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11.
Low-rhenium molybdenite by metamorphism in northern Sweden: Recognition, genesis, and global implications 总被引：8，自引：0，他引：8
Re–Os dating of molybdenite is an accurate means to date intrusions and intrusion-related ore deposits using the model age or isochron approach. But, molybdenite has a new niche in the greenschist- to granulite-facies metamorphic environment. Re–Os ages for metamorphic molybdenite may be used to construct regional metamorphic histories. Age significance and accuracy are established by analyzing multiple molybdenite separates extracted from single, petrographically-characterized molybdenite occurrences. In this study, twelve geologically distinct molybdenite-bearing samples from two small Mo districts in northern Sweden trace a 150 m.y. Paleoproterozoic Svecofennian metamorphic history from 1900 to 1750 Ma. These data reveal a little-known, widespread and protracted, Late Svecofennian anatexis in northern Sweden.The Kåtaberget Mo–(Cu, F) deposit is located in the Moskosel granite batholith north of the economically-renown Skellefte district. Four different molybdenite samples from outcrop at Kåtaberget indicate an intrusion age of 1895 ± 6 Ma with the formation of later pegmatite–aplite at 1875 ± 6 Ma. The Allebuoda (Björntjärn) and Munka Mo–(W) deposits in the Rappen district are represented by three outcrop and five drill core samples of molybdenite-bearing aplite–pegmatite–granite. These two deposits were previously described as intrusion-related Climax-type Mo mineralization. Re–Os ages for molybdenites from these deposits range from 1865 to 1750 Ma and, significantly, Re concentrations are markedly low, extending to the sub-ppm level. Age agreement within the deposits is conspicuously lacking, whereas, with one exception, age agreement within any single sample (geologic occurrence), as established by analysis of additional molybdenite separates, is very good. These data, together with fundamental geologic observations discussed in this paper, suggest that Mo–(W) mineralization in northern Sweden is not intrusion-related, but the local product of episodic melting of Archean–Paleoproterozoic supracrustal gneisses related to the Svecofennian orogeny. Petrographic traverses across the boundary between widespread, foliation-parallel units of aplitic to pegmatitic pink granite and hosting biotite gneiss directly capture the process of ore formation. Dehydration breakdown of zircon-rich biotite aligned with the foliation in the gneiss is accompanied by formation of new pristine, post-deformational biotite plus sulfides, oxides, hydrothermal zircon and fluorite, all associated with microcline-dominant leucosomes.This process has profound implication for the traditional leucogranite, intrusion-related genesis attributed to the broad classification of Mo–W–Sn–base and precious metal mineralization (e.g., South Mountain Batholith, Nova Scotia; Okiep, Namaqualand, South Africa; Mactung, Yukon; Pogo–Liese, Tintina, Alaska; Carajás and Goiás–Rio Tocantins, Brazil; New England Batholith, NSW, Australia; Bergslagen, Sweden; Nevoria, Western Australia; Alpeinerscharte, Austria; Erzgebirge, Germany; Sardinia–Corsica Batholith). In addition to biotite, metallogenic contributions (e.g., Mo, W, Sn, U, Bi, Cu, Pb, Zn, Fe, Ni, Co, Au, Ag, Te, As, Sb, REE) in various combinations may also be controlled by breakdown of amphibole. In effect, the trace element composition of dehydrating or recrystallizing components in a gneissic rock essentially defines the local and district metallogenic suite. In the absence of focusing structures (e.g., shear zones, sheeted vein development), this process will generally form small and disconnected subeconomic deposits with erratic and unpredictable grades. Low Re content in associated molybdenite is a key indicator for a subeconomic origin by local melting of biotite gneiss (Mo–W) or muscovite schist (Sn–W). 相似文献
12.
In this study, we present quantitative spatial information on the one- and two-dimensional distribution of inferred melt-bearing structures in anatectic supracrustal rocks of the Southern Brittany Migmatite Belt, south of the transcurrent South Armorican Shear Zone (SASZ); based on these data, we infer the mechanism of melt extraction from partially molten crust. Former melt-bearing structures include foliation-parallel leucosomes and cross-cutting granitic leucosomes that infill inter-boudin partitions and extensional shear surfaces, as well as discordant dykes of granite. Petrographic (i.e., mineralogical and microstructural) continuity of granite from structure to structure suggests that they once formed a continuous melt-bearing network. Measurements along one-dimensional line traverses perpendicular to layering of stromatic migmatite exposed in clean, sub-horizontal outcrop surfaces provide information about thickness and spacing distributions of foliation-parallel leucosomes. Most leucosome thicknesses fall in the range of 1–10 mm, with upper limits around 20–30 mm. The number of thicker layers decreases abruptly with increasing thickness, which is inconsistent with scale-invariance. This suggests that leucosome formation was controlled by short-range melt movement along grain boundaries to form melt-rich layers constrained by pre-existing compositional layering. Spacing distributions also are not scale-invariant; however, the large percentage of leucosomes (40–60%) in these line traverses suggests that spacing distributions may be controlled in part by impingement of leucosomes, making it difficult to derive genetic information from these data. Qualitative observation of inferred melt-bearing structures in mutually perpendicular two-dimensional exposures from the same outcrop reveals anisotropy of the leucosome network related to a well-developed sub-horizontal quartz–feldspar lineation reflecting stretching associated with transcurrent movement along the SASZ. Analysis of these two-dimensional distributions using the box-counting method corroborates the observed anisotropy, but indicates that leucosome morphology (and perhaps distribution) is not scale-invariant. The applicability of the box-counting method, or of fractal analysis, to understanding melt movement in migmatites is discussed in light of these results. Based on the anisotropy of melt-bearing structures, we infer that melt-movement in structures now represented by layer-parallel leucosomes was primarily sub-horizontal. These layers fed steeply dipping structures now represented by cross-cutting leucosomes, in particular those developed at inter-boudin partitions, and granite dykes. The formation and orientation of these steeply dipping structures was in part controlled by far-field stresses related to dextral displacement along the SASZ. Melt extraction is inferred to have occurred along these steeply dipping structures; extracted melt accumulated in plutons at higher crustal levels, such as the Quiberon, Sarzeau, and Guérande granites. 相似文献
13.
河北小觉地区阜平岩群斜长角闪岩及深熔产物的稀土和Nd同位素地球化学研究 总被引：5，自引：0，他引：5
工作中重点对河北平山小觉地区阜平岩群两类角闪质岩石深熔作用的地球化学进行了研究。一类为厚层状斜长角闪岩，相邻新生浅色体常量元素组成上向TTG花岗质岩石方向转化，稀土和高场强元素含量明显降低，轻重稀土分离程度增高，tDM减小，εNd(t0)增大。另一类为与黑云变粒岩－片麻岩互层的条带状、石香肠状斜长角闪岩，相邻新生浅色体与之存在不同的地球化学关系：（1）稀土总量相对增高，轻重稀土分离程度有所降低；（2）稀土总量和轻重稀土分离程度都有明显增高。后者Nd同位素组成与斜长角闪岩也存在很大区别。这些现象可用熔融母岩、形成条件等差异得到合理的解释。 相似文献
14.
青藏高原东南缘点苍山-哀牢山杂岩带中片麻岩的变质演化及深熔作用特征 总被引：6，自引：6，他引：0
片麻岩是点苍山-哀牢山变质杂岩带最常见的岩石类型,主要由夕线石榴黑云二长片麻岩、石榴黑云斜长片麻岩以及含十字石蓝晶夕线石榴片麻岩所组成,其原岩的化学成分与华北克拉通典型孔兹岩系十分相似.岩相学、成因矿物学和变质反应性质研究以及温压条件估算结果表明,研究区片麻岩类岩石变质峰期的温压条件为T=700～770℃,P=0.5～0.8GPa,已达到或接近麻粒岩相变质,晚期退变质阶段的温压条件为T=600～650℃,P=0.35～0.45GPa.片麻岩变质演化的P-T轨迹具有顺时针型式.在麻粒岩相变质阶段,片麻岩类岩石普遍发生深熔作用,主要表现为含水矿物黑云母的脱水熔融和长英质矿物的部分熔融.该项研究对于进一步揭示青藏高原东南缘点苍山-哀牢山造山带的变质演化深熔作用机理及动力学过程具有重要的科学意义. 相似文献
15.
深熔过程中熔体成分与锆石行为模拟计算 总被引：3，自引：2，他引：1
发生深熔作用是高级变质作用的一个重要特征。深熔过程中产生的熔体可为淡色花岗岩提供潜在的源区;深熔过程中锆石的行为直接影响对变质锆石记年地质意义的理解。在含Zr体系下的相平衡模拟显示泥质成分深熔过程中产生熔体的成分在P-T空间中规律变化。温度升高时熔体Zr/Si值、Zr、FeO、MgO以及CaO等含量明显增加,压力较高时K2O含量也随温度升高而明显增加。Na2O含量随温度升高而降低,但随压力升高而增加。压力升高时Al/Si值显著升高。温度较高时Na/(Na+K)等值线较陡,减压熔融过程不会显著改变熔体Na/(Na+K)值,而升温减压过程以及近等压升温过程都会明显降低熔体Na/(Na+K)值。中压时随温度升高熔体Fe/(Fe+Mg)值缓慢升高,而石榴石的生长发育会迅速降低熔体Fe/(Fe+Mg)值。不同温压条件下对应的固相线熔融、白云母脱水熔融以及黑云母脱水熔融形成的熔体成分具有明显差异。对比模拟熔体成分在P-T空间的演化,喜马拉雅地区电气石淡色花岗岩对应熔体的形成温压条件应低于二云母淡色花岗岩,同类型淡色花岗岩之间在形成条件上也可能存在一定差异,并经历了差异性演化过程。含Zr体系下的相平衡关系显示进变过程是消耗锆石的过程,因而在进变过程中变质锆石难以生长,发生深熔作用的岩石中的变质锆石主要在退变过程中形成并记录退变质年龄。熔体丢失相关模拟显示不同温度阶段发生熔体丢失对锆石稳定性的影响不同。温度较低时Zr含量较少的熔体丢失会扩大持续进变过程中锆石的稳定范围,而温度较高时富Zr熔体的丢失会降低持续进变过程中锆石的稳定温度。类似于分离熔融作用的过程最利于残留相中剩余锆石在持续进变过程中的保存。 相似文献
16.
新疆西南天山低压高温变质带深熔时代及其地质意义 总被引：1，自引：0，他引：1
西南天山木扎尔特地区低压高温变质带主要出露片麻岩类、斜长角闪岩类和麻粒岩类三种岩石类型,由于受到深熔事件的影响在其内部形成了规模不一的长英质脉体,然而对这些深熔长英质脉体的时代还缺乏准确的限定。本文通过详细的岩相学、锆石阴极发光图像研究,采用LA-ICP-MS技术对3件长英质脉体不同锆石微区进行了U-Pb定年,进而探讨西南天山低压高温变质带的形成时间。长英质脉体中的新生锆石具有弱的振荡环带,低的Th/U比值,锆石形态学和内部结构也表明锆石结晶于与深熔作用有关的熔体中,长英质脉体获得的深熔时代为276.5±2.0Ma、272.0±1.7Ma、265.5±1.5Ma,其年龄范围代表了木扎尔特地区低压高温变质带的形成时间可能为早中二叠世,该年龄与区域上西南天山造山带广泛出现的碰撞后岩浆事件的时代相一致,表明早二叠世西南天山造山带已进入造山后伸展减薄的后碰撞造山演化阶段。同时获得一组集中分布的深熔长英质脉体421.8±3.2Ma的继承锆石年龄,该年龄与寄主岩石夕线石榴黑云斜长片麻岩一组主要的年龄峰值一致,表明长英质脉体可能来源于夕线石榴黑云斜长片麻岩的部分熔融作用,对应于南天山志留纪晚期的岩浆事件。 相似文献
17.
《International Geology Review》2012,54(15):1887-1908
ABSTRACTThe widespread migmatites in the northwestern part of the Sulu Orogen, China, indicate regional anatexis that is of great significance when discussing the tectonic evolution of this continental orogenic belt. Cathodoluminescence (CL) images, U–Pb ages, and in situ trace element compositions of zircons from four pegmatite veins within these migmatites provide clear evidence for the nature of the post-collisional evolution of the Sulu Orogen. The inherited zircon cores reveal that the protoliths of the migmatites were middle Neoproterozoic magmatic rocks (810–620 Ma) of the South China Block. The protoliths underwent two partial melting events. The mantle domains of the inherited zircons record a Late Triassic (222.0–204.0 Ma) partial melting event that occurred during the exhumation and retrograde metamorphism, after ultrahigh-pressure (UHP) metamorphism. Subsequent newly grown zircons record a Middle–Late Jurassic to Early Cretaceous (164.1–125.5 Ma) anatexis event, indicating that the late Mesozoic anatexis started before ca. 164.1 Ma, reached a peak at ca. 152.1 Ma, and ceased at ca. 125.5 Ma. Combined with previous results of studies on the Sulu orogen, the late Mesozoic anatexis suggested that the thickened crust of the Sulu Orogen had started to become unstable before 164.1 Ma. The duration of ~164.1–137 Ma corresponds to a period of transition in the tectonic regime of the Sulu Orogen, enabling the early high-temperature ductile deformation. After ca. 137 Ma, the tectonic regime was fully transformed into extension and the Sulu Orogen underwent rapid thinning and collapse, thus leading to the late medium–low temperature ductile deformation (137–121 Ma) and laying the foundations for the large-scale magmatic emplacement during the late Early Cretaceous (127–115 Ma). These two partial melting events together promoted the rapid exhumation of the Sulu UHP rocks. 相似文献
18.
印度大陆俯冲过程中的高压变质与深熔作用：东喜马拉雅构造结南迦巴瓦杂岩的相平衡模拟研究 总被引：5，自引：5，他引：0
位于东喜马拉雅构造结的南迦巴瓦杂岩是高喜马拉雅结晶岩系的一部分,是印度大陆深俯冲到欧亚板块之下经历了高压变质作用的产物。基于岩相学和矿物化学研究,本文对南迦巴瓦杂岩中的泥质变质岩进行了相平衡模拟研究。结果表明,泥质岩石经历了高压麻粒岩相变质作用,峰期矿物组成是石榴石+蓝晶石+黑云母+斜长石+钾长石+石英+金红石,峰期变质条件是~820℃,13.0~13.5kb,表明印度大陆至少俯冲到了约45km深度,构成了青藏高原的加厚下地壳。高压泥质变质岩在进变质和峰期变质过程中经历了白云母和黑云母脱水反应引起的部分深熔,熔融程度可达27vol%,形成了花岗质成分的熔体,构成了喜马拉雅造山带淡色花岗岩的源区。因此,青藏高原具有一个深熔融的中下地壳,为其侧向流动提供了有利的流变学环境。 相似文献
19.
The Lyngen gabbro (LG), defining the major part of the Lyngen magmatic complex, is characterised by layered gabbros of N-MORB affinity (western suite) and layered gabbronorites, quartz-bearing gabbros and diorites/quartz-diorites of IAT (island-arc tholeiite) to boninitic affinity (eastern suite). The boundary between the eastern and western suites is generally defined by a large-scale ductile shear zone of suboceanic origin, the Rypdalen shear zone (RSZ). Tonalites occur within the RSZ and in the eastern suite of the LG. Variations in field occurrence and chemical composition of the tonalites suggest that they represent two petrologically different groups. Tonalite intrusion (the Vakkas pluton) up to 5 km2 large occur in the eastern suite of the LG, and are characterised by high Y contents (average 26 ppm) and high K2O/Rb ratios (average 0.062) compared to tonalites on the RSZ. The Vakkas pluton has lightly concave REE (rare earth element) patterns with negative Eu-anomalies, and positive ND-values (+3.7 to +3.9). Geochemical modelling based on the REE and field evidence suggests that these tonalites may have formed by fractional crystallization from a boninitic parental magma. Tonalites related to the RSZ form irregular veins and dikes that net vein the shear zone. They are characterised by low Y contents (average 6 ppm), low K2O/Rb ratios (average 0.025), and highly variable contents of Na2O, K2O, Sr and Ba, compared to the Vakkas pluton. Tonalites related to the RSZ show substantial variation in the content of the LREEs. They possess low abundances of the HREEs, and absence of, or slightly positive Eu-anomalies. The tonalites have highly variable ND-values (−0.6 to −9.4), probably resulting from enrichment of Nd from an external source. Geochemical modelling suggests that the LREE-rich tonalites formed by H2O-rich partial melting of differentiated products from the eastern suite of the LG. The presence of B in the fluid phase is suggested by the presence of tourmaline-bearing tonalite pegmatites. Thus, the anatectic tonalites of this group could have been formed by water-excess melting of a variety of gabbroic cumulates of the LG. In the LG, LREE-depleted tonalites (ND-values +5.1) also occur, and these are best explained in terms of partial melting of gabbroic cumulates from the transition zone between the eastern and the western suites of the LG. 相似文献
20.
西藏吉塘花岗岩地球化学特征及成因 总被引：7，自引：2，他引：5
沿澜沧江结合带发育一条长达1000余千米的印支期澜沧花岗岩带,吉塘岩体位于该带北段,产出在吉塘以西约3km,轴向NNW,侵位于古元古代吉塘群变质岩系中,长70km,宽2~10km、出露面积341km2。主要由花岗闪长岩和二长花岗岩组成,Rb-Sr等时线年龄值为220Ma。本文对吉塘岩体开展了系统的岩石地球化学特征分析。研究结果表明吉塘岩体为过铝质钙碱性S型花岗岩,吉塘岩体在岩石化学组成上,SiO2含量63%~71%,平均66.5%,Na2O含量2.8%~4.2%,K2O含量1.7%~3.4%,铝饱和指数A/CNK=1.09~1.48,CIPW标准矿物中刚玉1.5%~5.6％,微量元素组成类似于片麻岩质的中地壳。(87Sr/86Sr)i值为0.7280~0.7395,εNd(i)为-14.1~-16.2,指示岩浆源区为地壳物质,成因上与俯冲作用无关,Nd同位素亏损地幔模式年龄(tDM)在2.0Ga左右,与昌都陆块变质基底古元古代吉塘群的原始形成年代相当,岩体Sr、Nd同位素组成也与变质基底吉塘群片麻岩一致,综合分析认为,岩浆源岩为变质杂砂岩成分的古元古代吉塘群片麻岩,其原岩建造主要是火山弧成因的英安岩或英安质火山碎屑岩,微量元素组成指示为黑云母脱水熔融。分析认为岩浆形成于地壳加厚增温环境下的地壳深熔作用,构造上与板块碰撞后的环境相联系。支持澜沧江构造带为冈瓦纳与扬子大陆边缘多岛弧系统的边界即古特提斯主洋盆的观点。澜沧江洋的闭合时间早于澜沧花岗岩带的形成年龄220Ma,根据构造带上相关研究成果,倾向于认同碰撞时间在280Ma左右。 相似文献