顺序扫描 ICP-AES法测定高纯石墨灰分中14种杂质金属元素的方法研究   总被引：1，自引：0，他引：1  

张爱滨  魏进武  王燕  欧阳秀欢  李静 《中国海洋大学学报(自然科学版)》2003,33(4):609-614

本文研究了快速测定石墨灰分中14种杂质元素Al,Ca,Cd,Co,Cr,Cu,Fe,Mg,Mn,Mo,Ni,Ti,V,Zn的分析方法,以满足提纯石墨研究工作对快速了解石墨提纯效果的要求.依据测定样品中各元素的含量情况,实验选择14种元素的分析线.运用ICP-AES谱线轮廓图功能,消除常量元素产生的基体背景干扰.运用干扰系数法进行测定结果校正,并对ICP-AES测定灰分中14种元素的检出线、精密度、准确度进行了测定.结果显示,本方法分析石墨灰分中杂质元素能够满足提纯石墨研究工作的要求.  相似文献   

The vibration of a large ring-stiffened prolate dome under external water pressure     

Carl T.F. Ross  Andrew P.F. Little  Colin Bartlett 《Ocean Engineering》2004,31(1):1-19

The paper presents a theoretical and an experimental investigation into the free vibration of a large ring-stiffened prolate dome in air and under external water pressure.The theoretical investigation was via the finite element method where a solid fluid mesh with an isoparametric cross-section was used to model the water surrounding the dome, and a truncated conical shell and ring stiffener were used to model the structure. Good agreement was found between theory and experiment. Both the theory and the experiment found that as the external water pressure was increased the resonant frequencies decreased.  相似文献   

福建福宁湾表层沉积物中甲藻孢囊分布与多样性研究     

王朝晖  郑虎  王文婷  谢昌良  暨双辉  张宇宁 《海洋与湖沼》2022,53(6):1396-1404

孢囊是甲藻生活史中特殊的休眠阶段,被认为是赤潮发生的种源。于2018年4月采集了福建福宁湾海域表层沉积物,对沉积物中甲藻孢囊的分布规律进行了研究,重点揭示有毒有害甲藻孢囊的分布;同时测定了沉积物中生源要素含量,以揭示孢囊分布与生源要素的关系。共鉴定甲藻孢囊25种,其中别什藻(Biecheleria tirezensis)孢囊占据优势。孢囊的种类多样性指数(H'')偏低,为2.06~2.34;均匀度指数(J)为0.71~0.81。孢囊密度介于178.6~386.3 cysts/g (以干重计,下同),平均为286.0cysts/g。孢囊密度高值区位于水深较深、沉积物颗粒较细的长表岛外海域,而低值区则位于长表岛至海尾角的近岸海域。值得注意的是,研究分析鉴定出9种有毒有害甲藻的孢囊,包括麻痹性贝类毒素(paralytic shellfish poisoning,PSP)原因种奥氏亚历山大藻(Alexandrium ostenfeldii)和链状/塔玛亚历山大藻(Alexandrium catenella/tamarense)孢囊复合体、goniodomine A原因种平野亚历山大藻(Alexandrium hiranoi)、虾夷扇贝毒素(yessotoxin,YTX)原因种具刺膝沟藻(Gonyaulax spinifera)和网状原角藻(Protoceratium reticulatum)、产生鱼毒素的哈曼褐多沟藻(Pheopolykrikos hartmannii)以及赤潮藻类Barrufeta bravensis、锥状斯氏藻(Scrippsiella acuminata)和垂裂莱万藻(Levanderina fissa),其中Barrufeta bravensis、Gonyaulax spinifera和Scrippsiella acuminata的孢囊分布广泛且密度较高,需引起关注。  相似文献   

Spatial and vertical distributions of elements in sediments of the Colorado River delta and Upper Gulf of California   总被引：1，自引：0，他引：1  

Evgueni N. Shumilin  Jos D. Carriquiry  Víctor F. Camacho-Ibar  Dmitry Sapozhnikov  Stepan Kalmykov  Alberto Snchez  Sergio Aguíiga-García  Yuri A. Sapozhnikov 《Marine Chemistry》2002,79(3-4)

The abundance of major components (Fe, Ca, K, and organic carbon) and trace elements was analyzed in surface sediments and core samples from the Colorado River delta (CRD) and the Upper Gulf of California (UGC) using instrumental neutron activation analysis.The spatial distribution patterns of the elements studied are consistent with the model of sedimentary dynamics proposed for this area [Mar. Geol. 158 (1999) 125]: intense tidal resuspension of sediments in the delta with subsequent transport of suspended particulate matter in a southerly direction, followed by sedimentation of fine-grained material in a depocenter near the southwestern margin of the UGC. Concentrations of most of the elements are higher in the surface sediments of this depocenter. The gradual mixing of terrigenous and marine biogenic materials, normally expected for the estuarine sediments, was not detected in the CRD–UGC system because of homogenization of the sediments by tides and wind.Vertical profiles of element contents in samples of the sediment core collected in the depocenter area revealed (i) almost no anthropogenic contamination of the area by environmentally important trace elements such as Cr, Co, Sb, and As; (ii) a twofold decrease of Fe, Sc, Cr, and Co in upper core sediments; and (iii) the enrichment of the sediments at 60–62 cm depth in the core, in calcium carbonate, Ca, Sr, and the Eu_n/Sm_n shale-normalized ratio along with a depletion in this layer of Fe, Sc, Cr, Co, light rare-earth elements (REEs), and some other elements of terrigenous origin, presumably caused by the dilution of fluvial terrigenous material by biogenic carbonates, which were probably introduced at this level in the sediments by the action of a strong episodic winter storm, followed by the advective transport of shell fragments from the coastal clam banks or as a result of strong planktonic bloom.  相似文献   

渤海湾表层沉积物的中子活化分析   总被引：1，自引：0，他引：1  

李培泉  卢光山  扈治安 《海洋科学》1990,14(4):23-28

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Features of Monsoon, Typhoon and Sea Waves in the Taiwan Strait     

Chuankun Wang 《Marine Georesources & Geotechnology》2004,22(3):133-150

For Future cross-sea passage spanning the Taiwan Strait, no matter what kind of scheme is adopted, its design, construction, and administration are closely related to marine hydrological and meteorological environmental elements. In this article, based on a great number of observed data, analyses for wave, typhoon, and monsoon conditions in the Taiwan strait region are made and their distributional features and character values are given. Especially, the wave height and occurrence frequencies of disastrous waves are analyzed, and the values of design wave parameters (wave height and period with a given return period) are estimated to use for the reference of the scheme optimization and project preliminary program of cross-sea passage spanning the strait.  相似文献   

The buckling of GRP hemi-ellipsoidal dome shells under external hydrostatic pressure     

C. T. F. Ross  Bak Hock Huat  Tay Boon Chei  Chai Min Chong  M. D. A. Mackney 《Ocean Engineering》2003,30(5):691-705

The paper reports on a theoretical and an experimental investigation into six GRP hemi-ellipsoidal dome shells, which were tested to destruction under external hydrostatic pressure. All six domes were of oblate shape and of three different aspect ratios. Each aspect ratio consisted of two dome shells, one made from two layers of glass fibre and one made from three layers of glass fibre. The theoretical analysis was via the finite element method where a non-linear theory was used which allowed for both geometrical and material non-linearity. Comparison between theory and experiment was good.  相似文献   

Rare earth elements-rich phase and enriching mechanism in sediments from CC area, the Pacific Ocean   总被引：1，自引：0，他引：1  

Meng Xianwei  Chen Zhihu  Wang Xiangqin  Liu Na 《海洋学报(英文版)》2001,20(2):209-214

Compared to North American shale composition (NASC),REE contents of sediments from the CC area in the Pacific Ocean are obviously high except that cerium has equal content to that of NASC.Three-valence rare earth elements were completely enriched in phosphate-phase and cerium in iron-phase.Rare earth elements in the sediments were originally derived from seawater.During lithigenic and minerogenic processes of metalliferous nodules,three-valence rare earth elements in sediments mobilized and incorporated into sediments as authigenous biogenic-apatite,while cerium had change from Ce³⁺ to Ce⁴⁺ and directly precipitated from seawater and entered metalliferous nodules and caused Ceanomalies in REE pattern in sediments.  相似文献   

Possible evidence for enrichment of trace elements in the hydrous manganese oxide phases of suspended matter from an urbanized embayment     

Richard A. Feely  Gary J. Massoth  Anthony J. Paulson  James F. Gendron 《Estuarine, Coastal and Shelf Science》1983,17(6):693-708

Total and weak-acid-soluble trace elements in suspended matter from the Duwamish River and Elliott Bay were determined from samples collected in February and September 1980. The results indicate that Mn scavenging in the water column is coincident with enrichments of Cr, Ni, Cu, Zn, and Pb in the suspended matter, suggesting a possible enrichment of these trace elements in a hydrous Mn oxide phase. This process occurs primarily in the sub-surface waters of Elliott Bay. Since mass balance calculations show a net export of Mn out of the bay, this mechanism may be an important means of transporting toxic trace metals from polluted estuaries and embayments to cleaner coastal environments.  相似文献   

Uptake of platinum group elements by the marine macroalga, Ulva lactuca     

Andrew Turner  Marie S. Lewis  Leyla Shams  Murray T. Brown 《Marine Chemistry》2007,105(3-4):271-280

Uptake of environmentally relevant platinum group elements (PGE) by the marine macroalga, Ulva lactuca, has been studied. Removal of nM concentrations of Rh(III), Pd(II) and Pt(IV) added to filtered sea water appeared to proceed via pseudo-first-order kinetics, with respective forward rate constants of either 0.0039 or 0.0042 h^− 1, 0.0058 or 0.0096 h^− 1 and 0.0017 or 0.0032 h^− 1, depending on whether an irreversible or reversible reaction was invoked. The (quasi-) equilibrium distribution coefficients, derived from linear fits to uptake (sorption) isotherms, were about 1400, 900 and 350 mL g^− 1 on a dry mass basis for Rh, Pd and Pt, respectively. With increasing sea water pH, over the range 7.9 to 8.4, uptake of Rh by Ulva increased considerably, whereas a small increase in Pt removal was observed; in contrast, uptake of Pd exhibited no clear dependence on pH. The percentage of metal taken up that was internalised within cells, evaluated by washing selected algal samples in 3 mM EDTA, was about 40% for Rh, 80% for Pd and 95% for Pt. Results of this study were interpreted in terms of what is known about the aqueous speciation of PGE in sea water. Thus, Rh exists as cationic hydrated chloride complexes which are readily adsorbed at the algal surface. Palladium has an exceptional affinity for organic ligands, and uptake (and internalisation) appears to be governed by competition for Pd²⁺ from aqueous and algal binding sites. Platinum (IV) exists predominantly as a series of (mainly) negatively charged chloride and mixed hydroxychloride complexes that have little propensity to interact with the algal surface; however, its high degree of internalisation requires at least some interaction with specific and perhaps physiologically active sites.  相似文献