从平衡-封闭-静态转向非平衡-开放-动力学研究-热液矿床成因的若干新概念概述     

张荣华  胡书敏  张雪彤 《地质学报》2016,90(9):2437-2453

热液金属矿床成因研究过程中,观测与实验始终是密切结合的。上世纪70年代,平衡热力学的实验数据的快速积累,使人们用热力学理论计算可以预测和反演矿石和岩石的成因。但是,没有矿物-水溶液的反应速率数据,又没有与流体力学的结合,搞清楚矿石成因是困难的。七、八十年代,开始研究矿物与水溶液的反应动力学实验。科学家们开始瞄准了从平衡-封闭-静态转向非平衡-开放-动力学研究的这个大方向。1992年我们建立地球化学动力学开放研究实验室。研究高温高压矿物与水反应速率,发现固液的开放体系的自组织现象。实验发现温度影响矿物的各个元素反应速率改变,发现在跨越水临界态时矿物与水反应速率涨落、在近临界的气-液两相不混溶区一些金属进入气相、超临界流体的氧化作用及特别的溶剂性能影响矿物溶解性质。实验证实:临界态区流体与矿石成因有关。水岩相互作用的反应动力学实验温度从低温到550度,揭示矿石的金属来源、迁移、金属与蚀变分带机制。一大批大于300度的矿物与水反应动力学实验在国际界是少有报道的。九十年代,超高压的科学发展,与同步辐射光源的技术进步的结合,使固体地球科学又迈向了地球深内部。我们发展了高温高压流体性质的原位直测(测量850℃水溶液)红外谱,发现深部流体的新性质:气液两相流体的新结构,在临界温度区(300~400℃),水分子氢键网络的破坏受压力影响不大(23MPa~3GPa),同时,出现水的高电导率。研发新仪器为开放-流动-非平衡的反应动力学实验与极端条件下物质性质的直接观测结合,在科学前沿领域开辟了创新道路。  相似文献   

Determination of the factors governing soil erodibility using hyperspectral visible and near-infrared reflectance spectroscopy     

《International Journal of Applied Earth Observation and Geoinformation》2016

Soil erodibility, which is difficult to estimate and upscaling, was determined in this study using multiple spectral models of soil properties (soil organic matter (SOM), water-stable aggregates (WSA) > 0.25 mm, the geometric mean radius (D_g)). Herein, the soil erodibility indicators were calculated, and soil properties were quantitatively analyzed based on laboratory simulation experiments involving two selected contrasting soils. In addition, continuous wavelet transformation was applied to the reflectance spectra (350–2500 nm) of 65 soil samples from the study area. To build the relationship, the soil properties that control erodibility were identified prior to the spectral analysis. In this study, the SOM, D_g and WSA >0.25 mm were selected to represent the most significant soil properties controlling erodibility and describe the erodibility indicator based on a logarithmic regression model as a function of SOM or WSA > 0.25 mm. Five, six and three wavelet features were observed to calibrate the estimated soil properties model, and the best performance was obtained with a combination feature regression model for SOM (R² = 0.86, p < 0.01), D_g (R² = 0.79, p < 0.01) and WSA >0.25 mm (R² = 0.61, p < 0.01), respectively. One part of the wavelet features captured amplitude variations in the broad shape of the reflectance spectra, and another part captured variations in the shape and depth of the soil dry substances. The wavelet features for the validated dataset used to predict the SOM, WSA >0.25 mm and D_g were not significantly different compared with the calibrated dataset. The synthesized spectral models of soil properties, and the formation of a new equation for soil erodibility transformed from the spectral models of soil properties are presented in this study. These results show that a spectral analytical approach can be applied to complex datasets and provide new insights into emerging dynamic variation with erodibility estimation.  相似文献   

Re-parameterization of a quasi-analytical algorithm for colored dissolved organic matter dominant inland waters     

《International Journal of Applied Earth Observation and Geoinformation》2016

Quasi-Analytical Algorithms (QAAs) are based on radiative transfer equations and have been used to derive inherent optical properties (IOPs) from the above surface remote sensing reflectance (R_rs) in aquatic systems in which phytoplankton is the dominant optically active constituents (OACs). However, Colored Dissolved Organic Matter (CDOM) and Non Algal Particles (NAP) can also be dominant OACs in water bodies and till now a QAA has not been parametrized for these aquatic systems. In this study, we compared the performance of three widely used QAAs in two CDOM dominated aquatic systems which were unsuccessful in retrieving the spectral shape of IOPS and produced minimum errors of 350% for the total absorption coefficient (a), 39% for colored dissolved matter absorption coefficient (a_CDM) and 7566.33% for phytoplankton absorption coefficient (a_phy). We re-parameterized a QAA for CDOM dominated (hereafter QAA_CDOM) waters which was able to not only achieve the spectral shape of the OACs absorption coefficients but also brought the error magnitude to a reasonable level. The average errors found for the 400–750 nm range were 30.71 and 14.51 for a, 14.89 and 8.95 for a_CDM and 25.90 and 29.76 for a_phy in Funil and Itumbiara Reservoirs, Brazil respectively. Although QAA_CDOM showed significant promise for retrieving IOPs in CDOM dominated waters, results indicated further tuning is needed in the estimation of a(λ) and a_phy(λ). Successful retrieval of the absorption coefficients by QAA_CDOM would be very useful in monitoring the spatio-temporal variability of IOPS in CDOM dominated waters.  相似文献   

附有物理量和气象条件约束的光学卫星国土观测有效覆盖率评估     

巫兆聪  巫远  张熠  杨帆 《测绘学报》2016,45(7):841-849

传统光学卫星国土观测覆盖评估建立在卫星对地理想覆盖的基础上,并未考虑卫星存储、星地数据传输、观测时长等物理量及观测区域气象因素对于覆盖性能的影响。本文针对光学遥感卫星的国土观测需求.建立国土观测有效覆盖能力评估指标体系,根据卫星数据存储能力、星地数据传输能力、卫星单圈最大观测时长、卫星观测太阳高度角等性能参数,提出了基于物理性能约束下的有效覆盖计算方法。根据气象台站历年气象数据,提出了气象约束因子的计算方法。综合考虑卫星物理性能约束与观测区域气象约束,计算光学遥感卫星对地观测有效覆盖能力。最后根据专家设计的光学遥感卫星国土观测有效覆盖能力评估指标权重,利用层次分析法(AHP)评估光学遥感卫星系统对于国土观测的需求满足程度。试验结果表明,本文方法对于国土观测有效覆盖的估算和评价结果更加精确,更接近于国土观测的实际应用需求,为对地观测有效覆盖能力评估提供了一种更为精确的可行方案。  相似文献   

The variation of crustal stretching and different modes of rifting along the Australian southern continental margin     

N. Kharazizadeh  W. P. Schellart  J. C. Duarte  M. Hall 《Australian Journal of Earth Sciences》2016,63(2):159-174

The southern margin of Australia is a passive continental margin, formed during a Late Jurassic–Cretaceous rifting phase. The development of this passive margin is mainly associated with extensional processes that caused crustal thinning. In this work, we have measured the amount of extension and the stretching factor (β factor) across seven transect profiles approximately evenly distributed across the margin. The obtained results show that the amount of extension and the β factor along the margin vary from west to east. The lowest amount of extension, low–intermediate β factors and a very narrow margin are observed in the western part with 80 km of extension and is underlain mostly by the Archean Yilgarn Craton and the Albany–Fraser Orogen. The Gawler Craton in the centre of the south Australian margin is another region of low extension and low–intermediate β factor. The largest amount of extension (384 km) and the largest β factor (β = 1.88) are found in the eastern part of the passive margin in an area underlain by Phanerozoic Tasman Orogen units. Our results imply that there is a strong control of the age and thickness of the continental lithosphere on the style of rifting along the Australian passive margin. Rifting of old and cold lithosphere results in a narrow passive margin, with the formation of relatively few faults with relatively wide spacing, while rifting of younger, warmer lithosphere leads to wide rifting that is accommodated by a large number of faults with small spacing.  相似文献   

Magnetic properties of the remagnetized Middle-Ordovician limestones of the Ponón Trehué Formation (San Rafael Block,central-western Argentina): Insights into the Permian widespread Sanrafaelic overprint     

《Journal of South American Earth Sciences》2016

The widespread Sanrafaelic remagnetization reset most of the early Cambrian to mid-Ordovician carbonate platform of the Argentine Precordillera and the calcareous units of the San Rafael Block. We conducted a detailed rock-magnetic study on the Middle-Ordovician limestones of the Ponón Trehué Formation at both limbs of a tight anticline exposed in the San Rafael Block (Mendoza province, central-western Argentina) that are carriers of a syntectonic magnetization of Permian age. We found that the magnetic overprint in the Ponón Trehué Formation is carried by both pyrrhotite and magnetite, with goethite and subordinate haematite likely related to weathering. Hysteresis parameters, frequency dependence of magnetic susceptibility, Cisowski and modified Lowrie-Fuller tests suggest the presence of ultrafine particles of chemical origin. Demagnetization of natural remanent magnetization and of three-axis isothermal remanence confirm pyrrhotite and magnetite as important contributors to the remanence. Both minerals carry the same magnetic syntectonic component suggesting a coeval or nearly coeval remanence acquisition and therefore mineral formation. This and the results of the magnetic fabric analyses indicate an authigenic origin of the magnetic minerals during folding associated with the Sanrafaelic tectonic phase (ca. 280 Ma). Although the chemically active (oxidizing?) fluids expelled from the orogen as it developed in the early Permian is a viable explanation for the Sanrafaelic remagnetization, the role of the nearly coeval magmatism in Precordillera and the San Rafael Block remains to be properly evaluated.  相似文献   

长江三角洲全新世地层中潮滩沉积磁性特征及其古环境意义   总被引：3，自引：1，他引：2  

白雪莘  张卫国  董艳  潘大东  王张华  孙千里  陈静  陈中原  刘晋嫣 《沉积学报》2016,34(6):1165-1175

对长江三角洲北翼江苏南通地区NT钻孔（长60.9 m）进行了系统的环境磁学分析,并结合岩性特征、粒度、漫反射光谱（DRS）等手段,探讨了全新世早、晚期潮滩沉积的磁性特征及其古环境意义。NT孔自下而上可分为6层（U1~U6层）,其中U2层下部（49.9~44.8 m）和U6层（7.5~0.3 m）为潮滩沉积,具有较低的退磁参数S比值及较高的硬剩磁（HIRM）和SIRM/χ,表明反铁磁性矿物如赤铁矿、针铁矿等含量和比例较高。结合漫反射光谱（DRS）分析,发现U6层上部盐沼（1.5~0.3 m）赤铁矿和针铁矿富集,U2层下部的盐沼仅富集赤铁矿。这一差异与U2层和U6层形成的时期和沉积环境有关。U2层形成于晚更新世晚期至早全新世,且曾长期暴露地表,有利于赤铁矿的形成,其后随着海平面的持续上升,盐沼不断垂向加积,始终处于水下环境,不利于针铁矿的形成;U6层形成于晚全新世三角洲海岸的进积过程中,氧化还原相互交替的环境有利于针铁矿的形成,后期成陆后的成土作用生成了较多的磁赤铁矿和赤铁矿。研究表明,全新世三角洲发育过程中,不同时期形成的盐沼具有不同的磁性特征,磁性特征的研究可以提供潮滩沉积环境演变的信息,对三角洲古环境重建研究具有重要意义。  相似文献   

利用两种指纹因子判别小流域泥沙来源   总被引：2，自引：0，他引：2       下载免费PDF全文

陈方鑫  张含玉  方怒放  史志华 《水科学进展》2016,27(6):867-875

为精确识别黄土高原丘陵沟壑区典型小流域泥沙来源,分析了流域内“源-汇”地区土壤的理化性质及生物标志物（正构烷烃）作为潜在指纹识别因子,并建立了复合指纹模型。结果显示:单独的土壤理化指纹及正构烷烃均不能有效识别泥沙来源;土壤理化指纹和正构烷烃分别在林地、农地及沟道的辨别上显示出其局限性。多元化的复合指纹（碳优势指数CPI、Ca、TP、C₂₀、C₂₉、Fe）则能辨别90.5%的泥沙来源。模型结果显示沟道是该流域泥沙的主要来源,占60.8%,其次为农地占20.7%,林地占11.3%,草地占7.2%。研究表明,结合生物标志物的复合指纹法能更精确地反映泥沙来源,适用于各泥沙源头的地质条件差异较小的流域,对黄土高原小流域水土流失治理具有指导意义。  相似文献   

小浪底水库溯源冲刷效率评估试验          下载免费PDF全文

李涛  张俊华  夏军强  马怀宝  郜国明  王增辉 《水科学进展》2016,27(5):716-725

水库溯源冲刷试验是评估在水库速降水位过程中,结合工程控制条件、水沙条件、冲刷时机和初始水库蓄水条件等因素,研究支流拦门沙坎破坏程度对干流溯源冲刷的影响。采用按照水库高含沙模型相似律建立的小浪底水库实体模型开展了4个组次的水库降水库区发生溯源冲刷的试验,第1~4组次库容恢复率依次为11.6%、6.8%、12.2%和6.6%。拦门沙坎破坏越严重,水量越大,库区溯源冲刷量越大,库容恢复率大;侵蚀基准面越低,库区溯源冲刷量大,库容恢复率大;库区淤积量42.00亿m3时采用降低水位引起库区发生溯源冲刷优于库区淤积量32.00亿m3。对原有的陕西水利科学研究所与清华大学的逐日溯源冲刷公式在考虑支流促因的基础上进行了改进,说明支流蓄水量进入干流越多,引起支流口以下的干流河段冲刷量越大,其计算结果与实测值满足生产实践精度,可作为多沙河流水库调水调沙方案制定参考。  相似文献   

精细反演计算在镇江五洲山磁异常再解释中的应用     

张作宏  魏邦顺  张大莲  等 《江苏地质》2016,40(4):653-661

江苏镇江五洲山地区存在多个磁异常,通过对该地区地质背景、地磁场特征的分析研究,结合数据处理技术对DC-19异常开展了二维小波多尺度分解、三维物性反演以及2.5维剖面反演等精细处理计算。结果表明,矿孔的深部、旁侧还存在较大规模的磁铁矿体,认为该地区具有较好的寻找矽卡岩型磁铁矿的前景。说明利用计算技术,通过精细反演可进一步深化对以往异常的认识,达到重新评价异常的目的。  相似文献