the shower sizes, the KASCADE experiment is able to measure local muon densities for two different muon energy thresholds. The spectra have been reconstructed for various core distances, as well as for particular subsamples, classified on the basis of the shower size ratio N_μ/N_e. The measured density spectra of the total sample exhibit clear kinks reflecting the knee of the primary energy spectrum. While relatively sharp changes of the slopes are observed in the spectrum of EAS with small values of the shower size ratio, no such feature is detected at EAS of large N_μ/N_e ratio in the energy range of 1–10 PeV. Comparing the spectra for various thresholds and core distances with detailed Monte Carlo simulations the validity of EAS simulations is discussed.  相似文献   

On the accretion geometry of Cyg X-1 in the low/hard state     

F. Eugenio Barrio  Chris Done  Sergei Nayakshin 《Monthly notices of the Royal Astronomical Society》2003,342(2):557-563

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Warm gas kinematics in shell galaxies     

R. Rampazzo  H. Plana  M. Longhetti  P. Amram  J. Boulesteix  J.-L. Gach  O. Hernandez 《Monthly notices of the Royal Astronomical Society》2003,343(3):819-830

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Deuterium fractionation on interstellar grains studied with the direct master equation approach     

Tatiana Stantcheva  Eric Herbst 《Monthly notices of the Royal Astronomical Society》2003,340(3):983-988

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The emission distribution in RR Pictoris     

L. Schmidtobreick  C. Tappert  I. Saviane 《Monthly notices of the Royal Astronomical Society》2003,342(1):145-150

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Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献