White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater     

Arthur F. Landymore  Naval J. Antia 《Marine Chemistry》1978,6(4):309-325

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).  相似文献   

半封闭海湾潮间带部分围垦后纳潮量计算的商榷——以胶州湾为例   总被引：14，自引：1，他引：14  

杨世伦  陈启明  朱骏  张经 《海洋科学》2003,27(8):43-47

传统的海湾(泻湖)纳潮量计算方法不能精确地反映潮间带被部分围垦后纳潮量的实际情况,本考虑围堤的影响,将纳潮量分解为堤基以下的“梯形”区和堤基以上的“矩形”区两部分之和,在理论上更加严密。根据改进后方法算出的胶州湾近期纳潮量比传统方法算出的纳潮量大15％左右。可见,半个多世纪以来胶州湾的纳潮量只减少了约15％．而不是传统方法得出的约25％。  相似文献   

鲫鱼(Carassius auratus)在微冻保鲜过程中的质量变化   总被引：2，自引：0，他引：2  

曾名勇  黄海  李玉环  黄叶锋 《中国海洋大学学报(自然科学版)》2001,31(3):351-355

该文研究鲫鱼 ( Carassius auratus)在微冻 ( - 3℃ )保鲜过程中的质量变化规律。以感官评价、细菌总数、T- VBN值、p H值、ATPase活性、K值等作为质量指标。实验结果表明 ,微冻可以明显抑制细菌总数的增长 ,维持较低的 T- VBN和 K值。但是 ,微冻条件下鲫鱼的 ATPase活性下降速度较快  相似文献   

A Functional Analysis of the Benthic Macrofauna of the São Sebastião Channel (Southeastern Brazil)     

Emilia Arasaki  Pablo Muniz  & Ana Maria S. Pires-Vanin 《Marine Ecology》2004,25(4):249-263

Abstract.  The major problem in coastal areas of developing countries is disturbance caused by anthropogenic influence. This disturbance can be quantified by analysing the distribution and composition of marine communities using uni- and multivariate techniques and the biotic index. A study of benthic macrofauna was carried out along the São Sebastião Channel, northern coast of São Paulo State, Brazil, in an area with a submarine outfall, a petroleum terminal and a commercial harbour. Sampling was undertaken seasonally, by means of a van Veen grab (0.1 m²) at 15 oceanographic stations, from November 1993 to August 1994. A total of 392 species were identified (129 Polychaeta, 127 Mollusca, 98 Crustacea, 28 Echinodermata and 10 other phyla). The sedimentary pattern recorded for the São Sebastião Channel is very heterogeneous, influenced mainly by strong wind-driven currents, and differs from nearby shelf areas. The study area could be divided into three regions based on sediment texture and fauna: one region dominated by medium and coarse sand with low values of organic carbon; a second area where pelitic fractions were dominant with high values of organic carbon and nitrogen; and a third region characterised by fine and very fine sand, presenting intermediate organic carbon values. No temporal significant variation in abundance and species composition was found, except in autumn. The use of the 'marine Biotic Coefficient' showed the same ecological trend as the faunal abundance and demonstrated that the central continental region of the channel is affected by human activities.  相似文献   

Using benthic macrofauna to assess environmental quality of four intertidal mudflats in Hong Kong and Shenzhen Coast   总被引：4，自引：0，他引：4  

Cai Lizhe  Nora F. Y. Tam  Teresa W. Y. Wong  Ma Li  Gao Yang  Yuk-Shan Wong 《海洋学报(英文版)》2003,22(2):309-319

Abstract-Intertidal zone is a significant wetland between land and ocean. It plays an important rolein maintaining local ecological balance. Both Mai Po and Futian intertidal mudflats are located in Shen-zhen Bay and are important "refueling" point along the East Asian/Australian flyway of migratory birds.The environmental quality of Mai Po and Futian mudflats have aroused great concern due to rapid eco-nomic developments in Hong Kong and Shenzhen in recent decades. Microinfauna of Mai Po and Futianmudflats was investigated in December 2000 and the faunal data were used to assess their environmentalquality. Two other mudflats, namely Ma Wan Typhoon Shelter (a more disturbed area) and Luk Kengintertidal mudflat (a place with relatively less human disturbance), were also sampled for macroinfaunaand used as reference mudflats. Shannon-Weaver species diversity index (I_(sd)), biotic coefficient (C_b)and macrofaunal pollution index (I_(mp)) of the macrofauna community on four intertidal mudflats wereused to  相似文献   

Determination of the Critical Value of Deflection for Embedded Cylindrical Structures     

刘建起陈滨  王海艳 《中国海洋工程》2005,19(3):519-528

An embedded cylinder is a large-diameter cylinder embedded in a soil foundation. The state of failure of such an embedded cylindrical structure shows large deflection instead of slide and overturn of the traditional gravity type of structure placed on a rubble base or foundation base. The critical value of deflection of the embedded cylindrical structure, which is the maximum allowable deflection for stability calculation of the cylinder, is a vital control value. Through investigation on deflection and soil pressures on an embedded cylinder by model experiments, the variations of the angle of rotation θ of a cylinder with effective anti-overturning ratio η and moment MH of thrust are discussed. On the basis of experimental study, the critical value of deflection of the cylindrical structure is proposed in the paper. Meanwhile, the formulas for calculating deflection of cylinders are derived.  相似文献   

Heavy metals in marine sediments of Taranto Gulf (Ionian Sea, Southern Italy)   总被引：5，自引：0，他引：5  

Alessandro Buccolieri  Giovanni Buccolieri  Nicola Cardellicchio  Angelo Dell'Atti  Antonella Di Leo  Antonella Maci 《Marine Chemistry》2006,99(1-4):227

Al, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Ti and Zn concentrations have been determined in surface sediment samples collected in the Taranto Gulf (Ionian Sea, Southern Italy) in order to evaluate their levels and spatial distribution in this important area of the Mediterranean Sea. For various metals, the geoaccumulation index has been calculated as a criterion to assess if their concentrations represent contamination levels or can be considered as background levels. The results show that metals concentrations in sediments can be considered near the background levels found in the Mediterranean Sea.Analytical results have been elaborated by using a Geographical Information System (GIS) software to show metals accumulation areas. Using multivariate statistical analysis, we evaluate the possibility to distinguish the sampling stations, in relation to their geographical position. Results have showed metals distribution in the Taranto Gulf is principally influenced by industrial and urban wastes, located mostly in the northern coastal area of the Ionian Sea. Rivers in the Basilicata region and prevailing anticlockwise marine currents are further factors influencing metal accumulation in sediments.  相似文献   

Coastal geomorphic evolution at the Denglou Cape, the Leizhou Peninsula     

Wang Lirong  Zhao Huanting  Song Chaojing  Yuan Jiayi  Yu Hongbing 《海洋学报(英文版)》2002,21(4):597-611

ＩＮＴＲＯＤＵＣＴＩＯＮＴｈｅＤｅｎｇｌｏｕＣａｐｅ ,ｉｎｔｈｅｓｏｕｔｈｗｅｓｔｏｆｔｈｅＬｅｉｚｈｏｕＰｅｎｉｎｓｕｌａ ,ｉｓａｔｔｈｅｎｏｒｔｈｍａｒｇｉｎｏｆｔｒｏｐｉｃａｌｚｏｎｅ .ＳｅｖｅｒａｌｒｅｓｅａｒｃｈｅｓａｎｄｃａｒｔｏｇｒａｐｈｉｅｓｏｆｔｈｅｒｅｇｉｏｎａｌｇｅｏｍｏｒｐｈｏｌｏｇｙａｎｄＱｕａｔｅｒ ｎａｒｙｇｅｏｌｏｇｙ ,ｗｈｉｃｈｗｅｒｅｃａｒｒｉｅｄｏｕｔｉｎｔｈｅｐａｓｔ,ａｌｌｉｎｃｌｕｄｅｔｈｉｓａｒｅａ (ＭＧＬ ,ＳＣＳＩＯ ,ＣＡＳ ,1 978;ＧＰＣＳＧＲＣＺＴ…  相似文献   

烟台套子湾八角深水港的开发研究     

戚立心  王全东 《海岸工程》1996,15(4):9-19

通过调查和比较，认为在我国渤海和北黄海南岸的套子湾八角海区是一个条件优越的深水港址，在阐述开发八角深水港的重要意义同时，根据城市布局规划和岸线及水域资源，参照国际港口未来发展趋势，结合我国对中、西部地区经济发展战略，对八角深水港的开发和布局进行了研究，为烟台市发展成为“现代化、国际型港口城市”，提出了港区未来建设的模式。  相似文献   

海洋植物营养素的应用研究　Ⅰ.金藻类的培养     

龙丽娟  孙恢礼  何伟宏 《热带海洋学报》1998,(1)

用不同含量的93－B型海洋植物营养素对几种常用的金藻类饵料种进行培养对比试验。结果表明,海洋植物营养素用于培养金藻类效果良好,最适使用含量为30mp·L~-1域40mg·L~-1。此时效果与通常被推荐的培养液所培养的对照组相当或更好．含量过高,则造成某些营养盐过量而产生一定的毒害作用。此营养素使用简便。  相似文献