CZM-2型恒流自动充电器     

田树德 《东北地震研究》2003,19(2):73-76

介绍了CZM—2型恒流器自动充电器的主要特性、电路工作原理、安装和调试方法。  相似文献   

煤中发现镉矿物   总被引：2，自引：0，他引：2  

丁振华  FinkelmamRB 《地质地球化学》2002,30(2):95-96

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2.5次微分极谱溶出伏安法测定土壤中的镉＊     

袁倬斌  薛永军 《岩矿测试》1989,8(1):39-41

本文报告在悬汞电极上,用2.5次微分极谱阳极溶出伏安法测定环境标准参考物质——北京土壤中镉含量的方法。在0.37mol/L氨缓冲液-0.05mol/L KCl底液中,镉有一个良好的溶出极谱峰,其线性范围为1～100ng/ml,检测限为lng/g。土壤样品干燥后在聚四氟乙烯高压治解瓶中,用硝酸、氢氟酸、高氯酸消化(在180℃的空气浴中进行),蒸干后用0.01mol/L硝酸溶解、定容再加入底液进行测定。铅、铜、锌、铬、铁等不干扰测定。  相似文献   

天然水中痕量铜,镉,锌的催化极谱波测定     

何醒群  王义珍 《广东地质实验》1991,(19):48-56

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Comparative Studies on Uptake Pathway of Cadmium by Perna viridis     

FANG Zhanqiang 《中国海洋大学学报(英文版)》2006,5(1):49-54

Experiments were designed to expose the filter-feeding bivalve Perna viridis to different Cd-contaminated water environments in order to compare the different pathways through which Cd is accumulated. Results show that mussels can accumulate Cd through seawater, food, sediment and suspended particle pathways in a short period of time. Mussels＇ uptake of Cd through the seawater pathway reaches the highest concentration approximately 3 and 9 times larger than through the algae and sediment pathways respectively after 7 d. This indicates that the Cd-accumulation through seawater is most efficient. Results also indicate that the uptake directly through contaminated algae, particles or sediments ingested by mussels is less important when compared with the uptake of Cd by mussels through the seawater pathway. Metal uptake pathways and mechanisms of bioaccumulation by marine bivalve are also discussed in this paper.  相似文献   

Removal of Cadmium Ions from Aqueous Solution by Silicate-incorporated Hydroxyapatite          下载免费PDF全文

SHI Hebin ZHONG Hong LIU Yu DENG Jinyang 《《地质学报》英文版》2007,81(3):517-522

This article reports a preliminary research on silicate-incorporated hydroxyapatite as a new environmental mineral used to remove cadmium ions from aqueous solutions. The silicate-incorporated hydroxyapatite was prepared by coprecipitation and calcining, and silicate was incorporated into the crystal lattice of hydroxyapatite by partial substitution of phosphate. The amount of cadmium ions removed by silicate-incorporated hydroxyapatite was significantly elevated, which was 76% higher than that of pure hydroxyapatite. But the sorption behavior of cadmium ions on silicate-incorporated hydroxyapatite was similar to that of pure hydroxyapatite. Morphological study revealed that silicate incorporation confined the crystal growth and increased the specific surface area of hydroxyapatite, which were in favor of enhancing the cadmium ion sorption capacity of the samples. Incorporation of silicate into hydroxyapatite seems to be an effective approach to improve the environmental property of hydroxyapatite on removal of aqueous cadmium ions.  相似文献   

云南金顶超大型铅锌矿区镉的地球化学特征及其环境效应   总被引：11，自引：0，他引：11  

李航  叶霖  肖唐付  潘自平  何立斌  孙嘉龙  宁增平  彭景权 《矿物学报》2007,27(2):225-232

云南金顶铅锌矿是镉元素富集区,采矿活动导致镉元素释放出来进入地表环境造成镉污染。矿区不同岩石中镉分布差异比较大,围岩中镉含量范围在50×10-6~650×10-6之间,平均310×10-6,原生矿中镉含量范围14×10-6~2800×10-6,平均767×10-6,氧化矿中镉含量范围110×10-6~8200×10-6,平均1661×10-6,其平均值最高。氧化矿是镉元素的主要载体和释放源。淋滤实验表明矿石易氧化而释放出镉等有害元素,滤出元素可以迅速发生沉淀或被沉淀物包裹,其能力表现为Zn>Pb>Cd。研究结果表明,矿区下游江河段水体中隔的平均值为15.7μg/L,悬浮物中镉平均值为49.3 mg/kg,沉积物中镉平均值为203.7 mg/kg。矿区富镉岩石和矿物的自然风化是造成江水体和沉积物中镉污染的直接原因,对流域水生态环境造成潜在危害。  相似文献   

土壤对镉离子的竞争吸附研究——以北京城近郊为例   总被引：1，自引：1，他引：1  

王亚平潘小菲  许春雪冯绍元 王苏明 《岩矿测试》2007,26(4):251-256

对分别采自北京城近郊丰台区北天堂村、大兴区庑殿村、通州区永乐店镇、海淀区四季青乡和朝阳区来广营乡5个典型地区的土壤进行了Cd^2＋-Na^＋、Cd^2＋-Ca^2＋、Cd^2＋-Zn^2＋双阳离子竞争性静态吸附试验。结果表明，在不改变土壤的物理化学性质条件下，多种离子共同竞争吸附时，其吸附过程与单个外源金属阳离子的吸附结果不同；不同类型土壤对镉的吸附受钠、钙、锌离子的影响不是单方面的抑制作用或促进作用，影响机制随着外源镉离子浓度和外源钠、钙、锌离子浓度的大小而各异，而且其影响程度也有所不同。  相似文献   

不同原子光谱法用于环境介质中镉测定的比较     

王芬  彭国照 《高原山地气象研究》2007,27(4)

镉是重金属有毒元素,其对环境和人类健康危害极大.各国都制定一些强制性标准以限制镉对环境的污染与危害.为了准确测定镉的含量,国内外对镉的分析方法进行了广泛深入的研究.本文评述了近年来国内运用原子光谱法对镉的检测的研究进展,包括原子吸收光谱法,原子发射光谱法,原子荧光光谱法,并对上述方法作了比较.  相似文献   

镉、铅在某些河流环境中迁移净化机理的研究     

黎秉铭 《地球化学》1983,(2):205-212

It has been found that Pb and Cd can be gradually purified during their transportation in rivers and that the rate of purification for Pb is much greater than that of Cd,Such process is not only closely related to the degree of water dilution and the properties of Pb and Cd themselves, but also to the existing ligands, oxidation-reduction conditions, colloids, pH and other factors in the aquatic environment. Suspended particles and river-bed sediments have a strong ability of adsorption and purification with respect to Pb and Cd. This ability shows a positive correlation with the composition of clay in sediments on the river bed, but a negative correlation with the grain-size of quartz particles. our results indicate that both the adsorption and possible desorption of Pb and Cd in river-bed sediments and suspended particles may be highly responsible for the variations in Pb and Cd concentrations in aquatic environments. The dynamic adsorptiondesorption balance of Pb and Cd between riverbed sedimeuts and water varies with pH.It may be favorable for the purification of Pb and Cd in aquatic environments if pH is adjusted to slightly alkaline within the tolerance of environmental capacity.  相似文献