海黍子吸附重金属镉离子的研究     

常秀莲  王文华  冯咏梅  郑舒文 《海洋通报》2003,22(4):26-31

采用廉价的多细胞褐藻海黍子对重金属镉离子进行吸附，研究海黍子不同的预处理方法、溶液的pH值、初始Cd^3 浓度、外加盐等因素对Cd^3 的吸附特性的影响。并对吸附机理进行了初步的探讨，发现镉离子与海黍子中的钙离子发生离子交换作用，交换率占总吸附量的38％～50％。适宜的pH范围为3～6，海黍子的最大吸附量高达181mg/g，得出了适宜的吸附等温线方程，并进行了简单的洗脱研究。  相似文献   

Measurement of Mass-Independent Perturbations of Cadmium in Nuclear Debris Samples     

Daniel J. Meininger  William S. Kinman  Susan K. Hanson 《Geostandards and Geoanalytical Research》2023,47(2):457-465

The isotopic composition of cadmium in nuclear debris was measured by multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). Mass-independent perturbations due to fission product decay on the isotopes of Cd were observed. Relative fission yields for masses 111, 112, 114 and 116 were determined in each sample of nuclear debris and compared with reported values found in irradiated plutonium and uranium fuels. Mass spectrometry measurements of the valley fission product endpoints are extremely challenging due to the low cumulative fission yields and small amounts of each isotope that are produced. To overcome these challenges, a new purification method for Cd was developed and validated by examination of a number of geological reference materials.  相似文献   

4l0哌啶树脂分离富集－原子吸收测定化探样品中痕量镉     

李玉珍  陈德勋 《岩矿测试》1995,(4):285-287

研究了４１０哌啶树脂对Ｃｄ的吸附行为，在２％～２０％ＨＣＩ介质中［ＣｄＣｌ＿３］￣－被树脂吸附，采用４％～３０／ＨＮＯ＿３溶液可以解脱Ｃｄ，回收率在９６％以上。测定了Ｃｄ在该树脂上的分配系数为５４９０，对含Ｃｄ０．０６７μｇ／ｇ的标样ＧＳＲ－３平行测定６次，相对标准偏差为９．５％。方法用于化探样品中０．０Ｘ×１０￣－６级Ｃｄ的测定，结果满意。  相似文献   

计算极谱法同时测定镉镍的研究   总被引：1，自引：0，他引：1  

佘振宝  梁中 《岩矿测试》1993,12(1):46-49

采用普通极谱仪与计算机联机技术,用卡尔曼滤波处理以KSCN为支持电解质的Cd~(2+)和Ni~(2+)混合溶液的示波极谱重叠波。实验表明,极谱可逆波具有较好的加和性,可采用计算极谱方法对多组分(尤其是难以分开的重叠波)进行同时测定。  相似文献   

甲基异丁基酮负载泡塑富集—原子吸收测定岩矿中痕量金银铊镉   总被引：4，自引：4，他引：4  

陈金武  曾法刚 《岩矿测试》1993,12(2):85-88

研究了多种负载泡塑对Au、Ag、Ti、Cd的富集行为。提出了在HCI-KI-抗坏血酸介质中用甲基异丁基酮(MIBK)负载泡塑同时萃取,然后用2％硫脲-1％HCl解脱的富集方法,并采用火焰原子吸收连续测定地质样品中痕量Au、Ag、Tl和Cd,方法的测定下限(μg/g)分别为:0.2g、0.05、0.20和0.04。  相似文献   

某冶炼厂附近农田镉污染调查与对策   总被引：5，自引：2，他引：3  

闭向阳  马振东 《地质科技情报》2003,22(2):87-90

对遭受某铜矿冶炼厂镉污染的湖北省某镇约30km^2的农田土壤进行了调查,对土壤耕作层与亚耕层以及污染源(废气、废水和炉渣)中全量Cd和有效态Cd含量的系统测定结果表明：未受Cd污染、受轻度污染及受中度污染的土壤面积分别占3．6％,82．1％,14．3％;土壤中全量Cd及有效态Cd含量的分布规律均表现为西灌区＞东灌区＞灌间区;土壤耕作层与亚耕层中全量Cd含量的差异不大,而有效态Cd则主要富集于土壤耕作层中;受土壤pH值的影响,Cd在污染区土壤中的活化率低于远离冶炼厂未受污染的农田对照区。该镇农田的Cd污染主要来源于某铜矿冶炼厂的废气和废水,而炉渣的污染相对较小。运用生态方法治理该镇农田的Cd污染具有一定的可行性和适用性,值得研究利用。  相似文献   

自然界中ZnS-CdS完全类质同象系列的发现和初步研究   总被引：6，自引：1，他引：6       下载免费PDF全文

刘铁庚  张乾叶霖  邵树勋 《中国地质》2004,31(1):40-45

过去认为在自然界中的Cd只能有限替代ZnS中的Zn。但是，近几年笔者在研究贵州牛角塘镉锌矿床时，经电子探针、扫描电镜和透射电镜等多种方法的研究，发现锌硫化物中的Cd主要以类质同象存在，其含量可从0．8％增至37．93％；镉硫化物中的Zn同样主要以类质同象存在，其含量为2．43％～38．64％。锌硫化物与镉硫化物成渐变的过渡关系，并且Zn与Cd成很好的负相关关系，相关系数达0．99以上，形成ZnS-CdS的完全类质同象系列。这一发现无论在矿物学，还是在地球化学和矿床学上都具有重要的理论意义和实用价值。  相似文献   

Mechanism of cadmium resistance and adsorption of a yeast strain Rhodotorula sp. Y11     

YUAN Hongli  LI Zhijian  WANG Nengfei  HUANG Huaizeng 《中国科学D辑(英文版)》2005,48(Z2)

The mechanism of cadmium resistance of a yeast strain Rhodotorula sp. Y11 isolated from mine soil was investigated. We found that the yeast cells treated with different methods showed different cadmium-adsorption models. Grown in medium supplied with 100 mg/L of cadmium, 3.29% of the cell-absorbed cadmium was accounted in the cytoplasm. However, only 1% was taken into the cytoplasm and 99% was bound to the cell wall using the lyophilized biomass to adsorb cadmium in double distilled water. Treatments with alkali, ethanol-chloroform and proteinase showed different influences on the biosorption of whole cells and isolated cell walls. FT-IR analysis showed that acetyl of chitin was the active compound in the cells to absorb cadmium. The production of Metallothioneins, proteins related to the resistance to heavy metal in yeast, was evidently induced by cadmium, achieving 638.8 μg/g wet weight, which was about 85 folds higher than that in the uninduced biomass and was also much higher than that reported previously. The molecular weight of Metallothioneins was 6500 Da estimated by SDS-PAGE.  相似文献   

Environmental investigation for causality and remediation of cadmium contaminated soils in Tak Province, Thailand     

Anong Paijitprapapon Kiattiphong Udomtanateera Orapin Udomtanateera Vanruedee Chariyapisuthi Trakool C hengsuksawat 《中国地球化学学报》2006,25(B08):253-254

Highly elevated cadmium concentrations in paddy soil in the Mae Sod District, Tak Province, Thailand, was detected and widely reported in 2003. This emergence provoked public interest and demands for responsibility and remedial actions. As zinc mines and concentrator were located in the upstream area, mining activities were proclaimed a contamination source. Department of Primary Industries and Mines （DPIM）, a governmental organization responsible for mining and mineral processing, was thus challenged to verify the reliability of post monitoring data displaying consistently low heavy metal concentrations in compliance with the standard limits for over 15 years. Detailed survey and deep-going research on the causes, boundary and severity of cadmium contamination as well as the environmental impact alleviation were consequently conducted. Environmental samples were accumulated systematically for 2 years throughout the areas of upstream and downstream mining sites. A total of 259 soil samples from 53 spots at the depths of 0-20, 20-40, 40-60 and 60-200 cm were drilled with hand auger. Samples of water, stream sediment and mine tailing were also collected. Chemical analysis for cadmium （Cd）, zinc （Zn） and lead （Pb） concentrations with AAS and ICP were undertaken. The contaminated area was finally defined to spread over approximately 18 square kilometer mainly of mountainous mineralizing land and colluvium.  相似文献   

The environmental effect of cadmium-rich Pb-Zn deposit, as exemplified by Niujiaotang Cd-rich Zn deposit, Guizhou, China     

《中国地球化学学报》2006,25(B08):45-45

  相似文献