Sediment–water interactions of natural oestrogens under estuarine conditions     

J. C. Bowman  J. L. Zhou  J. W. Readman 《Marine Chemistry》2002,77(4)

The natural human female hormones oestrone and 17β-oestradiol have been implicated in the disruption of endocrine systems in some wildlife adjacent to sewage effluents. The sorption behaviour of these two compounds under estuarine conditions was studied by spiking either 2.55 μg of oestrone or 2.65 μg of 17β-oestradiol in kinetic experiments. In equilibrium experiments, 3 ng of oestrone or 3.2 ng of 17β-oestradiol was added in each of the centrifuge tubes. Sorption onto sediment particles was relatively slow, with sorption equilibrium being reached in about 70 and 170 h for oestrone and 17β-oestradiol, respectively. The effects of a variety of environmental parameters on sorption were studied including salinity, sediment concentration (SC), the presence of a third phase, particle size and, also, surfactant concentrations. Results show that although salinity did not induce any statistically significant effect on the sorption of 17β-oestradiol, it did statistically enhance the sorption of oestrone, and a salting constant of 0.3 l mol⁻¹ was derived. The partition coefficient for both compounds decreased with increasing sediment concentration, a phenomenon that has been widely reported and attributed to the presence of colloids (which could enhance dissolved concentrations). In this paper, the true partition coefficients for sediment particles (K_p^true) and colloidal particles (K_c^true) have been calculated, and a K_p^true value of 141 and 102 ml g⁻¹ was obtained for oestrone and 17β-oestradiol, respectively. In addition, K_c^true values for oestrone (222×10² ml g⁻¹) and 17β-oestradiol (135×10² ml g⁻¹) were two orders of magnitude higher than their respective K_p^true values, suggesting that the colloidal particles are significantly stronger sorbents for natural oestrogens than sediment particles. Particles of different sizes were found to have different partition coefficients due to the strong relationships between partition coefficients for the two compounds and particulate organic carbon (POC) contents and specific surface areas (SSAs). The presence of a surfactant was shown to reduce the partition coefficients for the two compounds, although its concentrations being used were higher than those normally found in the natural environment.  相似文献   

Comparison between zooplankton data collected by the Continuous Plankton Recorder survey in the English Channel and by WP-2 nets at station L4, Plymouth (UK)     

Eurgain H. John  Sonia D. Batten  Roger P. Harris  Graeme C. Hays 《Journal of Sea Research》2001,46(3-4)

Zooplankton sampling has been carried out by the Continuous Plankton Recorder (CPR) survey since the 1930s enabling the study of long-term changes in plankton populations, the elucidation of seasonal patterns of abundance, and more recently providing zooplankton biomass estimates for ecosystem models. Data for zooplankton abundance collected by CPR tows in the Western English Channel (between 1988 and 1998) were compared to vertically integrated samples collected from station L4 off Plymouth, UK. Comparisons were made for locally abundant copepods (including Acartia, Calanus, Para/Pseudocalanus, Centropages, Oithona and Temora) collected by CPR and WP-2 nets. All dominant species recorded at L4 were also common to the CPR data. However, the position of the taxa in the two datasets was not equivalent. Seasonal cycles revealed by CPR data were significantly similar to those recorded throughout the water column at L4 for most taxa. However, absolute levels of abundance differed for the two datasets: abundances were underestimated by CPR samples when compared to those of vertically integrated samples by a factor of between 2 and 35, with the exception of Centropages. The differing mesh sizes (200 and 270 μm) of the WP-2 net and CPR mesh could only partially explain these differences in abundance, implying that the behaviour of individual taxa and their depth in the water column also influenced the abundance recorded.  相似文献   

崂山花岗岩地区含锶、偏硅酸矿泉水的形成机理   总被引：1，自引：0，他引：1  

赵广涛  曹钦臣  孙悦鹏 《中国海洋大学学报(自然科学版)》1996,(2)

报道了崂山花岗岩地区矿泉水的特征。指出其矿泉类型为含锶、偏硅酸型，并讨论了其形成机理。  相似文献   

城市与工程测量EDM导线技术标准的分析   总被引：1，自引：0，他引：1  

严伯铎  任晔平 《海洋测绘》2006,26(4):15-20

基于导线测量误差理论与电磁测距(EDM)导线的特性,分析讨论了城市与工程测量EDM导线的各项技术参数,提出了各级EDM导线技术标准的建议,通过计算验证所给出的这些技术指标是合理可靠的。  相似文献   

Introduction     

Carscadden  J. E.; Vilhjalmsson  H. 《ICES Journal of Marine Science》2002,59(5):863-869

  相似文献   

Fe(OH)_3胶体与铜离子作用的研究     

张恩仁  田玉红  张正斌  刘莲生 《热带海洋学报》2001,(4)

使用切向流超滤系统得到粒度较均匀的Fe(OH)3胶体,进而对Fe(OH)3胶体粒子与Cu2 的作用进行了研究,并将实验结果与南沙群岛海区表层水中铜与胶体物质结合状况的调查数据进行了比较分析,得到如下结果:(1)在海水介质中,铜在Fe(OH)3胶体上结合的百分率(pH>5)随pH的升高而下降,随着Fe(OH)3胶体浓度的减小而下降?(2)在天然海水介质中,使铜在Fe(OH)3胶体上结合的百分率在50%-70%的有机物浓度为1.0mg·L-1,有机物浓度的增大使铜与无机胶体结合的百分率有下降的趋势?  相似文献   

起算点精度对GPS基线解算质量的影响   总被引：1，自引：0，他引：1  

谢劭峰  王新桥 《海洋测绘》2006,26(6):22-24

基线处理时要求知道一个点的坐标,其精度对GPS基线的解算结果有影响。采用实测数据研究起算点精度对GPS基线解算质量的影响,得出了其影响规律,同时给出了提高起算点精度的方法。  相似文献   

夏季东海西部表层海水中的pCO₂及海-气界面通量   总被引：10，自引：0，他引：10  

谭燕  张龙军  王凡  胡敦欣 《海洋与湖沼》2004,35(3):239-245

根据2001年夏季长江口及东海西部海域表层海水pCO  相似文献   

Should total landings be used to correct estimated catch in numbers or mean weight-at-age?     

Lewy  Peter; Lassen  Hans 《ICES Journal of Marine Science》1997,54(3):462-470

  相似文献   

南沙群岛南永2井沉积层"红色事件"和"黑色事件"的成因探讨     

姚衍桃  詹文欢 《热带海洋学报》2006,25(6):39-46

南沙群岛南永2井的红色沉积层和黑色沉积层标志着两次异常事件,简称为“红色事件”和“黑色事件”。这两个特殊沉积层的主要特征是磁化率为正值、锰铝(黑色沉积)和铁铝(红色沉积)含量高。关于它们的成因主要有两种观点:一种是火山喷发或地震活动,另一种是气候突变。将红色沉积层和黑色沉积层与南海其它珊瑚礁钻井资料、南海及其周缘火山活动和深海沉积中的微玻陨石进行详细对比,并综合分析几种成因的可能性大小。“红色事件”和“黑色事件”在南海其它珊瑚礁钻井中的反映不明显或无反映,表明两事件的影响范围很有限。尽管南海周缘的一些火山活动期次、全球气候变化的一些代用指标和深海沉积中的微玻陨石层在时间上与“红”、“黑”两事件有较好的对比,成岩作用也能使某些沉积层位形成铁富集或锰富集,但综合考虑各个因素可以排除周缘火山喷发、气候突变、撞击事件及成岩作用等4种成因。火山或地震活动引起的铁或锰热泉上涌可以对“红”、“黑”两事件作出较好的解释,是可能性较大的成因。  相似文献