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11.
《Chemie der Erde / Geochemistry》2017,77(1):81-93
The fresh and weathered garnet amphibolites, from the Akom II area in the Archaean Congo Craton, were investigated to determine the S, Cu, Ni, Cr, and Au-PGE values. The garnet amphibolites are composed of amphibole, plagioclase, garnet, quartz, and accessory apatite, spinel, sericite, pyrite, chalcopyrite and non-identified opaque minerals. The presence of apatite, sericite, and two generations of opaque minerals suggests that they might be affected by hydrothermal alteration. They are characterized by moderate Al2O3, Fe2O3, CaO, V, Zn, and Co contents with negative Eu- and Ce-anomalies. The sulfur concentrations are variable (380–1710 ppm). According to the sulfur contents, amphibolites can be grouped into two: amphibolites with low contents, ranging between 380 and 520 ppm (av. = 457 ppm); and amphibolites with elevated contents, varying from 1140 to 1710 ppm (av. = 1370 ppm). Amphibolites contain contrast amounts of Cu (∼ 1800 to 5350 ppm) while nickel contents attain 121 ppm. Chromium contents vary from 43 to 194 ppm. Sulfur correlates positively with Cu and Cr, but negatively with Ni and Ni/Cr ratio. The total Au-PGE contents attain 59 ppb.The presence of amphibole and feldspars confirms the low degree of amphibolite weathering. The secondary minerals are constituted of kaolinite, gibbsite, goethite and hematite. Despite the accumulation of some elements, the major and trace element distribution is quite similar to that of fresh amphibolites. Nevertheless, the weathering processes lead to the depletion of several elements such as S (239–902 ppm), Cu (520–2082 ppm), and Ni (20–114 ppm). Chromium and Au-PGE show an opposite trend marked by a slight enrichment in the weathered amphibolites. Amidst the Au-PGE, Pd (60 ppb) and Pt (23 ppb) have elevated contents in the fresh rocks as well as in the weathered materials. The PPGE contents are much higher than IPGE contents in both types of materials. The Pd/Pt, Pd/Rh, Pd/Ru, Pd/Ir, Pd/Os, and Pd/Au values indicate that Pt, Rh, Ru, Ir, Os and Au are more mobile than Pd. Chondrite-normalized base metal patterns confirm the abundance of Pd and the slight enrichment of Au-PGE in weathered rocks. Palladium, Rh and Ir are positively correlated with S. Conversely Pt and Ru are negatively correlated with S and Au is not correlated with S. Despite the high and variable S and Cu contents, the garnet amphibolites possess low Au-PGE and other base metals contents. 相似文献
12.
本文对秦岭岩群中的三个斜长角闪岩（变质沉积岩）样品进行了岩石学、锆石U-Pb年代学和岩石地球化学研究，限定了秦岭岩群的形成时代，讨论了秦岭岩群的构造背景及归属问题。锆石定年结果显示了971 Ma、1222 Ma和840 Ma三个最大沉积年龄。秦岭岩群是一个杂岩体，秦岭岩群中至少存在中元古代（较老组成部分）和新元古代早期（较新组成部分）的岩性单元。秦岭岩群变质沉积岩的锆石年龄峰主要集中在中元古代-新元古代早期，具有与扬子块体和华北块体明显不同的锆石年代学特征，秦岭岩群在中元古代-新元古代早期为独立发展的微陆块。结合秦岭岩群的年代学特征及前人的研究结果，秦岭岩群中的变质沉积岩应沉积于弧相关的构造环境。 相似文献
13.
Activities of titanite (Ttn, CaTiSiO5) and/or rutile (Rt, TiO2) phase components were calculated for 45 well‐characterized natural titanite‐ or rutile‐undersaturated epidote–amphibolites by using the equilibria: (i) 3 anorthite + 2 zoisite/clinozoisite + rutile + quartz = 3 anorthite + titanite + water (referred to as TZARS) and (ii) anorthite + 2 titanite = grossular + 2 rutile + quartz (referred to as GRATiS). In titanite‐bearing and rutile‐absent samples aRt is 0.75 ± 0.26. In titanite‐absent, rutile‐bearing samples aTtn is 0.89 ± 0.16. Mean values derived for aRt/aTtn are 0.92 ± 0.12 for rutile + titanite‐bearing samples and 0.42 ± 0.27 for samples lacking both titanite and rutile. Use of these values with TZARS yields pressure estimates for epidote–amphibolites that differ on average by <0.5 kbar from those recorded by established mineral barometers, even where both titanite and rutile are lacking. Despite rather large uncertainties in the average values obtained for aRt, aTtn or aRt/aTtn, application of TZARS yields pressure estimates that agree with independent estimates to within ±0.5 kbar for titanite‐ and/or rutile‐saturated samples, and to within ±0.8 kbar for samples that contain neither Ti‐phase. The accuracy and precision of the TZARS barometer are comparable to that of many well‐calibrated barometers. TZARS offers a much‐needed barometer for mafic rocks metamorphosed at epidote‐bearing amphibolite and blueschist facies conditions. In addition, the results provide a basis for application of other thermobarometers, such as Ti‐in‐zircon, where rutile activity is required as input. 相似文献
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15.
本文对胶南造山带变质岩系中角闪石的基本特征及形成条件进行了初步研究,根据不同地质单元中角闪石的类型、赋存状态、矿物组合等矿物学特点及电子探针分析结果,认为该区角闪石主要属钙质角闪石亚类。其形成的温压范围是：温度５４５～８０６．５℃,压力主要在０．２５～１．２ＧＰａ之间 相似文献
16.
西藏雅鲁藏布蛇绿岩带中段日喀则地区的白朗蛇绿混杂岩中,存在作为变质底板的石榴角闪岩。本文对其进行了矿物学、变质温压条件和岩石地球化学研究。根据岩相学和矿物化学研究,日喀则石榴角闪岩经历了四个变质阶段,矿物组合分别为:Am_1+Pl_1+Ep_1+Ttn(M1);Grt-c+Cpx-e+Ep_2+Pl_2+Rt(M2);Grt-r+Ep_3/Czo_3+Cpx-l+Am_3+Pl_3+Ttn(M3)和Prh+Ab+Czo+Chl+Cal(M4)。根据SAFMCNHO体系矿物组合演化的视剖面图,结合传统的地质温压计,估算出峰期前的温压条件为560~620℃/9.1~9.8kbar;峰值为830~870℃/18.0~22.0kbar,退变质阶段保留了640~680℃/10.7~14.9kbar的温压条件,最终止于葡萄石-绿纤石的前绿片岩相变质条件;得出一条逆时针的P-T轨迹。白朗变质底板的岩性可分为三类,即石榴角闪岩、角闪辉石岩和单辉角闪岩。三种岩性具有相似的地球化学性质:主量元素具有低钛(0.92%~1.29%)、低钾(0.26%)、低钠(0.24%~2.46%)的特征。稀土元素和微量元素特征与N-MROB相似,富集大离子亲石元素(Rb、Ba、U),亏损部分高场强元素(Nb、Ti、Zr、Hf),表现出白朗蛇绿混杂岩中的石榴角闪岩等与洋中脊玄武岩有亲缘性,且叠加有俯冲上板片SSZ环境特征。白朗石榴角闪岩的存在表明日喀则蛇绿岩在形成后不久就发生了构造就位,体现了大洋内部俯冲/侵位事件。 相似文献
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Beatrice Cappelli Luigi Carmignani Francesca Castorina Anselmo Di Pisa Giacomo Oggiano Riccardo Petrini 《Geodinamica Acta》2013,26(1-2):101-118
AbstractThe Hereynian basement of Northern Sardinia consists of two main teetonometamorphic complexes : the Southern Paleozoic Low to Medium Grade Metamorphic Complex (LMGMC) and the Northern (Precaimbrian ?) High Grade Metamorphic Complex (HGMC). These complexes are separateli bu the “Posada-Asinara Line” which is a several kilometer-wide mylonitie belt consisting of micaschist. parag-neiss and quartzite that cuts across all Northern Sardinia and contains scattered hodies of amphibolites with granulile and eclogite facies relies.Major element composition of ampbibolites indicates they were derived from metamorphosed basalts of tholciitie affinity. REE and the relative abundances of HKS elements strongly suggest an oceanic basaltie prololith (N- and T-typc MORB). A whole-rock Sm-Nd isochron for the amphibolite protoliths yields an age of ea. 960 Ma.The Northern Sardinia basement can he interpreted as a continental collisional zone with the “Posada-Asinara Line” representing a suture zone squeezed between a crustal nappe (HGMC), which represents the overthrust continental margin. and (he inner portion of the Varisean orogenie wedge, which represents the underthrust continental margin with its Paleozoic cover (LMGMC).Geological and geochemical evidence indicate that the “Posada-Asinara Line” may he considered as part of the South European Hereynian Suture Zone. 相似文献
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《International Geology Review》2012,54(7):863-881
Recent detrital zircon studies of metamorphosed and polydeformed rocks of the early Mesozoic Ayú Complex in southern Mexico suggest an allochthonous origin along the western Pangean margin. Bulk-rock geochemistry of the ca. 170–200 Ma ortho-amphibolites suggests a composition ranging from alkalic and transitional basalts to normalized mid-ocean ridge basalt (N-MORB) tholeiites. Rare earth element (REE) patterns of alkaline basalts (Group I) are characterized by steep negative slopes, whereas transitional basalts (Group II) show moderate light REE (LREE) enrichment. Subalkalic Group III displays slight LREE enrichment and Group IV has relatively flat REE patterns with slight depletion in LREEs. Multiple trace element plots of Group III–IV amphibolites reveal strongly negative Nb–Ta anomalies caused by subduction zone contamination. Initial ?Nd values (t = 190 Ma) of the amphibolites range from +9.01 to –2.16. Alkalic basalts have negative ?Nd values, suggesting derivation from an older subcontinental mantle source (T DM = 877 and 791 Ma). Group II–IV amphibolites have positive ?Nd values ranging from +2.31 to +9.01, indicating a transition from an older to a relatively juvenile mantle source that is typical of a back-arc setting. The geochemistry of the metasedimentary rocks suggests derivation from an acid-arc source. Chondrite-normalized REE patterns are characterized by enriched LREEs, flat HREE, and negative Eu anomalies. Sm–Nd systematics indicate that most samples were derived from cratonic basement and plot within the Oaxacan Complex envelope with ?Nd values (t = 195 Ma) ranging from –5.53 to –7.65. We interpret two samples with higher ?Nd values (–1.42 and +1.06) to reflect the additional influence of a more juvenile component. The amphibolites and metasedimentary rocks of the Ayú Complex document back-arc activity and are inferred to be correlative with various western Mexican Triassic–Jurassic mafic suites and the Potosí fan that formed along the western rifted margin of Pangea. 相似文献
19.
大别核部杂岩单元中斜长角闪岩的地球化学特征对于认识大别核部杂岩单元的特征及归属有着十分重要的意义。本文对大别核部杂岩单元中斜长角闪岩的岩石地球化学特征及Sm-Nd 同位素特征进行了较系统研究。斜长角闪岩的 Nd亏损地幔模式年龄(t_(DM))有3个不连续年龄段,它们分别为2.50～2.92Ga(平均2.71Ga);1.79～2.47Ga(平均2.14Ga);1.07～1.57Ga(平均1.38Ga)。模式年龄为中元古代、古元古代的斜长角闪岩的等时线年龄分别为1444±180Ma、2220±210Ma,其模式年龄与等时线年龄在误差范围内一致。表明至少模式年龄为元古宙的斜长角门岩的t_(DM)可代表其原岩的近似形成年龄,从而证明大别核部杂岩单元中存在着古元古代、中元古代两期自亏损地幔分异的基性火山岩变质形成的斜长角闪岩。而模式年龄为新太古代的斜长角闪岩,其模式年龄能否代表其形成年龄还需要进一步研究。各期斜长角闪岩在地球化学特征上的差异表现得不明显。通过对其原岩性质研究表明:原岩主要为拉斑玄武岩,少数为钙碱性玄武岩。大别核部杂岩中斜长角闪岩原岩ε_(Nd)(t)反映出大别核部杂岩地区上地幔自古元古代到中元古代一直沿着亏损地幔 Nd 同位素的演化线演化发展,这种性质及演化趋势与扬子北缘及南秦岭早期上地幔 Nd 同位素性质及演化趋势十分 相似文献
20.
Abstract Metre-scale amphibolite boudins in the Cheyenne Belt of south-eastern Wyoming are cut and deformed by shear zones which preserve a full strain transition across 7 cm, from relatively undeformed amphibolite with a relict igneous texture to mylonitic amphibolite with an L-S tectonic fabric. The strain transition is marked by the progressive rotation of amphibole + plagioclase aggregates into parallelism with the shear-zone boundary. An increase in strain magnitude is indicated by development of the tectonic fabric and progressive reduction of amphibole and plagioclase grain size as a result of cataclasis. Bulk chemistry of five samples across a single strain transition shows no significant or systematic variation in major element chemistry except for a minor loss of SiO2, which indicates that the shear zone was a system essentially closed to non-volatile components during metamorphism and deformation. Amphibolites throughout the shear zone consist of amphibole and plagioclase with only minor amounts of quartz, chlorite, epidote, titanite and ilmenite. Within the relatively undeformed amphibolite, amphibole and plagioclase have wide compositional ranges in single thin sections. Amphibole compositions vary from actinolitic hornblende to magnesio-hornblende with increases in Al, Fe, Na and K contents and decreases in Si and Mg that can be modelled as progress along tschermakite, edenite and FeMg-1 exchange vectors from tremolite. Plagioclase ranges from An60 in cores to An30 within grain-boundary domains. With increasing strain magnitude, local variation of amphibole composition decreases as amphibole becomes predominantly magnesio-hornblende. Plagioclase composition range also decreases, although grain-boundary domains still have higher albite content. These petrological data indicate that shear-zone metamorphism was controlled by the magnitude of strain during synmetamorphic deformation. SEM and microprobe imaging indicate that chemical reactions occurred by a dissolution and reprecipitation process during or after cataclastic deformation. This suggests that grain-boundary formation was an important process in the petrological evolution of the shear zone, possibly by providing zones for fluid ingress to facilitate metamorphic reactions. These results highlight the necessity for conducting detailed microstructural evaluation of rocks in order to interpret petrological, isotopic and geochronological data. 相似文献