Spectrophotometric pH measurement in estuaries using thymol blue and m-cresol purple     

Luke M. Mosley  Shamus L.G. Husheer  Keith A. Hunter   《Marine Chemistry》2004,91(1-4):175-186

The conditional acid dissociation constants (pK_a′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pK_a′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln⁻¹):The estimated accuracy of pH measurements using these calculated pK_a′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities.  相似文献   

Meiobenthic Organisms as Indicators of Mixing Processes in the Baltic Surface Sediments*     

Janusz Pempkowiak  Joanna Kozuch  Maria Szymelfenig 《Marine Ecology》1996,17(1-3):175-179

Abstract. Two sediment cores were collected in the southern Baltic Sea and sliced into 1.0cm-thick layers. Sediments of each layer were analysed for activities of ²¹⁰Pb, ¹³⁷Cs, ¹³⁴Cs and for the density of meiobenthic organisms (meiofauna). Zones with the rapid mixing occur in the uppermost layers (0–3 cm) of the cores based on ^I34Cs profiles. The extent and density of meiofauna confirmed the rapid mixing and revealed layers with slow mixing (4–8 cm). Sedimentation rates were derived from ²¹⁰Pb profiles below the mixing zones (1.21 and 1.72 mm a-^I) and were confumed by ¹³⁷Cs distribution. Of twenty-one major meiofauna taxa commonly found in the Baltic sediments, three were present in the cores.  相似文献   

河南省卢氏县张家山铁矿地质特征及成因浅析     

周红春  刘传权  郭克剑  彭松民  张毅星  王凌云 《华南地质与矿产》2008,(2):43-48

通过对张家山铁矿床矿体与围岩的接触关系、蚀变特征、矿石的矿物组合、化学组分等地质特征及成因的分析研究,认为张家山铁矿床应属风化淋滤型铁矿床,其原生矿床为铁多金属硫化物矿床,并厘定了该地区铁矿的找矿标志。  相似文献   

三工河流域新老绿洲发育度的比较   总被引：1，自引：0，他引：1  

何新梅  李小玉  肖笃宁  李彦 《干旱区地理》2006,29(3):342-347

绿洲是干旱区最重要的景观单元之一。人工绿洲是在干旱条件下经长期人类活动改造而形成的特殊景观。随着人类对绿洲水土资源开发利用程度的不断加强,绿洲呈现出不同的发展阶段。从天然绿洲到人工绿洲,是人类适应和改造干旱区自然环境的历程。在这一人地相互作用的过程中,绿洲显示出明显的发育演化特征。从多学科综合的角度,提出绿洲发育度的概念,并从灌溉体系的建设状况、水资源的利用水平、植被与生态建设、农业发展程度、社会经济水平和绿洲景观结构等7个方面提出了绿洲发育度的评价指标体系,以天山北坡2个人工绿洲为例,从空间上定量比较2个绿洲的发育程度,其中阜康市绿洲发育度高于222团绿洲(阜北农场)。  相似文献   

Peak discharge of a Pleistocene lava-dam outburst flood in Grand Canyon, Arizona, USA   总被引：1，自引：0，他引：1  

Cassandra R. Fenton  Robert H. Webb 《Quaternary Research》2006,65(2):324-335

The failure of a lava dam 165,000 yr ago produced the largest known flood on the Colorado River in Grand Canyon. The Hyaloclastite Dam was up to 366 m high, and geochemical evidence linked this structure to outburst-flood deposits that occurred for 32 km downstream. Using the Hyaloclastite outburst-flood deposits as paleostage indicators, we used dam-failure and unsteady flow modeling to estimate a peak discharge and flow hydrograph. Failure of the Hyaloclastite Dam released a maximum 11 × 10⁹ m³ of water in 31 h. Peak discharges, estimated from uncertainty in channel geometry, dam height, and hydraulic characteristics, ranged from 2.3 to 5.3 × 10⁵ m³ s⁻¹ for the Hyaloclastite outburst flood. This discharge is an order of magnitude greater than the largest known discharge on the Colorado River (1.4 × 10⁴ m³ s⁻¹) and the largest peak discharge resulting from failure of a constructed dam in the USA (6.5 × 10⁴ m³ s⁻¹). Moreover, the Hyaloclastite outburst flood is the oldest documented Quaternary flood and one of the largest to have occurred in the continental USA. The peak discharge for this flood ranks in the top 30 floods (>10⁵ m³ s⁻¹) known worldwide and in the top ten largest floods in North America.  相似文献   

Soil quality changes in land degradation as indicated by soil chemical, biochemical and microbiological properties in a karst area of southwest Guizhou, China   总被引：7，自引：0，他引：7  

Pingjiu Zhang  Lianqing Li  Genxing Pan  Jingchen Ren 《Environmental Geology》2006,51(4):609-619

Not only the nutritional status and biological activity but also the soil ecological functioning or soil health has been impacted profoundly by land degradation in the karst area of southwest China where the karst ecosystems are generally considered as extremely vulnerable to land degradation under intensified land-use changes. The objectives of this study are to elucidate the changes in overall soil quality by a holistic approach of soil nutritional, biological activity, and soil health indicators in the karst area as impacted by intense cultivation and vegetation degradation. Topsoil samples were collected on selected eco-tesserae in a sequence of land degradation in a karst area of southwest Guizhou in 2004. The soil nutrient pools of organic carbon (C_org), extractable extracellular carbon (C_ext), total soil nitrogen (N_t), alkali-hydrolyzable nitrogen (N_ah), total phosphorus (P_t), available phosphorus (P_a) were analyzed by wet soil chemistry. The soil biological properties were studied by means of measurements of microbial biomass carbon (both by fumigation–extraction, FE-C_mic, and by calculation from substrate-incubation respiration, SIR-C_mic) of respiration [respiration without addition of substrates, basal respiration (BR), and potential respiration (PR) with substrate-incubation] and of soil enzyme activities (invertase, urease, and alkaline phosphatase). Soil health status was assessed by simple indices of C_mic/C_org and BR/C_mic in conjunction with bacterial community structures determined by polymerase chain reaction and denaturing gradient gel electrophoresis. While the nutritional pool parameters, such as C_org and C_ext, described basically the changes in soil life-supporting capacity with cultivation interference and vegetation declined, those parameters of biological activity such as FE-C_mic, SIR, and SIR-C_mic as well as bacterial community structures measured by molecular method evidenced well the changes in soil functioning for ecosystem health with the land degradation.  相似文献   

区域水资源可持续利用的综合评价方法   总被引：8，自引：4，他引：8       下载免费PDF全文

宋松柏  蔡焕杰 《水科学进展》2005,16(2):244-249

水资源可持续利用指标体系及评价方法是水资源可持续利用研究的核心问题之一。以复合系统理论为基础,将水资源、社会经济和环境组成的复合系统定义为水资源可持续利用系统(RSWRS系统)。应用Bossel可持续发展基本定向指标框架,建立了水资源可持续利用指标评价体系。应用系统综合评价法,权重采用基于Bossel评分标准,以参考状态的离差平方和最大法计算,建立了以RSWRS系统发展综合指数和发展态势度量模型。以陕西省为例,进行了水资源可持续利用的综合定量评价。  相似文献   

Origin of fine-scale sheeted granites by incremental injection of magma into active shear zones: examples from the Pilbara Craton, NW Australia   总被引：1，自引：0，他引：1  

M. J. Pawley  W. J. Collins  M. J. Van Kranendonk 《Lithos》2002,61(3-4):127-139

In the Archaean Pilbara Craton of Western Australia, three zones of heterogeneous centimetre- to metre-scale sheeted granites are interpreted to represent high-level, syn-magmatic shear zones. Evidence for the syn-magmatic nature of the shear zones include imbricated and asymmetrically rotated metre-scale orthogneiss xenoliths that are enveloped by leucogranite sheets that show no significant internal strain. At another locality, granite sheets have a strong shape-preferred alignment of K-feldspar, suggesting magmatic flow, while the asymmetric recrystallisation of the grain boundaries indicates that non-coaxial deformation continued acting upon the sheets under sub-solidus conditions. Elsewhere, randomly oriented centimetre-wide leucogranite dykes are realigned at a shear zone boundary to form semi-continuous, layer-parallel sheets within a magma-dominated, dextral shear zone.

It is proposed that the granite sheets formed by the incremental injection of magmas into active shear zones. Magma was sheared during laminar flow to produce the sheets that are aligned sub-parallel to the shear zone boundary. Individual sheets are fed by individual dykes, with up to 1000s of discrete injections in an individual shear zone. The sheets often lack microstructural evidence for magmatic flow, either because the crystal content of the magma was too low to record internal strain, or because of later recrystallisation.  相似文献   

Participatory selection process for indicators of rangeland condition in the Kalahari   总被引：2，自引：0，他引：2  

Mark S Reed  & Andrew J Dougill 《The Geographical journal》2002,168(3):224-234

To develop indicator–based management tools that can facilitate sustainable natural resource management by non–specialists, meaningful participation of stakeholders is essential. A participatory framework is proposed for the identification, evaluation and selection of rangeland condition indicators. This framework is applied to the assessment of rangeland degradation processes and sustainable natural resource management with pastoralists in the southern Kalahari, Botswana. Farmer knowledge focused on vegetation and livestock, with soil, wild animal and socio–economic indicators playing a lesser role. Most were indicators of current rangeland condition; however 'early warning' indicators were also identified by some key informants. This demonstrates that some local knowledge is process–based. Such knowledge could be used to improve indicator–based management tools and extension advice on the livelihood adaptations necessary to prevent or reduce ecological change, capable of threatening livelihood sustainability. There is evidence that social background influences indicator use. Communal farmers rely most heavily on vegetation and livestock indicators, whilst syndicate and land–owning pastoralists cite wild animal and soil–based indicators most frequently. These factors must be considered if indicator–based management tools are to meet the requirements of a diverse community.  相似文献   

福建省海岸基岩节理的分形性质及其与宏观断裂系的关系   总被引：1，自引：0，他引：1  

刘晓曼  王建  朱敏  柏春广  朱晓华 《地理与地理信息科学》2003,19(6):101-103,111

该文以福建省福州市海岸基岩为例，通过野外实地勘测与室内分析相结合的研究方法，探讨了海岸基岩节理的分形性质及其与福建省宏观断裂系的相互关系。得到的基本结论为：第一，研究区节理与宏观断裂系的分形性质是客观存在的；第二，研究区节理与宏观断裂系在方向上存在着一定的响应关系；第三，研究区10^-2～10^-1m尺度的节理与福建省10^3～10^4m尺寸的断裂系存在一定的相似性。  相似文献