Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

Self-regulated black hole accretion, the M–σ relation and the growth of bulges in galaxies     

Mitchell C. Begelman †  Biman B. Nath ‡ 《Monthly notices of the Royal Astronomical Society》2005,361(4):1387-1392

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Coronal change at the south-west limb observed by Yohkoh on 9 November 1991, and the subsequent interplanetary shock at Pioneer Venus Orbiter     

Shinichi Watari  Z. Smith  H. A. Garcia  T. Detman  M. Dryer 《Solar physics》1996,167(1-2):357-369

A spectacular change in the lower corona on the south-west limb has been found in solar images taken by the Yohkoh soft X-ray telescope. The event is characterized by a large topological change in magnetic field and a large intensity decrease observed after the X1. 1/1B flare on 9 November, 1991. A coronal mass ejection (CME) was observed by the Mark III K-coronameter (MK3) at the HAO/Mauna Loa Observatory. Both the MK3 (white-light) and soft X-ray observations showed that one leg of this CME was located above the flare site. An interplanetary shock associated with this event was observed by Pioneer Venus Orbiter, and, possibly, by IMP-8.Also Cooperative Institute for Research in the Environmental Sciences (CIRES), University of Colorado, Boulder, CO 80309, U.S.A.  相似文献   

A measurement of the 362 GHz absorption line of Mars atmospheric H₂O₂     

R.T Clancy  B.J Sandor 《Icarus》2004,168(1):116-121

The 362.156 GHz absorption spectrum of H₂O₂ in the Mars atmosphere was observed on September 4 of 2003, employing the James Clerk Maxwell Telescope (JCMT) sub-millimeter facility on Mauna Kea, Hawaii. Radiative transfer analysis of this line absorption yields an average volume mixing ratio of 18±0.4 ppbv within the lower (0-30 km) Mars atmosphere, in general accordance with standard photochemical models (e.g., Nair et al., 1994, Icarus 111, 124-150). Our derived H₂O₂ abundance is roughly three times greater than the upper limit retrieved by Encrenaz et al. (2002, Astron. Astrophys. 396, 1037-1044) from infrared spectroscopy, although part of this discrepancy may result from the different solar longitudes (L_s) of observation. Aphelion-to-perihelion thermal forcing of the global Mars hygropause generates substantial (>200%) increases in HO_x abundances above ∼10 km altitudes between the L_s=112° period of the Encrenaz et al. upper limit measurement and the current L_s=250° period of detection (Clancy and Nair, 1996, J. Geophys. Res. 101, 12785-12590). The observed H₂O₂ line absorption weakens arguments for non-standard homogeneous (Encrenaz et al., 2002, Astron. Astrophys. 396, 1037-1044) or heterogeneous (Krasnopolsky, 2003a, J. Geophys. Res. 108; 2003b, Icarus 165, 315-325) chemistry, which have been advocated partly on the basis of infrared (8 μm) non-detections for Mars H₂O₂. Observation of Mars H₂O₂ also represents the first measurement of a key catalytic specie in a planetary atmosphere other than our own.  相似文献   

Constraints on a planetary origin for the gap in the protoplanetary disc of GM Aurigae   总被引：1，自引：0，他引：1  

W. K. M. Rice  Kenneth Wood  P. J. Armitage  B. A. Whitney  J. E. Bjorkman 《Monthly notices of the Royal Astronomical Society》2003,342(1):79-85

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Astrometric signatures of self-gravitating protoplanetary discs     

W. K. M. Rice  P. J. Armitage  M. R. Bate  I. A. Bonnell 《Monthly notices of the Royal Astronomical Society》2003,338(1):227-232

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Calibration of the kinematic method of studying solar wind disturbances on the basis of a one-dimensional MHD solution and a simulation study of the heliosphere disturbances between 22 november and 6 december 1977     

Wei Sun  S.-I. Akasofu  Z.K. Smith  M. Dryer 《Planetary and Space Science》1985,33(8):933-943

An empirical kinematic method developed by Hakamada and Akasofu (1982) is calibrated on the basis of a one-dimensional MHD solution. The calibrated results are used to simulate the stream-stream interaction and the background corotating structure in a simple situation and also during 22 November–6 December 1977. The solar wind disturbances caused by solar activities during this period are then introduced into the above background stream in simulating the heliospheric disturbance event which was observed by an aligned set of spacecraft at distances between 0.6 and 1.6 a.u. The observations and the simulated results are satisfactory, and a little more refinement in the simulation could reconstruct reasonably well the data by filling the data gaps in the solar wind speed, the density and the IMF magnitude.  相似文献   

The nature of Europa's dark non-ice surface material: Spatially-resolved high spectral resolution spectroscopy from the Keck telescope     

John R. Spencer  William M. Grundy  Robert W. Carlson  Gary B. Hansen 《Icarus》2006,182(1):202-210

We present new 1.45-1.75 μm spectra of Europa's dark non-ice material with a spectral resolution (λ/δλ) of 1200, obtained by using adaptive optics on the Keck telescope to spatially separate the spectrum of the non-ice material from that of the surrounding ice-rich regions. Despite the great increase in spectral resolution over the previous best spectra of the non-ice material, taken with Galileo's near-infrared mapping spectrometer (NIMS) with λ/δλ=66, no new fine-scale spectral structure is revealed. The smoothness of the spectra is inconsistent with available laboratory spectra of crystalline hydrated salts at Europa temperatures, but is more consistent with various combinations of non-crystalline hydrated salts and/or hydrated sulfuric acid, as have been matched to the lower-resolution NIMS spectra.  相似文献   

The Citation Impact of Digital Preprint Archives for Solar Physics Papers   总被引：1，自引：0，他引：1  

Travis S. Metcalfe 《Solar physics》2006,239(1-2):549-553

Papers that are posted to a digital preprint archive are typically cited twice as often as papers that are not posted. This has been demonstrated for papers published in a wide variety of journals, and in many different subfields of astronomy. Most astronomers now use the arXiv.org server (astro-ph) to distribute preprints, but the solar physics community has an independent archive hosted at Montana State University. For several samples of solar physics papers published in 2003, I quantify the boost in citation rates for preprints posted to each of these servers. I show that papers on the MSU archive typically have citation rates 1.7 times higher than the average of similar papers that are not posted as preprints, while those posted to astro-ph get 2.6 times the average. A comparable boost is found for papers published in conference proceedings, suggesting that the higher citation rates are not the result of self-selection of above-average papers. Editors’ Note: This paper lies outside the normal purview of Solar Physics papers, however the editors feel that the content is of sufficient importance for all Solar Physics authors and readers to merit its publication.  相似文献   

Spinor: Visible and Infrared Spectro-Polarimetry at the National Solar Observatory     

Hector Socas-Navarro  David Elmore  Anna Pietarila  Anthony Darnell  Bruce W. Lites  Steven Tomczyk  Steven Hegwer 《Solar physics》2006,235(1-2):55-73

The Spectro-Polarimeter for Infrared and Optical Regions (SPINOR) is a new spectro-polarimeter that will serve as a facility instrument for the Dunn Solar Telescope at the National Solar Observatory. This instrument is capable of achromatic polarimetry over a very broad range of wavelengths, from 430 to 1600 nm, allowing for the simultaneous observation of several visible and infrared spectral regions with full Stokes polarimetry. Another key feature of the design is its flexibility to observe virtually any combination of spectral lines, limited only by practical considerations (e.g., the number of detectors available, space on the optical bench, etc.). Visiting Astronomers, National Solar Observatory, operated by the Association of Universities for Research in Astronomy, Inc. (AURA), under cooperative agreement with the National Science Foundation.  相似文献