X射线荧光光谱法测定重晶石中的硫酸钡方法研究   总被引：1，自引：0，他引：1  

陈景伟  宋江涛  陈朝阳 《岩矿测试》2017,36(4):382-387

应用XRF可快速测定重晶石中钡元素的总量,但当测定硫酸钡含量时,由于样品中的碳酸钡计入钡量造成硫酸钡的测定结果不准确,铜、铅、锌等有色金属元素对熔样坩埚会造成损害,需要进行酸处理除去碳酸钡、铅等干扰。而样品经酸处理后不同样品的剩余量不同,造成熔剂与样品的比例不确定,也不能准确测定硫酸钡的含量,因此保证熔剂与样品比例一致是解决该问题的关键。本文优化了样品前处理、熔片制样和仪器工作条件,将一定量样品以10%盐酸和10%硝酸溶解,过滤除去碳酸钡、硫酸钙及铜、铅、锌等有色金属元素,未溶解样品在700℃下灼烧后以氧化铝补充到原取样量,实现了熔剂与样品比例一致,再以硝酸铵作氧化剂,溴化锂和碘化铵作脱模剂,1075℃熔融制片,即可用XRF准确测定硫酸钡的含量。本方法的相对标准偏差(RSD)小于0.4%,检出限为72μg/g,较ICP-OES等方法的检测周期短、干扰元素少,提高了测试效率和分析质量。  相似文献   

对福建李坊重晶石矿床成因的新认识——来自矿石构造、矿物学和流体包裹体的证据     

黎敦朋  罗坤  肖爱芳  孔令添 《地质学报》2019,93(12):3095-3110

福建李坊重晶石矿床是东南沿海地区发现的一个大型独立重晶石矿床,已有30余年的开采历史,在沉积重晶石矿床中占有重要地位,然而对该矿床的成因和成矿时代仍众说纷纭。本文通过对福建李坊重晶石矿床中矿石组构的野外调查、电子探针分析和重晶石的流体包裹体测温,取得如下发现和认识:①首次在重晶石矿石中发现了管孔状构造、角砾状构造、蜂窝状构造等热水喷流通道相沉积构造;②首次在重晶石矿石中发现具有热水成因指示意义的同生钡冰长石矿物;③140个重晶石的流体包裹体均一温度值为89.3～208.5℃,均值为162.7℃,表明李坊重晶石矿床属于低温热水沉积矿床;综合矿石构造、矿物学和流体包裹体测温等证据,提出李坊重晶石矿床为"白烟囱型"热水沉积矿床的新认识,为华南地区早古生代热水沉积矿床的研究和找矿勘探提供了重要新资料。  相似文献   

Computing Lippmann Diagrams from Direct Calculation of Mixing Properties of Solid Solutions: Application to the Barite-Celestite System     

M. Prieto  A. Fernández-González  U. Becker  A. Putnis 《Aquatic Geochemistry》2000,6(2):133-146

The Lippmann diagram for the system(Ba, Sr)SO₄-H₂O was computed at 25 °Cby determining the solid-phase activity coefficientsfrom first principles calculations. Directcalculations of the mixing properties of thebarite-celestite series indicate this solid solutionbehaves as non-ideal and non-regular. At 25 °C,the enthalpy of mixing shows a minimum around 50 mole% SrSO₄ due to an ordering tendency. Thefree energy of mixing shows two minima that delimit awide and symmetric miscibility gap (from 2.1 to 97.9 mole% SrSO₄) at this temperature. The excessfree energy of mixing requires a Guggenheim expansionseries of 5 terms to be described, where the termswith odd exponents are null as a consequence of thesymmetric distribution of the mixing properties withcomposition. The Lippmann diagram shows a peritecticpoint that corresponds to the composition of an aqueoussolution which is simultaneously at equilibrium withthe two extremes of the miscibility gap. The largedifference between the solubility products of theendmembers involves a strong preferential partitioningof the less soluble endmember towards the solid phase,which explains the extremely Ba-poor composition ofthe aqueous solution (aqueous activity fraction forBa²⁺ = 0.000446 ) at the peritectic point.  相似文献   

我国重晶石矿床成因及成矿远景综述   总被引：4，自引：0，他引：4  

宣之强 《化工矿产地质》1999,21(1):24-30

我国重晶石矿床的形成受大陆裂谷系、弧-盆系和陆内挤隆系三种大地构造环境控制,多数矿床形成于大构造旋回的早期阶段,并与一定的岩相古地理环境及岩浆活动有关。矿床可划分为外生成因[沉积型、风化（残积坡积）型]和内生成因（火山-沉积型、层控型、热液型）等不同类型。成矿之钡源主要来自深部的火山-气液。矿床多在中、低温,弱酸性向弱碱性过渡的氧化环境的硫酸盐型成矿溶液中形成。中国重晶石矿具有较好的找矿前景,在一些工业需求地区,有发现新矿床的可能。  相似文献   

Geology and Genesis of Barite Deposits of Lasbela and Khuzdar Districts, Balochistan, Pakistan   总被引：1，自引：0，他引：1  

Syed Nayyer AHSAN  Khalil Ahmed MALLICK 《Resource Geology》1999,49(2):105-111

Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.  相似文献   

Multiple Sources of Metals of Mineralization in Lower Cambrian Black Shales of South China: Evidence from Geochemical and Petrographic Study   总被引：6，自引：0，他引：6  

Jan Pa&#;ava    Bohdan K&#;íbek    Anna Vymazalová    Ivana Sýkorová    Karel &#;ák  Beate Orberger 《Resource Geology》2008,58(1):25-42

Black shales of the Lower Cambrian Niutitang Formation in southern China (Huangjiawan mine, Zunyi region, northern part of the Guizhou Province) host regionally distributed stratiform polymetallic Ni‐Mo‐platinum group elements (PGE)‐Au phosphate‐ and sulfide‐rich ores. These are confined to a ≥0.2‐m thick ore horizon composed of mineralized bodies of algal onkolites, phosphate nodules, and sulfide and shale clasts in a mineralized phosphate‐ and organic matter‐rich matrix. Compared to footwall and hanging wall shales, the ore bed is strongly enriched in Ni (up to 100‐fold), As (up to 97‐fold), Mo (up to 95‐fold), Sb (up to 67‐fold), Rh (up to 49‐fold), Cu (up to 37‐fold), Pd (up to 33‐fold), Ru (up to 24‐fold), Zn (up to 23‐fold), Pt (up to 21‐fold), Ir (up to 15‐fold), Co (up to 14‐fold), and Pb (up to 13‐fold). Even footwall and hanging wall black shales are significantly enriched by Mo (21‐fold) and Ni (12‐fold) but depleted in Cr in comparison to average Cambrian black shale. Organic matter is represented by separate accumulations dispersed in the rock matrix or as biotic bitumen droplets and veinlets in ore clasts. Similar organic carbon (C_org) values in an ore bed and enclosing footwall and hanging wall shales of little mineralization indicate that metal accumulation was not controlled only by biogenic productivity and organic matter accumulation rate. Evaporitic conditions during sedimentation of the basal part of the Niutitang Formation were documented by an occurrence of preserved Ni‐, V‐, Cr‐, and Cu‐enriched phosphate‐rich hardground with halite and anhydrite pseudomorphs on the paleosurface of the underlying Neoproterozoic carbonates. Neoproterozoic black shales of the Doushantuo Formation are characterized by increased metal concentrations. Comparison of metal abundances in both hardground and Doushantuo black shales indicate that black shales could have become a source of metal‐rich hardground during weathering. The polymetallic Ni‐Mo‐PGE sulfide‐rich ore bed is interpreted to represent a remnant of shallow‐water hardground horizon rich in metals, which originated in a sediment‐starved, semi‐restricted, seawater environment. During the Early Cambrian transgression an influx of fresh seawater and intensive evaporation, together with the hydrothermal enrichment of seawater in a semi‐restricted basin, resulted in the formation of dense metalliferous brines; co‐precipitation of metals together with phosphates and sulfides occurred at or above the oxic–anoxic sediment interface. Metal‐enriched hardground was disintegrated by the action of waves or bottom currents and deposited in a deeper part of the anoxic basin. Contemporaneously with the formation of a polymetallic Ni‐Mo‐PGE‐Au sulfide ore bed, economic sedimentary exhalative (SEDEX)‐type barite deposits were forming in a stratigraphically and geotectonically similar setting. The results of geochemical study at the Shang Gongtang SEDEX‐type Ba deposit indicate that concentrations of Ag, As, Cr, Cu, Fe, Mn, Ni, Pb, Sb, V, Zn and other metals decrease from top of the barite body toward the hanging wall black shale. Lower Cambrian black shales of the Niutitang Formation above the barite body also display similar element abundances as Neoproterozoic black shales of the Doushantuo Formation, developed in the footwall of the barite body. But the geochemical composition of the sulfide layer is different from the Ni‐Mo ore bed, showing only elevated Pb, Cu, Ni and Mo values. It is suggested that hydrothermal brines at Shang Gongtang might have leached metals from footwall Neoproterozoic sequences and became, after mixing with normal seawater, an additional source of Ag, Cr, Cu, Pb, Sb, Zn, Ni, PGE, V and other metals.  相似文献   

黔东早寒武世早期重晶石富集机制研究——来自硫同位素的约束     

王富良  黄艺  付勇  龙克树  文星桥 《地球学报》2020,41(5):686-698

在中国, 早寒武世早期重晶石矿床主要展布于扬子地台北缘秦岭—大巴山一带及扬子地台东南缘湘黔地区, 而黔东天柱大河边重晶石矿床已探明的资源储量就达到了2亿多吨, 是全国, 乃至世界上所罕见的超大型重晶石矿床。近年来, 于大河边重晶石矿床北西翼亦发现了赋存于同一层位的云洞重晶石矿床, 但二者的成矿特征却表现出显著的差异。本文对比了含矿较差的云洞重晶石矿床与高品位大河边重晶石矿床的含矿岩系、沉积相、地球化学特征等。结果表明两者之间的缺氧程度、热水作用强度存在明显差异。综合矿床地质和有机质、硫同位素特征, 提出成矿作用与生物活动和同期海底热液活动关系密切, 矿床中SO2– 4来源于海水硫酸盐, Ba2+来自海水和海底热液。大河边地区与云洞地区相比, 水位更浅, 氧逸度更高, 硫酸盐还原程度更弱, 剩余硫酸盐的浓度更高, 从而导致云洞重晶石矿床表现出较大河边重晶石矿床成矿性差的特征。  相似文献   

重晶石矿石成分分析标准物质研制   总被引：3，自引：2，他引：1  

冯静  王瑞敏  张激光 《岩矿测试》2010,29(2):175-178

研制了7个重晶石矿石成分分析标准物质。其中,GSO-1为铁矿型重晶石,GSO-2、GSO-3为萤石型重晶石,GSO-4、GSO-5为石英型重晶石,GSO-6为硫化物型重晶石,GSO-7为黏土型重晶石。样品采用陶瓷衬里的球磨机加工,加工后样品粒度达到-0.074 mm。采用X射线荧光光谱法检验了钡、铜、铅、锌、锆、铝、硅、铁和钙共9种元素的均匀性,并进行振动试验。8个实验室参加定值工作,提供了硫酸钡、氧化钡、三氧化硫和锶的7个标准值,全三氧化二铁的2个标准值,氟化钙的1个标准值及铜、铅、锌和水溶盐等标准值或参考值。2009年4月,7个样品已被国家质量监督检验检疫总局批准为国家一级标准物质,编号为GBW 07811~GBW 07817。  相似文献   

陕西石梯钡矿床中流体包裹体特征及成因意义   总被引：1，自引：0，他引：1       下载免费PDF全文

吴胜华  刘家军  柳振江  翟德高  要梅娟 《中国地质》2010,37(5):1469-1479

陕西石梯重晶石-毒重石矿床产于南秦岭早古生代大型钡成矿带中。矿石类型有重晶石矿石、毒重石矿石、重晶石-毒重石混合矿石和钡解石矿石,但以重晶石矿石为主。经显微测温表明,重晶石中流体包裹体的均一温度范围为103.4～253.1℃(主峰值140～160℃),盐度范围为(0.35～10.73)wt%NaCleqv;毒重石中流体包裹体的均一温度范围为152.8～303.7℃(主峰值200～220℃),盐度范围为(0.18～9.73)wt%NaCleqv;钡解石中流体包裹体的均一温度范围为107.8～260.0℃(主峰值160～200℃),盐度范围为(0.71～8.41)wt%NaCleqv。经激光拉曼分析表明,在矿物流体包裹体的气相组成中,各矿物有一定差异:重晶石含一定量N2、H2S和CH4,毒重石含大量CO2和N2,而钡解石含有CO2、N2和CH4。成矿流体温度相对较高、富含CO2是形成毒重石的重要条件。  相似文献   

The influence of impurities on the dissolution of Ca- and Sr-bearing barite at room temperature     

张学洪  朱义年Ingrid Stober Kurt Bucher 《中国地球化学学报》2006,25(1):71-84

1INTRODUCTION BARITE(BASO4)ISANEXTREMELYINSOLUBLESALT;THISAROUSESPROBLEMSINPETROLEUMINDUSTRYBECAUSE BASO4ISAPARTICULARLYINTRACTABLESCALINGAGENT.BARITE PRECIPITATIONINTHEWELLBOREENVIRONMENTGENERALLYRE QUIRESMECHANICALREMOVAL,WITHCONSIDERABLEASSOCIAT EDEXPE…  相似文献