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21.
The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt 总被引:4,自引:0,他引:4
J. Sánchez España E. López Pamo E. Santofimia Pastor J. Reyes Andrés J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD)
waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters
were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously
recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and
precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5
(stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates
of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially
sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4=
anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous
free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely
scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH
< 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co,
Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB. 相似文献
22.
A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a
damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations
of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide
a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect
the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate
the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential
hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms
of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground
motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account
in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based
on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for
emergency response. 相似文献
23.
列举了企业内邵会计控制存在的内部会计系统控制机制不健全,监督、考核机制乏力,财务控制存在漏洞、公司企业治理结构不完善等目前企业内部会计控制现状及重点存在问题。提出了完善企业的内部会计控制环境.不相容职务必须分离,强化监督,督促实施,加强会计基础工作,完善会计电算化管理,规范业务处理程序等具体改进建议。 相似文献
24.
利用FY-1C连续两年的遥感资料,以敦煌辐射校正场为分析区,系统分析了FY-1C可见光、近红外通道的衰减特征,开展了通道衰减订正试验。分析结果表明,FY-1C除可见光通道1衰减强烈外,其它各可见光、近红外通道衰减性能稳定。利用统计分析法,可以建立定标系数衰减订正量随时间的变化关系。订正后的定标系数与2000年辐射校正场外定标实验结果一致性很好。更新后的定标系数可以有效克服通道衰减带来的通道反射率测值误差,提高FY-1C可见光、近红外通道遥感资料定量应用的精度。 相似文献
25.
26.
Audrey GalvéAlfred Hirn Jiang MeiJosep Gallart Béatrice de VoogdJean-Claude Lépine Jordi DiazWang Youxue Qian Hui 《Earth and Planetary Science Letters》2002,203(1):35-43
New wide-angle reflection and refraction seismic data provide constraints on the structure of the upper lithosphere, and test models of its evolution to raise the northeastern part of the Tibetan Plateau. Amplitudes observed for reflections from the crust-mantle boundary are sufficiently large to suggest that there is no significant partial melt in the deep crust. The data show an increase of the crustal thickness between terranes from north of the Kun Lun Fault into the Qang Tang of central Tibet, and a contrast among their intracrustal images and compositions. In the north, P and S velocities are consistent with a dominantly felsic composition and show that only the upper crust thickened. South of the Kun Lun Fault a thicker crust made of two layers could result from the superposition of the originally thin crust of the Bayan Har terrane on the lower part of the crust of the domain to the north, which upper crust it shoved and thickened. Different modes of crustal thickening, either by thickening of individual layers or superpositions and imbrication among them appear to work jointly to raise the topography. 相似文献
27.
Comparison of Seismic Dispersion and Attenuation Models 总被引:2,自引:0,他引:2
The frequency-dependent attenuation of seismic waves causes decreased resolution of seismic images with depth, and the difference in transmission losses induces amplitude variations with offset. Transmission losses may occur due to friction or fluid movement, or may result from scattering in thin-layer. Whatever the physical mechanism, they can often be conveniently described using an empirical formulation wherein the elastic moduli and propagation velocity are complex functions of frequency.We have compiled and compared algebraically and numerically eight different models involving complex velocity: the Kolsky-Futterman model, the power-law model, Kjartansson's model, Müller's model, Azimi's second and third model, the Cole-Cole model, and the standard linear-solid model.For two different parameter sets, the attenuation and phase velocity are computed in the seismic frequency band, and the plane-wave propagation of a Ricker wavelet for the other models is compared with that for the Kolsky-Futterman model. The first parameter set consists of parameters for each of the models calculated from expressions given in the appendix. These expressions make the different models behave similarly to the KF model. The second parameter set consists of model parameters that are numerically adapted to the KF model.By selecting proper parameters, all models, except the standard linear-solid model, show behavior similar to that of the Kolsky-Futterman model. The SLS model behaves differently from the other models as the frequency goes to zero or infinity. Broadband measurement data is needed to select a specific model for a given seismic experiment. 相似文献
28.
29.
Power-law attenuation in acoustic and isotropic anelastic media 总被引:1,自引:0,他引:1
30.
An anisotropic fractured poroelastic effective medium theory 总被引:1,自引:0,他引:1
S. R. Tod 《Geophysical Journal International》2003,155(3):1006-1020