Laser Ablation ICP-MS Developments and Trends for 2003     

Paul J. Sylvester 《Geostandards and Geoanalytical Research》2005,29(1):41-52

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.  相似文献   

The development of subgrain misorientations with strain in dry synthetic NaCl measured using EBSD   总被引：1，自引：0，他引：1  

G.M. Pennock  M.R. Drury  C.J. Spiers 《Journal of Structural Geology》2005,27(12):2159-2170

The development of subgrain boundary misorientations with strain in dry, synthetic NaCl polycrystals, deformed at elevated temperature, has been investigated using electron backscattered diffraction (EBSD). At low natural strains, up to 0.5, average misorientations of subgrain boundaries increase with strain and a power law relationship exists between strain and average misorientations. The average misorientations are strongly influenced by grain orientation, suggesting that the misorientation–strain relationship may also be texture dependent in materials with high plastic anisotropy, like NaCl. A slight grain size dependency of the average misorientations was observed. The results indicate that with suitable calibration, average subgrain boundary misorientations may offer a method for estimating the strain accommodated by dislocation creep in NaCl and thus perhaps in other geological materials, although current theories for polycrystalline plasticity imply that misorientations may also depend on stress in some situations.  相似文献   

Discussion on influence of cavern’s span on surrounding rock classification     

ZHOU Jian-min  JIN Feng-nian  WANG Bin  ZHAO Pei-sheng 《岩土力学》2005,26(Z1):303-305

The influence of cavern’s span on surrounding rock classification is getting more and more recognition along with large span underground working’s increasingly coming forth. The authors analyse the timbering expense of cavern in jointed rock mass, the radius of plastic loosened zone and the size effect of macroscopical mechanical parameters of rock mass. Based on the complexion of depressing of surrounding rock’s stability due to increment of cavern’s span, the authors pinpoint attaching importance to the influence of cavern’s span on surrounding rock classification; and suggest reckoning the factor of cavern’s span in surrounding rock classification scientifically by studying the size effect of rock mass’s physico-mechanical parameters.  相似文献   

Characterization of hydrogeologic properties for a multi-layered alluvial aquifer using hydraulic and tracer tests and electrical resistivity survey     

Jeong-Woo Kim  Heechul Choi  Jin-Yong Lee 《Environmental Geology》2005,48(8):991-1001

A multi-layered aquifer, typical of riverbank alluvial deposits in Korea, was studied to determine the hydrologic properties. The geologic logging showed that the subsurface of the study site was comprised of four distinctive hydrogeologic units: silt, sand, highly weathered and fresh bedrock layers. The electrical resistivity survey supplied information on lateral extension of hydrogeologic strata only partially identified by a limited number of the geologic loggings. The laboratory column tracer test for the recovered core of the sand layer resulted in a hydraulic conductivity of 5.00×10⁻² cm/s. The slug tests performed in the weathered rock layer yielded hydraulic conductivities of 4.32–7.72×10⁻⁴ cm/s. Hydraulic conductivities for the sand layer calculated from the breakthrough curves of bromide ranged between 2.08×10⁻³ and 2.44×10⁻² cm/s with a geometric mean of 6.89×10⁻³ cm/s, which is 7 times smaller than that from the laboratory column experiment. The trend of increasing hydraulic conductivity with an increase in tracer travel length is likely a result of the increased likelihood of encountering a high conductivity zone as more of the aquifer is tested. The combined hydrogeologic site characterization using hydraulic tests, tracer tests, and column test with geologic loggings and geophysical survey greatly enhanced the understanding of the hydrologic properties of the multi-layered alluvial aquifer.  相似文献   

兰州大学(盘旋路校区)2003年生态足迹调查分析   总被引：11，自引：2，他引：11  

蒋莉  陈治谏  沈兴菊 《地理与地理信息科学》2005,21(2):82-85

人均消费产品的数量是计算区域人均生态足迹关键和基础的一步。通过实地问卷调查，运用自下而上法收集资料，计算小尺度生态足迹。兰州大学(盘旋路校区)2003年的生态足迹计算结果为：人均生态足迹0．892hm^2，男、女生的人均生态足迹分别为0．976hm^2和0．788hm^2。这些数据与全国或者西部的人均生态足迹相比明显偏低，但总生态足迹为4119．3hm^2，是校园面积的73．7倍。因此，应合理利用自然资源，减少学生的生态足迹，真正做到可持续发展。  相似文献   

兰州市2001年沙尘气溶胶质量浓度的特征分析   总被引：11，自引：14，他引：11  

权建农  奚晓霞  王鑫  李杰  张镭 《中国沙漠》2005,25(1):93-97

 分析了2001年沙尘暴期间兰州与靠近沙尘源区的武威的沙尘浓度和粒径分布特征,并运用对数正态分布规律拟合了沙尘粒径的分布。通过对比武威、皋兰和兰州沙尘暴期间沙尘浓度的变化以及武威与兰州的沙尘粒径分布特征,揭示了河西走廊沙漠对兰州市沙尘暴的影响。  相似文献   

生态足迹模型在山区生态可持续评价中的初步应用--以1999年北京西部山区为例   总被引：3，自引：0，他引：3  

李红  张凤荣  孙丹峰  周连第 《山地学报》2005,23(5):636-640

在剖析生态足迹分析法的理论基础上，进一步考虑不同消费水平对生态足迹时空变异的影响，划分农村居民和城镇居民两类不同的消费群体，分别计算各自的生态足迹，其次进一步细化模型中人均水资源足迹，从而构建生态足迹与生态容量平衡模型。根据平衡模型计算出生态盈亏，得出区域生态持续性评价结果。并以1999年北京西部山区门头沟区为例，进行模型计算和生态可持续评价，结果表明1999年门头沟区处于生态赤字状态，说明该区生态系统处于不可持续状态。在对门头沟区的初步研究基础上，指出生态足迹作为山区生态可持续评价指标的优点及当前存在的缺点。  相似文献   

Facies analysis of the Middle and Late Quaternary sediment infill of the northern Weihe Basin,Central China          下载免费PDF全文

Daniël S. Rits  Maarten A. Prins  Simon R. Troelstra  Ronald T. van Balen  Yan Zheng  Christiaan J. Beets  Bin Wang  Xiaoqiang Li  Jie Zhou  Hongbo Zheng 《第四纪科学杂志》2016,31(2):152-165

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Postglacial variability in near‐bottom current speed on the continental shelf off south‐west Spitsbergen          下载免费PDF全文

BEATA STERNAL  WITOLD SZCZUCISKI  MATTHIAS FORWICK  MAREK ZAJĄCZKOWSKI  STANISŁAW LORENC  JOANNA PRZYTARSKA 《第四纪科学杂志》2014,29(8):767-777

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From soil aggregates to riverine flocs: a laboratory experiment assessing the respective effects of soil type and flow shear stress on particles characteristics          下载免费PDF全文

T. Grangeon  I. G. Droppo  C. Legout  M. Esteves 《水文研究》2014,28(13):4141-4155

Particles eroded from hillslopes and exported to rivers are recognized to be composite particles of high internal complexity. Their architecture and composition are known to influence their transport behaviour within the water column relative to discrete particles. To‐date, hillslope erosion studies consider aggregates to be stable once they are detached from the soil matrix. However, lowland rivers and estuaries studies often suggest that particle structure and dynamics are controlled by flocculation within the water column. In order to improve the understanding of particle dynamics along the continuum from hillslopes to the lowland river environment, soil particle behaviour was tested under controlled laboratory conditions. Seven flume erosion and deposition experiments, designed to simulate a natural erosive event, and five shear cell experiments were performed using three contrasting materials: two of them were poorly developed and as such can not be considered as soils, whilst the third one was a calcareous brown soil. These experiments revealed that soil aggregates were prone to disaggregation within the water column and that flocculation may affect their size distribution during transport. Large differences in effective particle size were found between soil types during the rising limb of the bed shear stress sequence. Indeed, at the maximum applied bed shear stress, the aggregated particles median diameter was found to be three times larger for the well‐developed soil than for the two others. Differences were smaller in the falling limb, suggesting that soil aggregates underwent structural changes. However, characterization of particles strength parameters showed that these changes did not fully turn soil aggregates into flocs, but rather into hybrid soil aggregate–floc particles. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献