加氢和TSR反应对天然气同位素组成的影响   总被引：2，自引：1，他引：2  

刘文汇  张殿伟王晓锋 《岩石学报》2006,22(8):2237-2242

天然气形成过程中的加氢作用和 TSR 反应是有机-无机相互作用的重要方式。相邻水体和深部来源的氢,是天然气形成的重要氢源,塔里木盆地天然气的甲烷氢同位素组成明显表现出不同沉积水体对甲烷氢同位素的控制作用,大宛105～25井和阿克1井具有深部流体加氢的特征;TSR 反应中硫同位素在不同反应阶段和反应过程具有不同的分馏特征,这种特征在四川盆地高舍硫天然气中具有很好的表现,TSR 反应硫同位素分馏一般小于20‰,而单体硫、黄铁矿和硫酸盐矿物等其它反应过程的产物硫同位素分馏不明显。  相似文献   

GMS多通道资料综合判别可降水云   总被引：2，自引：1，他引：1  

刘文  边道相  张苏平 《气象》1998,24(2):24-26

利用１９９５年７～１０月影响山东的１２次降水天气过程３７０个时次的ＧＭＳ－５卫星云图,以及对应时次全省９５个雨量观测站自记降水资料,统计分析了静止气象卫星各通道资料与降水概率的关系。探讨了静止气象卫星云图综合识别可降水云的方法。  相似文献   

Solar activity effects in the ionospheric D region   总被引：2，自引：0，他引：2  

A. D. Danilov 《Annales Geophysicae》1998,16(12):1527-1533

Variations in the D-region electron concentration within the solar activity cycle are considered. It is demonstrated that conclusions of various authors, who have analyzed various sets of experimental data on [e], differ significantly. The most reliable seem to be the conclusions based on analysis of the [e] measurements carried out by the Faraday rotation method and on the theoretical concepts on the D-region photochemistry. Possible QBO effects in the relation of [e] to solar activity are considered and an assumption is made that such effects may be the reason for the aforementioned disagreement in conclusions on the [e] relation to solar indices.Paper Presented at the Second IAGA/ICMA (IAMAS) Workshop on Solar Activity Forcing of the Middle Atmosphere, Prague, August 1997  相似文献   

On the application of the classic Kessler and Berry schemes in Large Eddy Simulation models with a particular emphasis on cloud autoconversion, the onset time of precipitation and droplet evaporation     

S. Ghosh  P. R. Jonas 《Annales Geophysicae》1998,16(5):628-637

Many Large Eddy Simulation (LES) models use the classic Kessler parameterisation either as it is or in a modified form to model the process of cloud water autoconversion into precipitation. The Kessler scheme, being linear, is particularly useful and is computationally straightforward to implement. However, a major limitation with this scheme lies in its inability to predict different autoconversion rates for maritime and continental clouds. In contrast, the Berry formulation overcomes this difficulty, although it is cubic. Due to their different forms, it is difficult to match the two solutions to each other. In this paper we single out the processes of cloud conversion and accretion operating in a deep model cloud and neglect the advection terms for simplicity. This facilitates exact analytical integration and we are able to derive new expressions for the time of onset of precipitation using both the Kessler and Berry formulations. We then discuss the conditions when the two schemes are equivalent. Finally, we also critically examine the process of droplet evaporation within the framework of the classic Kessler scheme. We improve the existing parameterisation with an accurate estimation of the diffusional mass transport of water vapour. We then demonstrate the overall robustness of our calculations by comparing our results with the experimental observations of Beard and Pruppacher, and find excellent agreement.  相似文献   

The morphology of oxygen greenline dayglow emission     

S. Tyagi  V. Singh 《Annales Geophysicae》1998,16(12):1599-1606

In this study, the morphology of the oxygen greenline dayglow emission is presented. The volume emission rate profiles are obtained by using Solomons glow model. The glow model is updated in terms of recent cross sections, reaction rate coefficients and quantum yield of greenline emission. Throughout most of the thermosphere the modelled and observed emission rates are in reasonably good agreement. In the region between 98 and 120 km, the modelled emission rates are substantially higher (about a factor of 1.7) than the observed emission rates. This discrepancy is discussed in terms of scaling of solar fluxes which accounts the variation of solar activity for the day on which calculations are made. The modelled morphology of greenline emission is compared with those cases where WINDII data is available. The modelled and observed morphology is in reasonably good agreement at most of the latitudes above 120 km. In the mesosphere the qualitative nature of morphology is very similar to those of WINDII observation except the modelled emission rates are about a factor of 1.7 higher than the observed emission rates.  相似文献   

Development of a chemistry module for GCMs: first results of a multiannual integration     

B. Steil  M. Dameris  C. Brühl  P. J. Crutzen  V. Grewe  M. Ponater  R. Sausen 《Annales Geophysicae》1998,16(2):205-228

The comprehensive chemistry module CHEM has been developed for application in general circulation models (GCMs) describing tropospheric and stratospheric chemistry, including photochemical reactions and heterogeneous reactions on sulphate aerosols and polar stratospheric clouds. It has been coupled to the spectral atmospheric GCM ECHAM3. The model configuration used in the current study has been run in an –off-line mode, i.e. the calculated chemical species do not affect the radiative forcing of the dynamic fields. First results of a 15-year model integration indicate that the model ECHAM3/CHEM runs are numerically efficient and stable, i.e. that no model drift can be detected in dynamic and chemical parameters. The model reproduces the main features regarding ozone, in particular intra- and interannual variability. The ozone columns are somewhat higher than observed (approximately 10%), while the amplitude of the annual cycle is in agreement with observations. A comparison with HALOE data reveals, however, a serious model deficiency regarding lower-stratosphere dynamics at high latitudes. Contrary to what is concluded by observations, the lower stratosphere is characterized by slight upward motions in the polar regions, so that some of the mentioned good agreements must be considered as fortuitous. Nevertheless, ECHAM3/CHEM well describes the chemical processes leading to ozone reduction. It has been shown that the mean fraction of the northern hemisphere, which is covered by polar stratospheric clouds (PSCs) as well as the temporal appearance of PSCs in the model, is in fair agreement with observations. The model results show an activation of chlorine inside the polar vortex which is stronger in the southern than in the northern winter hemisphere, yielding an ozone hole over the Antarctic; this hole, however, is also caused to a substantial degree by the dynamics. Interhemispheric differences concerning reformation of chlorine reservoir species HCl and ClONO₂ in spring have also been well reproduced by the model.  相似文献   

Extrapolating EISCAT Pedersen conductances to other parts of the sky using ground-based TV auroral images     

M. J. Kosch  T. Hagfors  K. Schlegel 《Annales Geophysicae》1998,16(5):583-588

Ionospheric conductivity is not very easily measured directly. Incoherent scatter radars perhaps offer the best method but can only measure at one point in the sky at any one time and are limited in their time resolution. Statistical models of average conductivity are available but these may not be applied to individual case studies such as substorms. There are many instances where a real-time estimate of ionospheric conductivity over a large field-of-view is highly desirable at a high temporal and spatial resolution. We show that it is possible to make a reasonable estimate of the noctural height-integrated Pedersen conductivity, or conductance, with a single all-sky TV camera operating at 557.7 nm. This is not so in the case of the Hall conductance where at least two auroral wavelengths should be imaged in order to estimate additionally the energy of the precipitating particles.  相似文献   

Effects of geomagnetic activity on the mesospheric electric fields     

A. M. Zadorozhny  A. A. Tyutin 《Annales Geophysicae》1998,16(12):1544-1551

The results of three series of rocket measurements of mesospheric electric fields carried out under different geomagnetic conditions at polar and high middle latitudes are analysed. The measurements show a clear dependence of the vertical electric fields on geomagnetic activity at polar and high middle latitudes. The vertical electric fields in the lower mesosphere increase with the increase of geomagnetic indexes K_p and K_p. The simultaneous increase of the vertical electric field strength and ion conductivity was observed in the mesosphere during geomagnetic disturbances. This striking phenomenon was displayed most clearly during the solar proton events of October, 1989 accompanied by very strong geomagnetic storm (K_p = 8+). A possible mechanism of generation of the vertical electric fields in the mesosphere caused by gravitational sedimentation of charged aerosol particles is discussed. Simultaneous existence in the mesosphere of both the negative and positive multiply charged aerosol particles of different sizes is assumed for explanation of the observed V/m vertical electric fields and their behaviour under geomagnetically disturbed conditions.Paper Presented at the Second IAGA/ICMA (IAMAS) Workshop on Solar Activity Forcing of the Middle Atmosphere, Prague, August 1997  相似文献   

Noble gas components in planetary atmospheres and interiors in relation to solar wind and meteorites     

K. Marti  K. J. Mathew 《Journal of Earth System Science》1998,107(4):425-431

We discuss observed xenon isotopic signatures in solar system reservoirs and possible relationships. The predominant trapped xenon component in ordinary chondrites (OC) is OC-Xe and its isotopic signature differs from Xe in ureilites, in carbonaceous chondrites, in the atmospheres of Earth and Mars, and in the solar wind. Additional minor Xe components were identified in type 3 chondrites and in the metal phase of chondrites. The OC-Xe and ureilite signatures are both consistent with varying mixtures of HL-Xe and slightly mass fractionated solar-type Xe. Xenon in the Martian atmosphere is found to be strongly mass fractionated by 37.7‰ per amu, relative to solar Xe, favoring the heavy isotopes. Xenon in SNC’s from the Martian mantle show admixture of solar-type Xe, which belongs to an elementally strongly fractionated component. The origin of the isotopic signatures of Ne and Xe in the terrestrial atmosphere are discussed in the light of evidence that the Xe isotopic fractionations in the Martian and terrestrial atmospheres are consistent. However, in the terrestrial atmospheric Xe component excesses are observed for¹³²Xe and also for^129,131Xe, relative to fractionated solar Xe. The suggested chemically fractionated fission Xe component (CFF-Xe) seems to closely match the above excesses. We discuss models of origin for planetary volatiles and possible processes driving their evolution to present day compositions.  相似文献   

四川开江恐龙骨骼化石矿物组分分离和微量元素组合的研究   总被引：2，自引：0，他引：2  

张玉光  李奎  蔡开基 《沉积与特提斯地质》1998,18(4):49-56

文章详述了恐龙骨骼化石矿物组分的化学分离方法,同时对开江恐龙骨骼化石样品进行了分离和中子活化分析,通过对测试结果进行生物地球化学的对比研究,发现恐龙骨骼化石中某些微量元素异常明显,并推断其中的砷（Ａｓ）、铬（Ｃｒ）、铷（Ｒｂ）的高异常含量和锌（Ｚｎ）的低异常含量极有可能是导致开江恐龙动物群集群死亡的原因之一。  相似文献