Kinetics of the Gas-Phase Reactions of OH Radicals, NO3 Radicals and O3 with Three C7-Carbonyls Formed From The Atmospheric Reactions of Myrcene, Ocimene and Terpinolene     

Jillian Baker  Janet Arey  Roger Atkinson 《Journal of Atmospheric Chemistry》2004,48(3):241-260

Rate constants for the gas-phase reactions of OH radicals, NO₃ radicals and O₃ with the C₇-carbonyl compounds 4-methylenehex-5-enal [CH₂=CHC(=CH₂)CH₂CH₂CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH₂=CHC(CH₃)=CHCH₂CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm³ molecule^–1 s^–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10^–10, (4.75 ± 0.35) × 10^–13 and (1.46 ± 0.12) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10^–10, (2.17 ± 0.30) × 10^–12, and (4.13 ± 0.81) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10^–10, (1.75 ± 0.27) × 10^–12, and (5.36 ± 0.28) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10^–10, (1.81 ± 0.35) × 10^–12, and (6.98 ± 0.40) × 10^–17 for the OH radical, NO₃ radical and O₃ reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO₃ radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less.  相似文献   

An Algorithm for the Determination of All Significant Pathways in Chemical Reaction Systems     

Ralph Lehmann 《Journal of Atmospheric Chemistry》2004,47(1):45-78

When the output of a complex chemical model is analysed, a typical topic isthe determination of pathways, i.e., reaction sequences, that produce ordestroy a chemical species of interest.A representative example is the investigation of catalytic ozone destruction cycles in the stratosphere.An algorithm for the automatic determination of pathways in any given reactionsystem is presented. Under the assumption that reaction rates are known, it finds all significant pathways, i.e., all pathways with a rate above a prescribed threshold.The algorithm forms pathways step by step, starting from single reactions.The chemical species in the system are consecutively considered as `branching points'.For every branching-point species, each pathway producing it is connected witheach pathway consuming it.Rates proportional to `branching probabilities' are calculated.Pathways with a rate that is smaller than a prescribed threshold arediscarded.If a newly formed pathway contains sub-pathways, e.g., null cycles, it is split into these simpler pathways.In order to demonstrate the performance of the algorithm, it has been applied to the determination of catalytic ozone destruction cycles and methaneoxidation pathways in the stratosphere.  相似文献   

瞬变电磁法在煤矿水害防治中的应用   总被引：6，自引：0，他引：6  

周韬韩自豪  周建雄万广达 彭南宁 《中国煤田地质》2004,16(2):44-46

煤层附近的富水区(带)严重威胁着煤矿的生产安全，探明地下煤层附近富水区的赋存和断层、裂隙的发育情况，可以有效地指导煤矿水害的防治工作。对于含水地层及富水区，瞬变电磁法在多测道剖面上具有典型响应特征，据此可以查明地下水分布情况。在山东某煤田和河南某矿，应用瞬变电磁勘探，准确地查明了煤层顶底板富水区。．  相似文献   

综合物探方法在汤上屯地热勘探中的应用研究     

龙凡  韩天成 《地下水》2004,26(1):43-47

本文通过联剖、电测深、磁法和测温法等综合工作成果,分析、推断出汤上屯热水构造的产状、性质和热水出露条件,圈定出了热水分布范围.  相似文献   

A Review of Research on Human Activity Induced Climate ChangeⅠ. Greenhouse Gases and Aerosols     

王明星  刘强  杨昕 《大气科学进展》2004,(3)

Extensive research on the sources and sinks of greenhouse gases, carbon cycle modeling, and the characterization of atmospheric aerosols has been carried out in China during the last 10 years or so. This paper presents the major achievements in the fields of emissions of greenhouse gases from agricultural lands, carbon cycle modeling, the characterization of Asian mineral dust, source identification of the precursors of the tropospheric ozone, and observations of the concentrations of atmospheric organic compounds. Special, more detailed Information on the emissions of methane from rice fields and the physical and chemical characteristics of mineral aerosols are presented.  相似文献   

航空物探平剖图自动绘制的可视化处理   总被引：5，自引：2，他引：5  

刘浩军 《物探与化探》2004,28(2):147-149

简要介绍了航空物探平面剖面图的自动绘制方法,给出了绘制中对一些问题的处理方法;重点介绍了彩色渐变填充着色、彩色渐变渲染着色等几种可视化处理方法,并提出了着色中渐变度、透明度概念及应用方法。  相似文献   

基于扫描法在复杂地层剖面图绘制中的应用     

魏敏  黄地龙  邓飞 《新疆地质》2004,22(1):104-106

论述了基于扫描线填充算法的理论和适用填充剖面图的数据结构．同时应用该算法采用Delphi和OpenGL绘制了某地质工程实例的二维、三维复杂地质填充剖面图，并取得了较好效果．  相似文献   

中国大陆科学钻探主孔1200米构造柱及变形构造初步解析   总被引：31，自引：20，他引：31  

许志琴张泽明  刘福来杨经绥唐哲民  陈世忠柴耀楚李天福  陈方远 《岩石学报》2004,20(1):53-72

在利用成象测井资料准确地恢复岩心空间位置的基础上，建立了位于江苏省东海县毛北村的中国大陆科学钻探主孔岩心1200m精细构造柱。划分了由榴辉岩与超镁铁质岩组成的第一岩性-构造单元及由副片麻岩夹榴辉岩与超镁铁质岩透镜体组成的第二岩性-构造单元，自上而下岩石的面理产状由向东陡倾变为向南东缓倾。第一岩性-构造单元的榴辉岩与超镁铁质岩是毛北榴辉岩杂岩体的组成部分，在榴辉岩中发现以南北向拉伸线理及由北往南的剪切指向为特征的超高压变质岩早期变形举止。位于第二岩性一构造单元下部(770-1130m深度)300多米厚的韧性剪切带是地表出露的毛北韧性剪切带在孔下的延伸，剪切应变及石英组构分析表明，在伴随的退变质角闪岩相一绿帘角闪岩相一绿片岩相的转换过程中，剪切应变由自SE往NW的“逆冲”转为NW向SE的正向滑移。结合钻孔围区地质，重塑了上部由毛北榴辉岩杂岩体与副片麻岩围岩组成的轴面向SE倾斜的同斜倒转褶皱系，以及下部为韧性剪切带的构造模型。钻孔验证了VSP地震反射剖面中850-1200m深度的强反射层与韧性剪切带相吻合。结合苏鲁超高压变质地体的折返构造的研究，提出该构造模型的成因与折返阶段超高压变质地体的斜向上的挤出及后折返阶段的穹隆形成有关。  相似文献   

Thermo-mechanical structure beneath the young orogenic belt of Taiwan     

Kuo-Fong Ma  Teh-Ru Alex Song 《Tectonophysics》2004,388(1-4):21

We investigate the thermo-mechanical properties beneath the young orogenic belt of Taiwan by constructing a shear strength profile from a vertical stratified rheological structure. The stratified rheological structure is estimated based on the recently developed thermal structure and its likely composition. Subduction–collision in the young orogenic belts and the thick accretionary wedge make a significant contribution to the growth of sialic crust in the hinterland. The sialic bulk crust not only results in a low seismic velocity but also produces weak crust in the hinterland. The earthquake depth–frequency distribution in the foreland and hinterland correlates very well with the regimes of the brittle/ductile transition revealed in the strength profile. Our results show that the observed two-layer seismicity in the foreland is due to a moderate geotherm and an intermediate mafic bulk composition; while single-layer seismicity in the hinterland is due to its felsic bulk composition. In the foreland, the mechanically strong crust (MSC) and the mechanically strong lithosphere (MSL) coincide with frequent seismicity. The shallow MSC in the hinterland is consistent with the 20- to 25-km seismicity occurring there. The total lithospheric integrated strength (LIS) in the hinterland is only about half of that in the foreland, suggesting a weak lower crust and lithosphere mantle in the hinterland. The results confirm that the earthquake cutoff depth is a proxy for temperature. The calculated decrease of effective elastic thickness (EET) from the orogenic margin (foreland) to the center (hinterland) is consistent with the results of flexure modeling in most orogenic belts. Due to the weak LIS in the hinterland, crustal thinning and rifting may occur in the future. Our results, thus, suggest that the mechanical structure is also closely related to the composition and is not directly reflected in the thermal structure.  相似文献   

基于物方影像匹配和概率松弛的断面自动提取   总被引：4，自引：0，他引：4  

郑顺义  张祖勋  张剑清 《测绘信息与工程》2004,29(2):26-27

提出了基于物方影像匹配的断面提取,为了提高匹配的可靠性,引入了概率松弛法,最终获得了高精度的断面.  相似文献