量子化学方法研究氯代苯酚类化合物对水生物毒性的构效关系     

许旋  罗一帆  李华祥 《广东海洋大学学报》1992,(2)

对20个氯代苯酚类化合物进行了CNDO/2量子化学计算,讨论了化合物电子结构与其对水生物翻车鱼(Bluegill)、花鳉鱼(Guppy)、和虾(Shrimp)半致死量之间的关系,分别获得了表示其构效关系的三个线性方程,它们的显著性均远高于α=0.01水平。结果表明:氯代苯酚化合物苯环上碳原子的兀电荷之和(∑Qπ_R)越大苯环上碳原子的净电荷之和(∑Q_R)越大,或LUMO轨道能(E_(LUMO))越低,均使化合物对Bluegill和Guppy水生物的毒性增大;而化合物苯环上羟基邻位的碳原子的兀电荷布居(P_3)越大,同时HOMO轨道能E_(HOMO)越高,则化合物对Shrimp毒性也越大。据此,可预测氯代苯酚类化合物对上述三种水生物的毒性。  相似文献   

FARMLAND AND URBAN AREA DYNAMICS MONITORING INCHINA USING REMOTE SENSING AND SPATIALSTATISTICS METHODOLOGY     

LIU Ming-liang  ZHUANG Da-fang  LIU Ji-yuan 《中国地理科学(英文版)》2001,11(1):42-49

1 INTRODUCTIONGlobal change research involves much geo-objectsand geo-process, such as climate and environmentalchange, substance and energy cycling, land-use/land-cover change (LUCC), interactivity between human and nature, etc.. So it need cooperation frommany research communities including international research programs groups such as IGBP (InternationalGeosphere-Biosphere Programme IPCC (Intergovemmental Panel on Climate Change), IHDP (InternationalHuman Dimension Program o…  相似文献   

Yields of Nucleosynthesis from massive and intermediate mass stars and constraints on their final evolution     

D. C. V. Mallik  Sushma V. Mallik 《Journal of Astrophysics and Astronomy》1985,6(3):113-130

Nucleosynthetic yields and production rates of helium and heavy elements are derived using new initial mass functions which take into account the recent revisions in O star counts and the stellar models of Maeder (1981a, b) which incorporate the effects of massloss on evolution. The current production rates are significantly higher than the earlier results due to Chiosi & Caimmi (1979) and Chiosi (1979), and a near-uniform birthrate operating over the history of the galactic disc explains the currently observed abundances. However, the yields are incompatibly high, and to obtain agreement it is necessary to assume that stars above a certain mass do not explode but proceed to total collapse. Further confirmation of this idea comes from the consideration of the specific yields and production rates of oxygen, carbon and iron and the constraints imposed by the observational enrichment history in the disc as discussed by Twarog & Wheeler (1982). Substantial amounts of⁴He and¹⁴C, amongst the primary synthesis species, are contributed by the intermediate mass stars in their wind phases. If substantial numbers of them exploded as Type I SN, their contribution to the yields of¹²C and⁵⁶Fe would be far in excess of the requirements of galactic nucleosynthesis. Either efficient massloss precludes such catastrophic ends for these stars, or the current stellar models are sufficiently in error to leave room for substantial revisions in the specific yields. The proposed upward revision of the¹²C (α,γ)¹⁶O rate may produce the necessary changes in stellar yields to provide a solution to this problem. Stars that produce most of the metals in the Galaxy are the same ones that contribute most to the observed supernova rate.  相似文献   

Rhombic Cell Analysis. Ⅱ. Application to the IRAS／PSCz Catalogue     

Tao Kiang  Yong-Feng Wu  Xing-Fen Zhu Dunsink Observatory Dublin Institute for Advanced Studies Dublin Ireland Center for Astrophysics  University of Science  Technology of China  Hefei 《中国天文和天体物理学报》2004,4(3):209-220

Rhombic cell analysis as outlined in the first paper of the present seriesis applied to samples of varying depths and liming luminosities of the IRAS/PSCzCatalogue. Numerical indices are introduced to summarize essential information.Because of the discrete nature of the analysis and of the space distribution of galax-ies, the indices for a given sample must be regarded as each having an irreduciblescatter. Despite the scatter, the mean indices show remarkable variations acrossthe samples. The underlying factor for the variations is shown to be the limitingluminosity rather than the sampling depth. As samples of more and more luminousgalaxies are considered over a range of some 2.5 magnitudes (a factor of some 75in space density), the morphology of the filled and empty regions defined by thegalaxies degrades steadily towards insignificance, and the degrading is faster for thefilled than the empty region.  相似文献   

⁴⁰Ar/³⁹Ar and oxygen isotope studies of polymetamorphism from Tinos Island, Cycladic blueschist belt, Greece     

M. BRÖCKER  H. KREUZER  A. MATTHEWS  M. OKRUSCH 《Journal of Metamorphic Geology》1993,11(2):223-240

Abstract Petrological, oxygen isotope and ⁴⁰Ar/³⁹Ar studies were used to constrain the Tertiary metamorphic evolution of the lower tectonic unit of the Cyclades on Tinos. Polyphase high-pressure metamorphism reached pressures in excess of 15 kbar, based on measurements of the Si content in potassic white mica. Temperatures of 450–500° C at the thermal peak of high-pressure metamorphism were estimated from critical metamorphic assemblages, the validity of which is confirmed by a quartz–magnetite oxygen isotope temperature of 470° C. Some ⁴⁰Ar/³⁹Ar spectra of white mica give plateau ages of 44–40 Ma that are considered to represent dynamic recrystallization under peak or slightly post-peak high-pressure metamorphic conditions. Early stages in the prograde high-pressure evolution may be documented by older apparent ages in the high-temperature steps of some spectra. Eclogite to epidote blueschist facies mineralogies were partially or totally replaced by retrograde greenschist facies assemblages during exhumation. Oxygen isotope thermometry of four quartz–magnetite pairs from greenschist samples gives temperatures of 440–470° C which cannot be distinguished from those deduced for the high-pressure event. The exhumation and overprint is documented by decreasing ages of 32–28 Ma in some greenschists and late-stage blueschist rocks, and ages of 30–20 Ma in the lower temperature steps of the Ar release patterns of blueschist micas. Almost flat parts of Ar–Ar release spectra of some greenschist micas gave ages of 23–21 Ma which are assumed to represent incomplete resetting caused by a renewed prograde phase of greenschist metamorphism. Oxygen isotope compositions of blueschist and greenschist facies minerals show no evidence for the infiltration of a δ¹⁸O-enriched fluid. Rather, the compositions indicate that fluid to rock ratios were very low, the isotopic compositions being primarily controlled by those of the protolith rocks. We assume that the fundamental control catalysing the transformation of blueschists into greenschists and the associated resetting of their isotopic systems was the selective infiltration of metamorphic fluid. A quartz–magnetite sample from a contact metamorphic skarn, taken near the Miocene monzogranite of Tinos, gave an oxygen isotope temperature of 555° C and calculated water composition of 9.1%. The value of δ¹⁸O obtained from this water is consistent with a primary magmatic fluid, but is lower than that of fluids associated with the greenschist overprint, which indicates that the latter event cannot be directly related to the monozogranite intrusion.  相似文献   

Challenging a Paradigm: Do We Need Active and Inactive Areas to Account for Near-Nuclear Jet Activity?     

Crifo  J.-F.  Rodionov  A. V.  Szegö  K.  Fulle  M. 《Earth, Moon, and Planets》2002,90(1-4):227-238

We briefly describe an advanced 3D gas dynamical model developed for the simulation of theenvironment of active cometary nuclei. The model canhandle realistic nucleus shapes and alternative physical models for the gas and dust production mechanism.The inner gas coma structure is computed by solving self-consistently(a) near to the surface the Boltzman Equation(b) outside of it, Euler or Navier-Stokes equations.The dust distribution is computed from multifluid ``zero-temperature' Euler equations,extrapolated with the help of a Keplerian fountain model.The evolution of the coma during the nucleus orbital and spin motion,is computed as a succession of quasi-steady solutions. Earlier versions of the model using simple,``paedagogic' nuclei have demonstrated that the surface orographyand the surface inhomogeneity contribute similarly to structuring the near-nucleusgas and dust coma,casting a shadow on the automatic attribution of such structures to ``active areas'.The model was recently applied to comet P/Halley, for whichthe nucleus shape is available. In the companion paper of this volume,we show that most near-nucleus dust structuresobserved during the 1986 Halley flybys are reproduced, assuming that the nucleus is strictly homogeneous. Here, we investigate the effect of shape perturbations and homogeneityperturbations. We show that the near nucleus gas coma structure is robust vis-a-vissuch effects. In particular, a random distribution of active and inactive areaswould not affect considerably this structure, suggesting that such areas,even if present, could not be easily identified on images of the coma.  相似文献   

测绘项目管理实施引论     

龚强 《地理信息世界》2002,(4)

根据我国测绘生产单位的实际情况 ,测绘项目管理的具体实施大致包括对项目的识别、选定、启动与筹集资金、计划、成本估算、执行计划、控制、收尾等主要步骤。当项目确定后 ,需要启动和筹集资金。而计划是项目管理的基本组成部分 ,包括明确项目目标和工作范围。项目成本估算有因素估算法和利用WBS方法的详细估算。项目质量管理规划的依据有质量目标、范围说明、标准和规范等。  相似文献   

Short-term Climate Characteristics at Ny-(A)lesund over the Arctic Tundra Area     

Deng Haibin  Lu Longhua  Bian Lingen 《极地研究(英文版)》2005,16(2)

Based on the Germany Koldwey Station's 1994-2003 conventional observation hourly data, this paper conducts a statistical analysis on the short-term climate characteristics for an arctic tundra region (Ny-(A)lesund island) where our first arctic expedition station (Huanghe Station) was located. Affected by the North Atlantic warming current, this area has a humid temperate climate, and the air temperature at Ny-(A)lesund rose above 0 ℃ even during deep winter season during our research period. The wind speed in this area was low and appeared most at southeast direction. We find that the temperature at Ny-(A)lesund rose in the faster rate (0.68 ℃/10 a) than those at the whole Arctic area. Compared with the floating ices where our expedition conducted in the Arctic, Ny-(A)lesund was warmer and more humid and had lower wind speed. Comparison of the near surface air temperature derived by NCEP/NCAR reanalysis to the conventional measurements conducted at the Koldwey site in Ny-(A)lesund area shows a good agreement for winter season and a significant difference for summer season.  相似文献   

Isobaric cooling and anti-clockwise P–T paths in the Variscan Odenwald Crystalline Complex, Germany     

T. M. Will  E. Schmädicke 《Journal of Metamorphic Geology》2003,21(5):469-480

Mineral assemblages in Al₂O₃‐rich, SiO₂‐ and K₂O‐poor metapelitic rocks from the western Odenwald Crystalline Complex (Variscan Mid‐German Crystalline Rise, southern Germany) include corundum, spinel, cordierite, sillimanite, garnet and staurolite. Quartz is absent from almost all samples. Therefore, the applicability of conventional geothermobarometry is very limited or even impossible. Detailed petrographic investigation on selected samples permits inference of the sequence of appearance and disappearance of several mineral assemblages. The recognition of such partial re‐equilibration stages and their associated mineral assemblages, together with mineral stabilities predicted from KFMASH pseudosections, enables the determination of the pressure‐temperature (P–T) trajectories experienced by these rocks during the Variscan metamorphism. The rocks were metamorphosed under low‐P/high‐T conditions and underwent an anti‐clockwise P–T evolution. A pressure increase from about 2 kbar to 4 ± 0.5 kbar was accompanied by heating. Peak metamorphic conditions were reached at pressures of 4 ± 0.5 kbar and temperatures of at least 640 °C, probably even higher. The retrograde evolution is characterised by near‐isobaric cooling from ≥ 640 °C to approximately 550 °C. The rocks underwent the anti‐clockwise evolution in a subduction‐related magmatic arc setting. The close spatial association of the low‐P/high‐T rocks with recently discovered metabasic eclogites in the eastern part of the Odenwald Crystalline Complex may indicate a fossil paired metamorphic belt in the Central European Variscides.  相似文献   

山西地震综合数据处理系统     

王玲英 《山西地震》1991,(1):4-24

《山西地震综合数据处理系统》是遵循《国家地震局数据库技术规范》,以PDP-11/23~+小型机与IBM/PC联机为硬件支撑,以网状型数据库为核心,含前期处理、库管理、数据检索、科学计算、分析会商5个子系统的较大型应用软件系统。具有对数据进行收集、录入、预处理、存储、管理、加工及应用等功能。整个系统通过总控菜单程序实现了异种机间上百个模块的调度,使查询-处理一体化。该系统把地震数据库、日常监测数据处理、专家地震预报系统有机地衔接于一体,可直接服务于地震科研和震情会商。该系统的建设是山西省重大科技攻关项目,也是国家地震局的合同制项目。  相似文献