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21.
Carbonyl products have been identified and their formation yields measured in experiments involving the gas phase reaction of ozone with 1,1-disubstituted alkenes at ambient T and p=1 atm. of air. Sufficient cyclohexane was added to scavenge the hydroxyl radical in order to minimize OH-alkene and OH-carbonyl reactions. Formation yields (carbonyl formed/ozone reacted) of primary carbonyls were close to the value of 1.0 that is consistent with the mechanism: O3+R1R2C=CH2 (HCHO+R1R2COO)+(1–)(R1COR2+H2COO) where formaldehyde and the ketone R1 COR2 are the primary carbonyls and R1R2COO and H2COO are the corresponding biradicals. Measured values of were 0.58–0.82 and indicate modest preferential formation of formaldehyde and the disubstituted biradical as compared to the ketone and the biradical H2COO. Carbonyls other than the primary carbonyls were identified. Their formation is discussed in terms of subsequent reactions of the disubstituted biradicals R1R2COO. Similarities and differences between disubstituted and monosubstituted biradicals are outlined. 相似文献
22.
Bruce A. Callander 《GeoJournal》1997,42(1):55-63
IPCCs statement in its 1995 report (IPCC 1996) that a human influence was discernible in global climate has been widely quoted but often misunderstood. The character of the evidence underpinning this detection statement is explained so that its strengths and weaknesses can be better understood and the subtleties of its message better appreciated. To demonstrate the close linkage between the government-approved summary and the underlying chapters of the IPCC report the detailed evolution of the detection statement from first draft through to the form finally approved by the IPCC is described. 相似文献
23.
Günter Helas Jürgen Lobert Dieter Scharffe Luise Schäfer Johann Goldammer Jean Baudet Brou Ahoua Ayité-Lô Ajavon Jean-Pierre Lacaux Robert Delmas Meinrat O. Andreae 《Journal of Atmospheric Chemistry》1995,22(1-2):163-174
Ozone has been observed in elevated concentrations by satellites over areas previously believed to be background. There is meteorological evidence, that these ozone plumes found over the Atlantic Ocean originate from vegetation fires on the African continent.In a previous study (DECAFE-88), we have investigated ozone and assumed precursor compounds over African tropical forest regions. Our measurements revealed large photosmog layers at altitudes from 1.5 to 4 km. Both chemical and meteorological evidence point to savanna fires up to several thousand km upwind as sources.Here we describe ozone mixing ratios observed over western Africa and compare ozone production ratios from different field measurement campaigns related to vegetation burning. We find that air masses containing photosmog ingredients require several days to develop their oxidation potential, similar to what is known from air polluted by emissions from fossil fuel burning. Finally, we estimate the global ozone production due to vegetation fires and conclude that this source is comparable in strength to the stratospheric input. 相似文献
24.
Hajduk, et al (1992) have drawn attention to a possible source of error in our earlier analysis of visual and radar observations of shower meteors from which we calculated the ozone concentration at meteor heights. We have considered their main criticism that the features of our data which we used to calculate the ozone concentration may have been due to the constraint that our meteors had to be observed by both methods. We have shown that observations collected from radar-only systems show very similar characteristics and that these can be analysed without recourse to visual data to produce very similar results to those from our original analysis.
Presented at theInternational Conference on Meteoroids 23 – 31 August 1994 in Bratislava.Submitted to Earth, Moon and Planets 相似文献
25.
F. Carrier B. Bourdon . Pili C. Truffert R. Wyns 《Journal of Geochemical Exploration》2006,88(1-3):266
Airborne gamma-ray spectrometry data (uranium, potassium and thorium contents) reveal geochemical heterogeneities within the monolithological Hyrôme watershed (ca. 150 km2) in the Armorican massif (western France). Our observations and computations provide important constraints on the spatial distribution and the associated magnitudes of chemical erosion processes at the scale of a small watershed. Two distinct, partially preserved, weathering profiles exhibit a strong correlation between regolith evolution and airborne-derived K/Th ratios, suggesting that the variability is linked to supergene processes. Using both airborne data and laboratory measurements on rock samples, the total net export of potassium has been estimated at 422 ± 50 kg/m2 and the chemical weathering rate of potassium at 17 ± 2 kg/km2/a. 相似文献
26.
Daily zenith scattered light intensity observations were carried out in the morning twilight hours using home-made UV-visible
spectrometer over the tropical station Pune (18‡31′, 73‡51′) for the years 2000–2003. These observations are obtained in the
spectral range 462–498 nm for the solar zenith angles (SZAs) varying from 87‡ to 91.5‡. An algorithm has been developed to
retrieve vertical profiles of ozone (O3) and nitrogen dioxide (NO2) from ground-based measurements using the Chahine iteration method. This retrieval method has been checked using measured
and recalculated slant column densities (SCDs) and they are found to be well matching. O3 and NO2 vertical profiles have been retrieved using a set of their air mass factors (AMFs) and SCDs measured over a range of 87–91.5‡
SZA during the morning. The vertical profiles obtained by this method are compared with Umkehr profiles and ozonesondes and
they are found to be in good agreement. The bulk of the column density is found near layer 20–25 km. Daily total column densities
(TCDs) of O3 and NO2 along with their stratospheric and tropospheric counterparts are derived using their vertical profiles for the period 2000–2003.
The total column, stratospheric column and tropospheric column amounts of both trace gases are found to be maximum in summer
and minimum in the winter season. Increasing trend is found in column density of NO2 in stratospheric, tropospheric and surface layers, but no trend is observed in O3 columns for above layers during the period 2000–2003 相似文献
27.
28.
青藏高原近地面层微气象学特征 总被引:12,自引:3,他引:12
Liu Huizhi Zhang Hongsheng Bian Lin'gen Chen Jiayi Zhou Mingyu Xu Xiangde Li Shiming Zhao Yijun 《大气科学进展》2002,19(1):73-88
利用1998年5月-7月在改则、当雄和昌都三测站获得的近地面层气象要素变化的观测资料,分析了青藏高原近地面层风速、温度和湿度日变化特征及廓线规律,发现高原近地面层微气象学特征具有自己的特点;同时还讨论了高原近地面层白天出现的逆湿现象。 相似文献
29.
根据Dobson和TOMS资料分析北京和昆明大气臭氧总量变化特征 总被引:11,自引:0,他引:11
用约20年 Dobson和TOMS资料来分析北京(39.93°N,116.40°E)和昆明 (25.02°N,102.68°)两地大气臭氧总量的变化特征,结果表明:(1)在1979-2000年间北京大气臭氧长期变化趋势是-0.642 DU/年,而昆明在1980-2000年间的趋势是-0.009 DU/年;(2)北京和昆明两地大气臭氧都有很强的季节内变化(尤其冬季更强),与季节性变化强度相当;(3)在北京和昆明,由记录较短的大气臭氧资料分析得到的长期变化趋势,与较长记录得到的结果有显著差异;(4)在北京(中纬度)和昆明(低纬度)大气臭氧都有显著的准两年振荡信号;(5)两个站点大气臭氧的年际变化主要由长期趋势项和准两年振荡信号组成;(6)Dobson仪测量得到的臭氧总量与TOMS资料非常一致。 相似文献
30.
土壤剖面元素分布及其地质、环境意义 总被引:18,自引:2,他引:18
土壤垂直剖面上物化性质,矿物和化学组成的深入研究,可以提供有关成土母质,成壤演化作用的重要信息,识别人类活动叠加的污染强度和影响深度,为土壤地球化学背景值调查,土壤污染及其生态环境影响的评价,环境地球化学灾害的监控与预菟研究提供科学的方法和依据。根据广东珠江三角洲,湖北江汉平原,四川成都盆地部分土壤剖面实测资料,分析研究了土壤化学组成的剖面变化与成土母质类型及组成,土壤成熟度和污染影响的关系。探讨了土壤剖面地球化学特征的地质与环境指示意义,判断分析了土壤受到的污染叠加作用及其影响深度。 相似文献