镁矿石中钙镁的快速连续测定   总被引：4，自引：1，他引：3  

栾日坚  丁梅清 《岩矿测试》1999,20(2):139-141145

在一份ｐＨ１０的氨缓冲溶液中,分别用乙二醇二乙醚二胺四乙酸和环己二胺四乙酸连续滴定Ｃａ和Ｍｇ。方法用于镁矿石中Ｃａ和Ｍｇ的测定。结果与标准值和外检结果一致。测定镁矿石中ＣａＯ和ＭｇＯ１２次的ＲＳＤ分别为〈５％和〈０．３０％。  相似文献   

EGTA滴定法测定海水Ca²⁺浓度精度评估及其在近海海域实测的必要性          下载免费PDF全文

张锗  边海珍  任宏伟  胡玉斌 《应用海洋学学报》2023,42(3):514-519

海水Ca²⁺浓度是计算碳酸钙饱和度的重要参数之一,通常由海水钙盐比值计算得出,但该方法在受多种因素影响的近海海域可能不适用。本研究开展了EGTA自动电位滴定法对不同盐度海水Ca²⁺浓度测定精度和准确度的研究,探究“盐效应”对Ca²⁺浓度测定可能存在的影响,并比较了近海养殖区海水实测Ca²⁺浓度与通过钙盐比估算值的差异。研究表明：①EGTA自动电位滴定法测定不同盐度海水Ca²⁺浓度精度较高,在各个盐度条件下,5次平行测定的标准偏差为0.001~0.006 mmol/kg,精度均优于0.1%;②在盐度20.00~34.62范围内,Ca²⁺的实测值与通过钙盐比值计算所得的相对误差为-0.043%~0.023%,准确度在± 0.05%内;③不同盐度海水样品Ca²⁺浓度的实测值与理论值基本吻合,电位滴定法测定Ca²⁺浓度不存在“盐效应”问题;④受陆源输入过程的影响,近海（烟台牟平养殖区）表层及底层海水Ca²⁺的实测值比按钙盐比值的计算值分别高出0.360 mmol/kg和0.333 mmol/kg,表明利用钙盐比值估算法不适用于近海海水中Ca²⁺浓度,通过实测Ca²⁺浓度计算近海海水碳酸钙饱和度可以更准确评估近海酸化的程度。  相似文献   

溶解氧测定探头式与经典滴定法的互校及无氧水零点校正法     

彭兴跃  洪再展 《海洋科学》2004,28(8):23-27

设计了制作无氧水及溶解氧梯度水的装置,以研究溶解氧测定中溶解氧探头测定结果与经典滴定法测定结果的互校性、可靠性。结果表明,在从无氧水到18g／L(对一个大气压空气来说是过饱和)的氧含量范围内,这2种方法有很好的线性关系。但是,经典滴定法比溶解氧探头测定的值偏高,这是经典滴定法从采样固定到滴定整个非在线测定过程易于受各种干扰所体现的固有的缺点。特别是对于极度缺氧或无氧水样的测定,经典滴定法会得出偏高甚至错误的结论。因此作者推荐环境监测中溶解氧的测定采用溶解氧探头的测定数据．而滴定的方法可以采用无氧水对零点进行校正。  相似文献   

A weighing lysimeter in a regenerating eucalypt forest: Design,construction, and performance     

W. Reyenga  F. X. Dunin  B. C. Bautovich  C. R. Rath  L. B. Hulse 《水文研究》1988,2(4):301-314

A 36 tonne monolithic weighing lysimeter (3.7 m diameter and 1.5 m deep) was installed in Kioloa State Forest near Batemans Bay, New South Wales, Australia, to provide a continuous record of water use from a regenerating natural eucaplyt community, five years old at installation. The resolution is equivalent to 0.05 mm of evaporation and provides hourly information for diurnal variation of forest evaporation. The sensitivity of 14 ppm compares favourably with those reported for other lysimeters, similar in magnitude, in the U.S.A. Design criteria for selecting, isolating and suspending a sample community ‘in situ’ with an electro-mechanical balance are outlined. Procedures adopted during installation are described with emphasis placed on precautions taken to minimize disturbance and to avert possible changes in character of the isolated natural community. Lysimeter performance was assessed both in terms of its accuracy and its operation as a remote facility with infrequent attention.  相似文献   

Evaluation of the ventilated chamber for measuring evaporation from a forest     

F. X. Dunin  E. A. N. Greenwood 《水文研究》1986,1(1):47-62

Evaporation from a regenerating forest was determined concurrently by atmospheric measurements of the Bowen ratio, soil water depletion, and by weighing lysimeter. The methods agreed closely over 18 days in spring and 11 days in summer. Accordingly, the Bowen ratio technique was then used as the control against which any effect on evaporation by enclosure of the lysimeter with a chamber of varied ventilation rate could be quantified hourly and daily. Accuracy of gas analysis was checked against lysimeter values. Daily evaporation by the lysimeter was generally unaffected by enclosure—on a few afternoons there was a statistically significant enhancement of hourly values by the chamber. This was accounted for by difference in turbulence between chamber and forest. The general agreement in daytime hourly values is attributed to the frequent occurrence of equilibrium evaporation (rate at which evaporation is independent of ventilation). At night, evaporation was higher during enclosure. Comparisons were not possible with rain or dew. Determination of evaporation by gas analysis agreed within about 5 per cent of lysimeter values during a dry period. We conclude that the ventilated chamber as used provides realistic estimates of evaporation by forests. We show how periods of bias can be anticipated and corrected by theory.  相似文献   

自动电位滴定仪高效高精度测定海水碱度值   总被引：1，自引：0，他引：1       下载免费PDF全文

陶小晚  钟少军  阎军  瞿成利 《海洋科学》2008,32(10):77-80

为研究海洋碳循环和海洋碳酸盐系统,需要测定样品的碳酸盐碱度。利用电位滴定仪(万通~(?)798MPT Titrino)配合软件tiamol.1检测了海水总碱度。根据碳酸盐解离常数计算出了海水碳酸盐碱度,相时标准偏差低于0.1%(±2μmol/kg),单个样品用量约25 mL,检测时间约9 min。实验结果表明,用自动电位滴定仪测定海水总碱度速度快,精度高,方法可行。  相似文献   

质量滴定分析方法及其应用          下载免费PDF全文

李红霞  董欧阳  姚燕  王红英  曾德文 《盐湖研究》2011,19(3):31-36

介绍了质量滴定分析法,通过质量滴定法对Hg(NO3)2和EDTA滴定液浓度的标定及对CaCl2、MgCl2和LiCl样品溶液浓度的测定,以及测定结果与基准称重法和重量分析法浓度测定结果相比较,验证了质量滴定法测定的准确性和精度,获得了相对偏差小于0.11%的一致结果。结果表明,溶液离子浓度的测定可用质量滴定法替代容量法和重量法。  相似文献   

基体分离-电位滴定法测定高硫金属矿中的微量氯   总被引：2，自引：1，他引：1  

胡晓静  卢琪  姜莉  钟志光  仇薪越  聂东锐  王琦  张华一  曹凤梅 《岩矿测试》2010,29(1):80-82

使用碳酸钠-氧化锌混合碱焙烧样品,将硫化物矿中的低价硫转化为硫酸盐或高价硫,过滤分离基体,采用电位滴定法测定硫化物矿(铜精矿、锌精矿、硫铁矿)中的微量氯,消除由于硫化银沉淀的产生对氯化银测定结果的干扰。通过电位突越,确定滴定终点,消除色度和浊度对滴定终点的影响。采用电极电位-浓度二次微商滴定曲线,计算滴定终点。对混合碱的选择及加入量、焙烧温度、溶液酸度、测定温度、滴定介质以及基体和共存元素的干扰进行了试验。方法精密度(RSD,n=9)均小于9%,回收率为94.1%~105.6%。  相似文献   

Chemical characterization of humic substances isolated from mangrove swamp sediments: The Qinglan area of Hainan Island,China     

Yaoling Zhang  Jinzhou Du  Fenfen Zhang  Yihua Yu  Jing Zhang 《Estuarine, Coastal and Shelf Science》2011

In order to improve the understanding of structural and reactive features of sediment organic matter from mangrove swamp as well as evaluate the relationship between such features and the impact from different sources (marine and terrestrial), humic and fulvic acids were isolated from two mangrove swamp sediments located in the Qinglan harbors on Hainan Island, China. One is a forest surface sediment site (WWM2), and the other is an estuary subaqueous sediment site (BMW). The humic and fulvic acids were characterized and compared using chemical and spectroscopic methods, including elemental analysis, thermogravimetric analysis (TGA), Fourier Transformed Infrared Spectroscopy (FTIR), ¹³C nuclear magnetic resonance (¹³C NMR) and potentiometric titrations. The results indicated that there were less aliphatic compounds but more aromatic compounds and oxygen-containing functional groups in fulvic acids. Humic acids contained more long-chain hydrocarbons and nitrogen compounds. Comparison of the C/N ratios and δ¹³C values for the humic substances at both sites indicated a larger marine and/or microbial contribution to the BMW site. Humic substances at the WWM2 site have more acidic functional groups than those of the BMW site. Compared to the literature, more phenolic groups existed in the samples of both sites, which may be due to the autochthonous contribution of mangrove plants.  相似文献   

Interception loss from eucalypt forest: Lysimeter determination of hourly rates for long term evaluation     

F. X. Dunin  E. M. O'Loughlin  W. Reyenga 《水文研究》1988,2(4):315-329

Analyses of the response by a weighing lysimeter in Kioloa State Forest during and after rainfall provided values of interception loss rate. The derived rates for time scales between 0.1 and 1.0mm h^?1 were generally similar throughout storm events to losses determined from throughfall and stemflow observations. During post-rainfall periods of canopy drying, enhanced rates of lysimeter evaporation were consistent with micrometeorological determinations of the partitioning of available radiant energy, based on atmospheric gradients of humidity and temperature. Interception losses from the eucalypt forest, deduced from the lysimeter response, varied between 10 and 15 per cent of gross rainfall in three consecutive 12 month periods whereas the corresponding rainfall ranged between 590 and 1530 mm yr^?1. Daytime losses accounted for about two-thirds of total interception loss with a similar fraction occurring during rain periods. Storage capacity of the evergreen forest canopy was inferred to be 0.35 mm. Hourly loss rates during rainfall ranged up to 0.8 mm h^?1 but with decreasing mean values and variability with increasing time scale resulting in a monthly mean value computed for the total number of hours of rain of approximately 0.1 mm h^?1. A preliminary analysis of loss rate in terms of storm windspeed and rainfall intensity explained about half of its variation in statistically derived relationships. Improved time resolution of the order of seconds was considered a prerequisite to the physical understanding of turbulent transport from saturated canopies. The small value of interception storage capacity was considered in relation to that for pine forest as a basis for explaining observed differences in interception behaviour between eucalypt forest and coniferous plantations in the same area. Large differences in interception losses between the Kioloa site and evergreen forest in the South Island of New Zealand and also eucalypt forest in Western Australia were attributed to dissimilar meteorological conditions at the various sites.  相似文献