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《Chemie der Erde / Geochemistry》2019,79(4):125538
Roaldite – Fe4N – has been identified in the São Julião de Moreira iron meteorite using electron backscatter diffraction (EBSD) and simultaneously acquired energy-dispersive x-ray spectroscopy (EDS). Mean-periodic-number images derived from raw EBSD patterns confirm this phase by an even higher spatial resolution compared to EDS.Roaldite appears in the form of systematically and repetitively aligned plates. Despite the locally heavy plastic deformation, it is shown that the origin of the oriented precipitation of roaldite is linked to the orientation of the kamacite matrix. Roaldite can be considered to be precipitated from kamacite using an inverse Kurdjumov-Sachs (K-S) or Nishiyama-Wassermann (N-W) orientation relationship. A more accurate discrimination is impossible due to the accumulated shock deformation, which blurs the local reference orientation of kamacite. The habit plane of roaldite is found to be {112}R, which is most likely parallel to {120}K of kamacite. Some of the roaldite plates contain two orientation variants which repeatedly alternate. Their misorientation angle is about 12°. 相似文献
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Factors affecting corrosion and approaches for improving durability of ocean reinforced concrete structures 总被引：1，自引：0，他引：1
Investigation shows that concrete corrosion is a common problem for ocean reinforced concrete (R.C.) structures along China’s coast. A discussion of the corrosion characteristics, based on real project cases and field surveys, is presented in this paper. These factors that might affect corrosion, such as environmental effects, construction quality, cover thickness, property of the concrete material and structure type, are evaluated. Based on the analysis of these corrosion characteristics and affecting factors, the approaches available to improve the durability of ocean R.C. structures are proposed. 相似文献
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用电化学方法测量了Mg_2B_2O_5晶须增强AZ91D镁基复合材料在3.5%NaCl溶液中的开路电位、动电位极化曲线和交流阻抗,研究了晶须体积分数对镁合金基体耐腐蚀性能的影响,并利用SEM和XRD表征了腐蚀后复合材料表面的微观形貌和相组成。结果表明,随着Mg_2B_2O_5晶须体积分数的增加,AZ91D镁基复合材料的耐腐蚀性逐渐提高。当硼酸镁晶须的体积分数为35%时,材料的自腐蚀电位提高0.2V以上,自腐蚀流密度降低了1个数量级;SEM测试表明,复合材料表面生成了一层晶须增韧的腐蚀钝化膜,对基体起到保护作用。 相似文献
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The goal of cathodic protection is to prevent corrosion by maintaining buried pipelines at a constant potential with respect to the surrounding soil. In practice, however, the implementation is very complicated since many factors can contribute to the current flowing off the pipe. Design requires characterization of the parameters impacting the corrosion process, such as soil resistivity, size of the pipe and quality of the coating.In the present paper, we have studied the effect of geomagnetic fields on the pipe-induced currents considering it as an additional cause of corrosion. A theoretical method implemented to model the induced currents was tested in a previous work and the effect during disturbed days was quantified. This theoretical model indicated that the intensity of the current induced in a pipeline by the varying geomagnetic field depends on the intensity and rate of change of the field and the electrical resistivity of the soil. This induced current is in equilibrium with the host current and there is no current drainage between the pipeline and the host until, along the length of the pipeline, the host resistivity becomes different. At that point, current must flow between the pipe and host in order to establish a new equilibrium. It is this drainage current, flowing between the pipeline and the host, which causes corrosion problems.Following these results, experimental tests were performed in Tierra del Fuego. In this zone, a geophysical study was made to determine the discontinuities in soil resistivities and simultaneous measurements of the geomagnetic field and the drainage of current were recorded at different sites. The results obtained from the correlation of the data are consistent with the theoretical predictions. 相似文献
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Wallace H. Campbell 《Pure and Applied Geophysics》1978,116(6):1143-1173
The Alaskar pipeline is a highly conducting anomaly extending 800 miles (1300 km) from about 62° to 69° geomagnetic latitude beneath the most active regions of the ionospheric electrojet current. The spectral behavior of the magnetic field from this current was analyzed using data from standard geomagnetic observatories to establish the predictable patterns of temporal and spatial changes for field pulsation periods between 5 min and 4 hr. Such behavior is presented in a series of tables, graphs and formulae. Using 2- and 3-layer models of the conducting earth, the induced electric fields associated with the geomagnetic changes were established. From the direct relationship of the current to the geomagnetic field variation patterns one can infer counterpart temporal and spatial characteristics of the pipeline current. The relationship of the field amplitudes to geomagnetic activity indices,A
p, and the established occurrence of various levels ofA
p over several solar cycles were employed to show that about half of the time the induced currents in the pipe would be under 1 A for the maximum response oscillatory periods near 1 hr. Such currents should be of minimal consequence in corrosion effects for even a section of the pipeline unprotected by sacrificial electrodes. Of greater interest was the result that the extreme surges of current should reach over one-hundred amperes in the pipeline during high activity. 相似文献
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通过地下水的形成、赋存、运移规律以及对富水性、水化学特征的分析研究;通过对区域构造特点、岩组划分、岩体结构、结构面分级、岩石质量等级和其它工程地质条件的分析研究,系统地总结和描述了山门银矿区的水文地质、工程地质特征。 相似文献
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硫酸盐还原菌对海水状态和碳钢腐蚀行为的影响 总被引：4，自引：0，他引：4
采用溶液环境参数和电极电化学参数测量技术研究了海水中硫酸盐还原菌生长和衰亡过程对溶液状态和D36碳钢腐蚀过程的影响。结果表明,硫酸盐还原菌通过新陈代谢作用把溶液中的硫酸盐转化为硫离子而增大了氧化还原电位和酸度,并导致D36钢的腐蚀电位负移和腐蚀速度增加。极化曲线和电化学阻抗谱证实,虽然金属腐蚀过程在上述过程中并未发生机理性变化,但阳极过程和部分阴极过程的加速是腐蚀速度增加的主要原因。上述结果同时表明．硫酸盐还原菌本身和新陈代谢中间体并未直接参与腐蚀过程,主要是通过产生的硫离子改变溶液状态来加速腐蚀过程的。 相似文献
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The Red River drains 242000 km2 with 90% of this area being downstream of discharges from naturally occurring brine seeps and springs. The upstream area
has been designated as a major chloride emission area in Texas and Oklahoma. Ten major brine source emission areas along the
tributaries to the Red River were identified by U.S. Public Health Service and U.S. Army Corps of Engineers. Eight of these
areas were deemed suitable for the control of brine emissions by structural methods including a ring dike to enclose brine
springs; low flow dams to capture and divert stream flows with high chloride content to evaporation lakes; and shallow aquifer
brine collection wells with a deep-well disposal system. Two adjacent emission areas, designated as Areas XIII and XIV, contribute
500 metric tons of salt per day to the Red River. These areas, along Jonah Creek and Salt Creek, tributaries to the Prairie
Dog Town Fork of the Red River were selected for investigation to control brine emission by utilization of shallow collection
wells and disposal by deep injection wells. Drilling programs and pumping tests were performed to determine the number and
location of shallow collection wells. Eighteen wells with 12 operating full time, will be located in the primary emission
areas. The collected brine will be conveyed through corrosion-resistant pipelines to a treatment facility for filtration at
a rate of 300 l/s. Additional pipelines will convey the filtered brine to deep injection wells for disposal. Nine deep wells
will be installed with seven operating full time. Design criteria for the project are 100-year life expectancy and automated
operation with minimum supervision and maintenance. The required minimum operating, maintenance and supervision coupled with
100-year life expectancy of the project added significantly to the estimated US $58 million capital cost of the project. However,
the reduction in annual cost for labor, repairs and replacement of the component of the system should result in a lower life
cycle cost. The estimated annual operating and maintenance cost is US $4.7 million.
Received: 5 May 1998 · Accepted: 30 June 1998 相似文献
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钢在不同海底沉积物中的腐蚀研究 总被引：3，自引：1，他引：3
1993年9月—1994年9月在中国科学院海洋研究所培育楼流动海水实验室将普通碳钢（A3钢）和低合金钢（16Mn钢）以分别和电连接两种挂片方式置于海面大气区、海水全浸区和不同的海底沉积物中进行一年的室内模拟实验。结果表明，两种钢在海洋环境中的腐蚀率在分别挂片时呈下列顺序：海面大气区＞海水全浸区＞海底沉积区；在电连挂片时出现如下顺序：海面大气区＞海底沉积区＞海水全浸区。随着海底沉积物颗粒度的减小，水／泥（砂）界面腐蚀最轻的钢片的腐蚀速度在电连挂片时成正相关关系，分别挂片时影响不大。处于沉积区最底部的钢片因成为宏电池的阳极，而遭受最严重的腐蚀。低合金钢的腐蚀率比普碳钢略大。 相似文献