Chemistry of marine resources-ⅩⅨ. The molecule design and synthesis of crow-link type alkyd resin and its enrichment behaviour for potassium ion in sea water     

Sun Yushan  Feng Fei  Sun Hanzhang  Peng Qiqiang  Xia Zongfeng  Wang Wei 《海洋学报(英文版)》1994,13(3):377-388

This paper first presents the molecule design and synthesis of crown-link type alkyd resin,and its enrichment behaviour for potassium ion in low concentration solution and sea water.On the basis of some theory concepts of Host-Guest chemistry developed in recent years,we have designed and synthesized a new polymer enrichment agent of crow-link resin for potassiumion,i.e.,polymacrocyclic ether bislactone of diethylene glycolpyromyllitic acid(briefly called crown-link type alkyd resin or PBL resin).The yield was about 97.4%,almost quantitatively.  相似文献   

海洋钙离子非保守行为及海洋钙问题     

曹知勉  戴民汉 《地球科学进展》2008,23(1):8-16

钙离子是海洋11种常量离子之一,与钠、钾等离子的保守性不同,钙离子在海洋中的分布表现出微小但系统的变化。钙离子的变化往往与海洋碳酸钙的形成和溶解过程有关,所以,钙离子可直接指示海洋碳酸钙通量（深层海洋碳通量的主要组成部分）。同时,碳酸钙沉淀或溶解又会改变总碱度和溶解无机碳,通过钙离子变化也能间接探讨海洋碳酸盐系统和海洋吸收CO2的能力。介绍了以碳酸钙溶解形成超额钙为主的海洋钙离子多种非保守行为及其控制过程,讨论这些过程对海水组成和海洋碳酸盐系统的影响,探讨未来海洋酸化条件下钙离子可能的变化及其潜在的效应,最后展望在南海开展钙离子精细行为的研究意义。   相似文献   

新疆罗布泊盐湖卤水资源综合开发研究   总被引：10，自引：3，他引：7  

李浩  唐中凡  刘传福  雷光元 《地球学报》2008,29(4):517-524

罗布泊盐湖赋存有丰富的含钾硫酸镁亚型卤水,现已探明仅罗北凹地区段孔隙度储量2.67×109t(折合KCl),属特大型钾盐卤水矿藏,是生产硫酸钾的理想原料;此外,卤水中含有丰富的钠、镁、锂、硼等资源,综合回收利用价值较大。本文针对罗布泊盐湖卤水资源,在有效利用盐湖钾资源同时,加快其他共生资源的综合开发进程,将新疆罗布泊盐湖资源开发建设推向持续、合理、有效、高值的循环经济发展的道路,为国家西部经济开发做出贡献。  相似文献   

Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

新疆第四纪盐类矿产的形成和控制因素——兼论“高山深盆”成盐模式   总被引：1，自引：0，他引：1  

王得林 《新疆地质》1993,(1)

根据袁见齐教授“高山深盆”成盐模式,探讨新疆天山对第四纪盐类矿床的形成和控制作用,阐述了天山地貌、气候、水文特征与盐类矿产的分布规律和特征。认为“高山深盆”并非一定是四周环山的深盆,可以是某一高山与其间深盆或两侧盆地的有机组合。高山的屏障作用造成了垂直的气候分带,在潮湿多雨的山区利于成盐组份的析出并迁移到干旱少雨的闭流深盆中,形成盐类矿床。  相似文献   

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨     

付伟  赵芹  罗鹏  李佩强  陆济璞  周辉  易泽邦  许成 《地质学报》2022,96(11):3901-3923

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。  相似文献   

全谱直读等离子发射光谱法直接测定天然矿泉水中的SO2-4   总被引：2，自引：0，他引：2  

查立新  刘洪青  马玲  戴先蓉 《安徽地质》2002,12(1):75-77

采用全谱直读等离子发射光谱(ICP-AES)直接测定天然矿泉水中SO2-4的方法在优化工作条件下SO42-的测定下限为0.09mgL-1,方法简便,快速,适用于批量生产.  相似文献   

Lithium and lithium isotope profiles through the upper oceanic crust: a study of seawater-basalt exchange at ODP Sites 504B and 896A     

Lui-Heung Chan  Jeffrey C Alt 《Earth and Planetary Science Letters》2002,201(1):187-201

Ocean Drilling Program (ODP) Hole 504B near the Costa Rica Rift is the deepest hole drilled in the ocean crust, penetrating a volcanic section, a transition zone and a sheeted dike complex. The distribution of Li and its isotopes through this 1.8-km section of oceanic crust reflects the varying conditions of seawater alteration with depth. The upper volcanic rocks, altered at low temperatures, are enriched in Li (5.6-27.3 ppm) and have heavier isotopic compositions (δ⁷Li=6.6-20.8‰) relative to fresh mid-ocean ridge basalt (MORB) due to uptake of seawater Li into alteration clays. The Li content and isotopic compositions of the deeper volcanic rocks are similar to MORB, reflecting restricted seawater circulation in this section. The transition zone is a region of mixing of seawater with upwelling hydrothermal fluids and sulfide mineralization. Li enrichment in this zone is accompanied by relatively light isotopic compositions (−0.8-2.1‰) which signify influence of basalt-derived Li during mineralization and alteration. Li decreases with depth to 0.6 ppm in the sheeted dike complex as a result of increasing hydrothermal extraction in the high-temperature reaction zone. Rocks in the dike complex have variable isotopic values that range from −1.7 to 7.9‰, depending on the extent of hydrothermal recrystallization and off-axis low-temperature alteration. Hydrothermally altered rocks are isotopically light because ⁶Li is preferentially retained in greenschist and amphibolite facies minerals. The δ⁷Li values of the highly altered rocks of the dike complex are complementary to those of high-temperature mid-ocean ridge vent fluids and compatible to equilibrium control by the alteration mineral assemblage. The inventory of Li in basement rocks permits a reevaluation of the role of oceanic crust in the budget of Li in the ocean. On balance, the upper 1.8 km of oceanic crusts remains a sink for oceanic Li. The observations at 504B and an estimated flux from the underlying 0.5 km of gabbro suggest that the global hydrothermal flux is at most 8×10⁹ mol/yr, compatible with geophysical thermal models. This work defines the distribution of Li and its isotopes in the upper ocean crust and provides a basis to interpret the contribution of subducted lithosphere to arc magmas and cycling of crustal material in the deep mantle.  相似文献   

单道扫描电感耦合等离子体发射光谱法测定地质样品中的微量稀土元素     

郭振华  张立英  杜百娟 《化工矿产地质》2003,25(1):57-60

采用Na_2O_2熔融矿样,水提取,加三乙醇胺、EGTA做掩蔽剂。经氢型阳离子交换树脂交换分离富集稀土元素,由于选择了合适的仪器条件及测定波长,有效地消除了电感耦合等离子体发射光谱法(ICP-AES)测定过程中的基体干扰和光谱干扰。应用于地质样品中的稀土元素分析,获得了满意的准确度、精密度及检出限。  相似文献   

Focused ion beam technique and transmission electron microscope studies of microdiamonds from the Saxonian Erzgebirge, Germany     

Larissa F. Dobrzhinetskaya  Harry W. Green  Matthew Weschler  Mark Darus  Young-Chung Wang  Hans-Joachim Massonne  Bernhard St  ckhert 《Earth and Planetary Science Letters》2003,210(3-4):399-410

A focused ion beam of Ga ions is a relatively new technique that has been developed for microelectronic industries. Now researchers of the Earth sciences find it to be a promising tool for studying various geological materials. Using the FIB technique and an FEI Strata DB 235 dual beam system, we have successfully prepared several electron-transparent foils, which crossed μm-sized diamonds included in host minerals such as zircon and garnet from quartzofeldspathic rocks of the Saxonian Erzgebirge, Germany. Scanning and transmission electron microscopy applied to these foils revealed that the diamonds contain crystalline nanometric inclusions. These inclusions consist of minerals of known stoichiometries such as SiO₂ and Al₂SiO₅, whereas others are characterized by different combinations of Si, K, P, Ti, and Fe in the presence of oxygen (stoichiometries are not clear at this stage of research). One suite of inclusions is assumed to be represented by archerite, KH₂PO₄, which is known to be stable at pressures of 4–22 GPa, and one nanocrystal containing Pb, oxygen and carbon is interpreted to be Pb_xO_y or PbCO₃. Along with solid crystalline inclusions, the diamonds contain cavities filled by liquid/gas that escaped during sample preparation. These are associated with dislocations of diamond growth. Our data are consistent with the concept of diamond crystallization from a COH-rich multicomponent supercritical fluid and suggest that the composition of such a fluid is more consistent with a local crustal source rather than that of a mantle origin.  相似文献