Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region     

Jorge Moreda-Piñeiro  Elia Alonso-Rodríguez  Isabel Turnes-Carou  Carmen Moscoso-Pérez  Gustavo Blanco-Heras  Loreto Gómez Tellado  Purificación López-Mahía  Soledad Muniategui-Lorenzo  Darío Prada-Rodríguez 《Journal of Atmospheric Chemistry》2017,74(1):1-21

The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl^?, NO₃ ^?, SO₄ ^2?, Na⁺, K⁺, Ca²⁺, Mg²⁺ and NH₄ ⁺) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites.  相似文献   

Crystal and molecular structure and spectroscopic behavior of isotypic synthetic analogs of the oxalate minerals stepanovite and zhemchuzhnikovite     

Oscar E. Piro  Gustavo A. Echeverría  Ana C. González-Baró  Enrique J. Baran 《Physics and Chemistry of Minerals》2016,43(4):287-300

The crystal structure of synthetic stepanovite, Na[Mg(H₂O)₆][Fe(C₂O₄)₃]·3H₂O, and zhemchuzhnikovite, Na[Mg(H₂O)₆][Al_0.55Fe_0.45(C₂O₄)₃]·3H₂O, has been determined by single-crystal X-ray diffraction methods. The compounds are isotypic to each other and to the previously reported Na[Mg(H₂O)₆][M(C₂O₄)₃]·3H₂O (M: Cr, Al). They crystallize in the trigonal P3c1 space group with Z = 6 molecules per unit cell and (hexagonal axes) a = 17.0483(4), c = 12.4218(4) Å for the iron compound, and a = 16.8852(5), c = 12.5368(5) Å for the Al/Fe solid solution. Comparison of our crystallographic results with previous X-ray diffraction and chemical data of type stepanovite and zhemchuzhnikovite minerals provides compelling evidence that these natural materials possess the same crystal and molecular structure as their synthetic counterparts. It is shown that the originally reported unit cell for stepanovite represents a pronounced sub-cell and that the correct unit cell and space group are based on weak superstructure reflections. The infrared and Raman spectra of both synthetic analogs were also recorded and are briefly discussed.  相似文献   

Estimation of monthly global solar irradiation using the Hargreaves–Samani model and an artificial neural network for the state of Alagoas in northeastern Brazil     

Gustavo Bastos Lyra  Sidney Sára Zanetti  Anderson Amorim Rocha Santos  José Leonaldo de Souza  Guilherme Bastos Lyra  José Francisco Oliveira-Júnior  Marco Antônio Maringolo Lemes 《Theoretical and Applied Climatology》2016,125(3-4):743-756

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A model of diffuse degassing at three subduction-related volcanoes     

Glyn Williams-Jones  John Stix  Martin Heiligmann  Anne Charland  Barbara Sherwood Lollar  N. Arner  Gustavo V. Garzón  Jorge Barquero  Erik Fernandez 《Bulletin of Volcanology》2000,62(2):130-142

2 and δ¹³C in soil gas were measured at three active subduction-related stratovolcanoes (Arenal and Poás, Costa Rica; Galeras, Colombia). In general, Rn, CO₂ and δ¹³C values are higher on the lower flanks of the volcanoes, except near fumaroles in the active craters. The upper flanks of these volcanoes have low Rn concentrations and light δ¹³C values. These observations suggest that diffuse degassing of magmatic gas on the upper flanks of these volcanoes is negligible and that more magmatic degassing occurs on the lower flanks where major faults and greater fracturing in the older lavas can channel magmatic gases to the surface. These results are in contrast to findings for Mount Etna where a broad halo of magmatic CO₂ has been postulated to exist over much of the edifice. Differences in radon levels among the three volcanoes studied here may result from differences in age, the degree of fracturing and faulting, regional structures or the level of hydrothermal activity. Volcanoes, such as those studied here, act as plugs in the continental crust, focusing magmatic degassing towards crater fumaroles, faults and the fractured lower flanks. Received: 16 December 1997 / Accepted: 27 January 2000  相似文献   

Geostatistical facies simulation with geometric patterns of a petroleum reservoir   总被引：1，自引：1，他引：0  

Paulo?Roberto?Moura?de?CarvalhoEmail author  Jo?o?Felipe?Coimbra?Leite?da?Costa  Luiz?Gustavo?Rasera  Luiz?Eduardo?Seabra?Varella 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(7):1805-1822

During exploration and pre-feasibility studies of a typical petroleum project many analyses are required to support decision making. Among them is reservoir lithofacies modeling, preferably using uncertainty assessment, which can be carried out with geostatistical simulation. The resulting multiple equally probable facies models can be used, for instance, in flow simulations. This allows assessing uncertainties in reservoir flow behavior during its production lifetime, which is useful for injector and producer well planning. Flow, among other factors, is controlled by elements that act as flow corridors and barriers. Clean sand channels and shale layers are examples of such reservoir elements that have specific geometries. Besides simulating the necessary facies, it is also important to simulate their shapes. Object-based and process-based simulations excel in geometry reproduction, while variogram-based simulations perform very well at data conditioning. Multiple-point geostatistics (MPS) combines both characteristics, consequently it was employed in this study to produce models of a real-world reservoir that are both data adherent and geologically realistic. This work aims at illustrating how subsurface information typically available in petroleum projects can be used with MPS to generate realistic reservoir models. A workflow using the SNESIM algorithm is demonstrated incorporating various sources of information. Results show that complex structures (e.g. channel networks) emerged from a simple model (e.g. single branch) and the reservoir facies models produced with MPS were judged suitable for geometry-sensitive applications such as flow simulations.  相似文献   

Comparison of the spatio-temporal distribution of the roughneck shrimp Rimapenaeus constrictus (Stimpson, 1874) (Crustacea,Penaeoidea) from monthly samples collected 20 years apart: Effects of a marine protected area in southeastern Brazil     

Veronica P. Bernardes  Aline N. Sousa  Camila H. Bernardo  Gustavo M. Teixeira  Rogério C. Costa  Fernando L. Mantelatto  Adilson Fransozo 《Marine Ecology》2020,41(5):e12605

This study was motivated by the data about a Rimapenaeus constrictus population from Ubatuba Bay, obtained in the 1990s, and by the establishment of a marine protected area (MPA) in the same region in 2008. We obtained comparable data about the distribution and abundance of this species collected 20 years apart, to evaluate the effectiveness of the MPA, for its preservation and possible changes in the populational profile. Biotic and abiotic data were obtained monthly, in September 1995–August 1996 (period 1 = 1ºP), and in September 2016–August 2017 (period 2 = 2ºP), from five transects within Ubatuba Bay. In total, 710 and 2,362 individuals were caught in the 1^oP and 2^oP, respectively. Despite this increase in abundance, aspects of the spatial distribution did not change substantially. The high abundance recorded at 5 m of depth was probably due to the creation of the MPA and to the accumulation of detritus at this depth. The high abundance seen in the transect sheltered from waves may be related to sediment heterogeneity, which was higher in this transect, and to the fact that this area is naturally protected from fisheries. In the 1ºP, the highest abundances were recorded in spring and summer, whereas in the 2ºP, they occurred in autumn and winter. This change may be explained by the entrance of the South Atlantic Central Water (SACW), which drives shrimps towards shallower areas. During the 2ºP, a fishing ban occurred in autumn (March 1st until May 31st), which is also when the SACW retreats and water temperature and salinity increase. These two factors combined may have been responsible for the increased shrimp abundance. In conclusion, both conservation practices (MPA and fishing ban) along with the existence of an area naturally protected from fisheries seem to have positively affected the population of R. constrictus, leading to an increase in abundance over the 20-year interval.  相似文献   

Ocean heat content for tropical cyclone intensity forecasting and its impact on storm surge   总被引：1，自引：0，他引：1  

I.-I. Lin  Gustavo J. Goni  John A. Knaff  Cristina Forbes  M. M. Ali 《Natural Hazards》2013,66(3):1481-1500

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Integrating the LISFLOOD‐FP 2D hydrodynamic model with the CAESAR model: implications for modelling landscape evolution     

Tom J. Coulthard  Jeff C. Neal  Paul D. Bates  Jorge Ramirez  Gustavo A. M. de Almeida  Greg R. Hancock 《地球表面变化过程与地形》2013,38(15):1897-1906

Landscape evolution models (LEMs) simulate the geomorphic development of river basins over long time periods and large space scales (100s–1000s of years, 100s of km²). Due to these scales they have been developed with simple steady flow models that enable long time steps (e.g. years) to be modelled, but not shorter term hydrodynamic effects (e.g. the passage of a flood wave). Nonsteady flow models that incorporate these hydrodynamic effects typically require far shorter time steps (seconds or less) and use more expensive numerical solutions hindering their inclusion in LEMs. The recently developed LISFLOOD‐FP simplified 2D flow model addresses this issue by solving a reduced form of the shallow water equations using a very simple numerical scheme, thus generating a significant increase in computational efficiency over previous hydrodynamic methods. This leads to potential convergence of computational cost between LEMs and hydrodynamic models, and presents an opportunity to combine such schemes. This paper outlines how two such models (the LEM CAESAR and the hydrodynamic model LISFLOOD‐FP) were merged to create the new CAESAR‐Lisflood model, and through a series of preliminary tests shows that using a hydrodynamic model to route flow in an LEM affords many advantages. The new model is fast, computationally efficient and has a stronger physical basis than a previous version of the CAESAR model. For the first time it allows hydrodynamic effects (tidal flows, lake filling, alluvial fans blocking valley floor) to be represented in an LEM, as well as producing noticeably different results to steady flow models. This suggests that the simplification of using steady flow in existing LEMs may bias their findings significantly. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Unique episodic groundwater recharge event in a South American sedimentary aquifer and its long-term impact on baseflow     

Maurício Dambros Melati  Fernando Mainardi Fan  Gustavo Barbosa Athayde  Pedro Antônio Roehe Reginato  Walter Collischonn  Camila de Vasconcelos Muller Athayde 《水文研究》2021,35(10):e14388

The anomalous entrance of water into groundwater systems can affect storage throughout long periods and normally relies on infrequent and irregular pulses of groundwater recharge defined by the term episodic recharge. Recently there was a groundwater recharge of large magnitude with unknown circumstances in the Caiuá aquifer. This unique event was explored in detail here and allowed to better understand the occurrence of such events in humid subtropical climates in South America. For this study, groundwater monitoring daily data from the Integrated Groundwater Monitoring Network was used combined with a specific yield obtained from geophysical wireline logging to obtain groundwater recharge rates. To improve the investigation, we also used a baseflow separation method to obtain the groundwater contribution into local rivers. The groundwater storage variations were also assessed by remote sensing with the GRACE data. Results showed the importance of high soil moisture storage on the occurrence of large episodic recharge events. We estimated that the groundwater recharger volumes derived from 1 year that included the unique episodic recharge observed (total of 866 mm for April 2015–March 2016) were comparable with the sum of 7 years of groundwater recharge (total of 867 mm). Atypical rainfall in winter periods were responsible for the increase in soil moisture that explained that unique event. GRACE-based GWS showed concordance detecting the occurrence of the unique episodic recharge. However, the variation in terms of volumes obtained by GRACE does not represent the behaviour observed in the aquifer by the WTF method. The results also indicated that changes in aquifer storage caused by episodic recharge events directly affect low flows in rivers over long periods. The main knowledge gap addressed here relates to exploring a unique episodic recharge event quite rare to observe with its long-term impacts on hydroclimatic variability over a humid subtropical portion of the Caiuá aquifer.  相似文献   

DDT in endangered Galapagos sea lions (Zalophus wollebaeki)     

Alava JJ  Ross PS  Ikonomou MG  Cruz M  Jimenez-Uzcátegui G  Dubetz C  Salazar S  Costa DP  Villegas-Amtmann S  Howorth P  Gobas FA 《Marine pollution bulletin》2011,62(4):660-671

We characterize for the first time the presence of DDT and its metabolites in tropical Galapagos sea lions (Zalophus wolleabeki). ∑DDT concentrations in Galapagos sea lion pups sampled in 2005 and 2008 ranged from 16 to 3070 μg/kg lipid. Concentrations of ∑DDT in pups in 2008 averaged 525 μg/kg lipid and were 1.9 times higher than that (281 μg/kg lipid) detected in pups in 2005. These concentrations are lower than those reported in many pinnipeds elsewhere, comparable to those in Hawaiian monk seals, and higher than those in southern elephant seals. The health risk characterization showed that 1% of the male pups exceeded the p,p′-DDE toxic effect concentration associated with anti-androgenic effects reported in rats. The findings provide preliminary guidance on the relationship between DDT use and ecological impacts, serving as a reference point against which possible future impact of tropical DDT use can be assessed.  相似文献