Cu2+对序批式反应器中活性污泥胞外聚合物产量及其组分的影响     

李姗姗  朱四富  马丙瑞  于娜玲  赵长坤  信帅帅  潘云浩  吴淑妍  武原原  高孟春 《中国海洋大学学报(自然科学版)》2020,(2):107-115

研究了长期暴露条件下Cu2+对序批式反应器(SBR)性能及其活性污泥胞外聚合物(EPS)特性的影响。结果表明,进水中加入10 mg·L-1的Cu2+后,在SBR运行的第16~55天,COD和NH+4-N的去除率保持稳定;在第56~75天,COD和NH+4-N的平均去除率与进水Cu2+浓度为0 mg·L-1时相比分别下降了3.88%和6.41%。浓度为10 mg·L-1的Cu2+长期作用下,活性污泥中EPS、松散附着EPS(LB-EPS)和紧密附着EPS(TB-EPS)产量及LB-EPS和TB-EPS中蛋白质(PN)含量增加。傅里叶变换红外光谱分析表明10 mg·L-1 Cu2+的长期暴露导致TB-EPS中PN的C=O键、N-H键和C-O键相对含量降低。X射线光电子能谱(XPS)测试结果显示在10 mg·L-1 Cu2+长期暴露条件下,LB-EPS和TB-EPS中元素Cu和O百分含量增加。  相似文献   

Global Statistical Assessment and Cross-Calibration with Jason-2 for Reprocessed HY-2 A Altimeter Data     

Maofei Jiang  Ke Xu  Yalong Liu 《Marine Geodesy》2018,41(3):289-312

HY-2 A (Haiyang-2 A) satellite was launched on August 16, 2011 and radar altimeter is one of its main payloads. We reprocessed two years of HY-2 A altimeter sensor geophysical dataset records (SGDR) data. This paper presents the main results in terms of reprocessed HY-2 A altimeter data quality: verification of data availability and validity, monitoring several relevant altimeter parameters, and assessment of the HY-2 A altimeter system performances. A cross-calibration analysis of reprocessed HY-2 A altimeter data with Jason-2 was conducted. The reprocessed HY-2 A altimeter data show good quality and have a low level of noise with respect to Jason-2. The same geophysical correction methods were used to calculate the sea surface height (SSH) for the two missions. The mean standard deviations of the crossover differences for HY-2 A and Jason-2 are 5.24 cm and 5.34 cm, respectively. The mean standard deviation of the crossover differences between HY-2 A and Jason-2 is 5.37 cm. These show that HY-2 A can provide SSH measurements at almost the same level of accuracy as Jason-2. The relative SSH bias between HY-2 A and Jason-2 due to the Ultra Stable Oscillator (USO) drift is obviously observed, and it can affect the calculation of mean sea level and should be further studied and corrected.  相似文献   

随机森林模型在遥感水深反演中的应用     

邱耀炜  沈蔚  纪茜 《海洋技术学报》2019,38(5)

随着我国浅海测绘需求的日益增长,文中利用四波段的WorldView-2高分辨率遥感影像,选取我国南海西沙群岛中的甘泉岛和台湾南湾地区作为典型试验区,开展水深反演研究。引入随机森林算法构建了随机森林水深反演模型,并同常用的3种水深反演模型进行精度对比。结果表明,在甘泉岛和南湾地区随机森林模型反演的水深值和真实水深值的RMSE分别为0.85 m和1.59 m,MRE分别为8%和12%,均优于其他3种模型。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Mapping wetland characteristics using temporally dense Sentinel-1 and Sentinel-2 data: A case study in the St. Lucia wetlands,South Africa     

《International Journal of Applied Earth Observation and Geoinformation》2020

Wetlands have been determined as one of the most valuable ecosystems on Earth and are currently being lost at alarming rates. Large-scale monitoring of wetlands is of high importance, but also challenging. The Sentinel-1 and -2 satellite missions for the first time provide radar and optical data at high spatial and temporal detail, and with this a unique opportunity for more accurate wetland mapping from space arises. Recent studies already used Sentinel-1 and -2 data to map specific wetland types or characteristics, but for comprehensive wetland characterisations the potential of the data has not been researched yet. The aim of our research was to study the use of the high-resolution and temporally dense Sentinel-1 and -2 data for wetland mapping in multiple levels of characterisation. The use of the data was assessed by applying Random Forests for multiple classification levels including general wetland delineation, wetland vegetation types and surface water dynamics. The results for the St. Lucia wetlands in South Africa showed that combining Sentinel-1 and -2 led to significantly higher classification accuracies than for using the systems separately. Accuracies were relatively poor for classifications in high-vegetated wetlands, as subcanopy flooding could not be detected with Sentinel-1’s C-band sensors operating in VV/VH mode. When excluding high-vegetated areas, overall accuracies were reached of 88.5% for general wetland delineation, 90.7% for mapping wetland vegetation types and 87.1% for mapping surface water dynamics. Sentinel-2 was particularly of value for general wetland delineation, while Sentinel-1 showed more value for mapping wetland vegetation types. Overlaid maps of all classification levels obtained overall accuracies of 69.1% and 76.4% for classifying ten and seven wetland classes respectively.  相似文献   

Targeting rare earth element bearing mine tailings on Bangka Island,Indonesia, with Sentinel-2 MSI     

《International Journal of Applied Earth Observation and Geoinformation》2020

A laboratory study on rare earth element bearing mine tailings, collected from Bangka Island, Indonesia, reported a new spectral absorption feature at 674 nm associated with Erbium. The present study aims to evaluate the capability of the European Space Agency’s Sentinel-2 MSI sensors to detect this absorption feature from space. An arithmetic band operation is performed on selected visible and near-infrared spectral bands of a Sentinel-2 image. The results show that Sentinel-2 MSI is capable of detecting the 674 nm Erbium-related absorption feature within the particular environmental setting of the study area.  相似文献   

Estimating aboveground biomass of the mangrove forests on northeast Hainan Island in China using an upscaling method from field plots,UAV-LiDAR data and Sentinel-2 imagery     

《International Journal of Applied Earth Observation and Geoinformation》2020

The mangrove forests of northeast Hainan Island are the most species diverse forests in China and consist of the Dongzhai National Nature Reserve and the Qinglan Provincial Nature Reserve. The former reserve is the first Chinese national nature reserve for mangroves and the latter has the most abundant mangrove species in China. However, to date the aboveground ground biomass (AGB) of this mangrove region has not been quantified due to the high species diversity and the difficulty of extensive field sampling in mangrove habitat. Although three-dimensional point clouds can capture the forest vertical structure, their application to large areas is hindered by the logistics, costs and data volumes involved. To fill the gap and address this issue, this study proposed a novel upscaling method for mangrove AGB estimation using field plots, UAV-LiDAR strip data and Sentinel-2 imagery (named G∼LiDAR∼S2 model) based on a point-line-polygon framework. In this model, the partial-coverage UAV-LiDAR data were used as a linear bridge to link ground measurements to the wall-to-wall coverage Sentinel-2 data. The results showed that northeast Hainan Island has a total mangrove AGB of 312,806.29 Mg with a mean AGB of 119.26 Mg ha⁻¹. The results also indicated that at the regional scale, the proposed UAV-LiDAR linear bridge method (i.e., G∼LiDAR∼S2 model) performed better than the traditional approach, which directly relates field plots to Sentinel-2 data (named the G∼S2 model) (R² = 0.62 > 0.52, RMSE = 50.36 Mg ha⁻¹<56.63 Mg ha⁻¹). Through a trend extrapolation method, this study inferred that the G∼LiDAR∼S2 model could decrease the number of field samples required by approximately 37% in comparison with those required by the G∼S2 model in the study area. Regarding the UAV-LiDAR sampling intensity, compared with the original number of LiDAR plots, 20% of original linear bridges could produce an acceptable accuracy (R² = 0.62, RMSE = 51.03 Mg ha⁻¹). Consequently, this study presents the first investigation of AGB for the mangrove forests on northeast Hainan Island in China and verifies the feasibility of using this mangrove AGB upscaling method for diverse mangrove forests.  相似文献   

DFT对Rb⁺水合团簇及其相关性质的分析          下载免费PDF全文

张文倩  葛蒲  房春晖  周永全  朱发岩  刘红艳  李武 《盐湖研究》2019,27(3):81-92

运用密度泛函理论(DFT)在ωB97XD/gen (O、H元素Aug-cc-PVDZ; Rb元素Lanl2DZ)基组水平上研究了[Rb(H_2O)_n]~+(n=1～12)水合团簇的结构和光谱学性质。研究结果表明,通过分析气相和液相中的稳定能以及水合团簇可知,稳定构型出现在8配位的团簇中。第一配位层水分子数为8时形成Rb~+第一近似饱和水合层。此外,拉曼光谱显示[Rb(H_2O)_n]~+(n=1～12)水合团簇中O-H伸缩振动峰随着水分子数增加发生移动和加宽,Rb~+发生水合时,O-H对称和非对称伸缩振动发生红移,随着水合数的增多,频率蓝移。此外,文中对拉曼光谱中O-H振动的频率位置结合团簇结构进行了说明。  相似文献   

基于新型高频声学多普勒流速剖面仪的河口近底部边界层观测初探     

兰庭飞  吴昊  唐杰平  李占海  汪亚平 《海洋通报》2019,38(6):640-649

河口物质输运、能量交换与底边界层内的水动力过程密切相关,底边界层参数(如切应力、拖曳系数)的确定至关重要。挪威Nortek公司生产的新型声学多普勒流速剖面仪AD2CP相比传统ADCP具有高频、低噪的优点,可用于高频(16Hz)流速剖面观测,而被广泛应用于底边界层观测的ADV只能测量单点高频流速。本文采用AD2CP在长江口南槽最大浑浊带区域进行座底式观测,并与同步近底部三脚架上ADV的观测结果进行对比。结果表明,使用AD2CP测得的近底部平均流速与ADV的测量结果吻合良好;使用惯性耗散法计算了底切应力,基于ADV的单点高频流速数据计算结果为2.16×10~(-2)～5.69×10~(-1)N/m~2,基于AD2CP的结果为2.09×10~(-2)～4.26×10~(-1)N/m~2,二者范围大致相当。在此基础上,基于AD2CP数据计算出摩阻流速为4.55×10~(-3)～2.06×10~(-2)m/s、底拖曳系数范围为1.84×10~(-4)～2.49×10~(-3),与ADV的计算结果基本一致。此外,由于AD2CP可以获得高频的流速剖面数据,优于单点ADV,具备观测近底部边界层参数和边界层内湍流剖面的潜力。  相似文献   

可见光下Li+/CNTS-TiO2光催化剂降解海洋柴油污染的研究          下载免费PDF全文

于晓彩  王力萍  刘京华  郭美岑  朱婉婷  廖佳琪  吴云英 《海洋学研究》2019,37(1):52-58

通过溶胶-凝胶法,以CNTS-TiO₂为前驱物制备了Li⁺掺杂CNTS-TiO₂的纳米复合光催化剂(以下均称为Li⁺/CNTS-TiO₂),采用X射线衍射(XRD)、扫描电镜(SEM)等测试手段对光催化剂进行表征,结果表明制得的催化剂为纳米材料且在TiO₂的基础上增大了比表面积。利用掺杂量为3%的Li⁺掺杂CNTS-TiO₂复合光催化剂(以下均称为3%Li⁺/CNTS-TiO₂)光催化降解海洋柴油污染,在可见光条件下考察了Li⁺掺杂量、煅烧温度、光催化剂投加量、柴油初始质量浓度、光催化反应时间、H₂O₂质量浓度等条件对光催化实验的影响。进行正交实验,确定最优化工艺条件为:Li⁺掺杂量为3%,光催化剂的煅烧温度为600 ℃,3%Li⁺/CNTS-TiO₂的投加量为0.1 g/L,降解柴油初始质量浓度为0.4 g/L,光催化反应时间为3 h,H₂O₂质量浓度为0.6 g/L,降解率可以达到95%以上。同时对此光催化剂进行应用试验,试验结果表明光催化剂去除效果优异,去除率可达91.87%。  相似文献