Slip rates variability and sediment mobilization on a shallow landslide in the northern Swiss Alps     

Marco Schwab  Christine Läderach  Dirk Rieke-Zapp  Fritz Schlunegger 《Swiss Journal of Geoscience》2007,100(2):281-292

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Stratigraphic filtering and source penetration depth     

Mirko van der Baan  James Wookey  Dirk Smit 《Geophysical Prospecting》2007,55(5):679-684

Seismic exploration underneath highly heterogeneous layers such as basalt flows is possible by lowering the principal source frequency. Unfortunately this also reduces resolution. Wave‐localization theory is a multiple scattering theory that can be used to study stratigraphic filtering in chaotic lithologies. It predicts the apparent attenuation due to scattering of a plane wave traversing a layer with high velocity fluctuations. It can therefore predict the optimum principle source frequency in the trade‐off between loss of resolution and increased penetration depth. We show how this can be done with the help of a few statistical parameters derived from a well‐log analysis; namely, the average background velocity, the expected standard deviation in the velocity fluctuations, the typical scale length of the heterogeneities and the thickness of the basalt layer. In the likely situation that no local well logs exist, a multitude of scenarios can easily be examined at low cost.  相似文献   

On the meridional circulation and balance of momentum in the Southern Ocean of POP     

Dirk Olbers  Vladimir O. Ivchenko 《Ocean Dynamics》2001,52(2):79-93

 The circulation of the Southern Ocean is studied in the eddy-resolving model POP (Parallel Ocean Program) by an analysis of zonally integrated balances. The TEM formalism (Transformed Eulerian Mean) is extended to include topography and continental boundaries, thus deviations from a zonally integrated state involve transient and standing eddies. The meridional circulation is presented in terms of the Eulerian, eddy-induced, and residual streamfunctions. It is shown that the splitting of the meridional circulation into Ekman and geostrophic transports and the component induced by subgrid and Reynolds stresses is identical to a particular form of the zonally integrated balance of zonal momentum. In this balance, the eddy-induced streamfunctions represent the interfacial form stresses by transient and standing eddies and the residual streamfunction represents the acceleration of the zonal current by density fluxes in a zonally integrated frame. The latter acceleration term is directly related to the surface flux of density and interior fluxes due to the resolved and unresolved eddies. The eddy-induced circulation is extremely vigorous in POP. In the upper ocean a shallow circulation, reversed in comparison to the Deacon cell and mainly due to standing eddies, appears to the north of Drake Passage latitudes, and in the Drake Passage belt of latitudes a deep-reaching cell is induced by transient eddies. In the resulting residual circulation the Deacon cell is largely cancelled and the residual advection of the zonal mean potential density is balanced by diapycnal eddy and subgrid fluxes which are strong in the upper few hundred meters but small in the ocean interior. The balance of zonal momentum is consistent with other eddy-resolving models; a new aspect is the clear identification of density effects in the zonally integrated balance. We show that the wind stress and the stress induced by the residual circulation drive the eastward current, whereas both eddy species result in a braking. Finally, we extend the Johnson–Bryden model of zonal transport to incorporate all relevant terms from the zonal momentum balance. It is shown that wind stress and induction by the residual circulation carry an eastward transport while bottom form stress and the stress induced by standing eddies yield westward components of transport. Received: 26 June 2001 / Accepted: 2 November 2001  相似文献   

The aeolian dust accumulation curve     

Dirk Goossens 《地球表面变化过程与地形》2001,26(11):1213-1219

This article presents a simple physical concept of aeolian dust accumulation, based on the behaviour of the subprocesses of dust deposition and dust erosion. The concept is tested in an aeolian dust wind tunnel. The agreement between the accumulation curve predicted by the model and the accumulation curve obtained in the experiments is close to perfect and shows that it is necessary to discriminate between the processes of aeolian dust deposition and aeolian dust accumulation. Two important thresholds determine the accumulation process. For wind speeds below the deflation threshold, the aeolian accumulation of dust increases linearly with the wind speed. For wind velocities between the deflation threshold and the accumulation limit, the sedimentation balance is above unity and there is still accumulation, though it rapidly drops once the deflation threshold has been exceeded. At wind speeds beyond the accumulation limit, the sedimentation balance is below unity and there will no longer be an accumulation of dust. The thresholds have been determined in a wind tunnel test at friction velocity u_* = 0·34 m s^?1 (deflation threshold) and u_* = 0·43 m s^?1 (accumulation limit), but these values are only indicative since they depend heavily on the characteristics of the accumulation surface and of the airborne grains. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

Big Earth data: disruptive changes in Earth observation data management and analysis?     

Martin Sudmanns  Dirk Tiede  Stefan Lang  Helena Bergstedt  Georg Trost  Hannah Augustin 《International Journal of Digital Earth》2020,13(7):832-850

ABSTRACT

Turning Earth observation (EO) data consistently and systematically into valuable global information layers is an ongoing challenge for the EO community. Recently, the term ‘big Earth data’ emerged to describe massive EO datasets that confronts analysts and their traditional workflows with a range of challenges. We argue that the altered circumstances must be actively intercepted by an evolution of EO to revolutionise their application in various domains. The disruptive element is that analysts and end-users increasingly rely on Web-based workflows. In this contribution we study selected systems and portals, put them in the context of challenges and opportunities and highlight selected shortcomings and possible future developments that we consider relevant for the imminent uptake of big Earth data.  相似文献   

A Late Tournaisian synmetamorphic folding and thrusting event in the eastern Variscan foreland: 40Ar/39Ar evidence from the phyllites of the Wolsztyn–Leszno High,western Poland     

Żelaźniewicz  Andrzej  Marheine  Dirk  Oberc-Dziedzic  Teresa 《International Journal of Earth Sciences》2003,92(2):185-194

A Variscan foreland in western Poland comprises two NW-trending basement highs, which are concealed under Carboniferous through Triassic strata of the Fore-Sudetic Monocline (FSM). Both highs consist of multiply deformed quartz-sericite - albite - chlorite phyllites of unknown protolith age. ⁴⁰Ar/³⁹Ar laser probe dating of white micas in up to 0.5-mm-thick mica layers, which form the S₂ axial-plane foliation in phyllites of the Wolsztyn-Leszno High, yielded an age of 340.1DŽ.6 Ma for the lower greenschists facies metamorphism and probably also for the F₂ folding. This deformation was associated and followed by thrusting, which brought about the basement highs. The latter delivered clasts to overlying late Viséan-early Namurian flysch basin that was mainly sourced from the Saxothuringian Sudetes in which most of the deformation occurred between 345-335 Ma. The FSM basement may represent an independent terrane, referred to as the Wielkopolska terrane, belonging to the Armorican Terrane Assemblage.  相似文献   

Chemical Mechanism Development: Laboratory Studies and Model Applications     

Harald Geiger  Ian Barnes  Karl H. Becker  Birger Bohn  Theo Brauers  Birgit Donner  Hans-Peter Dorn  Manfred Elend  Carlos M. Freitas Dinis  Dirk Grossmann  Heinz Hass  Holger Hein  Axel Hoffmann  Lars Hoppe  Frank Hülsemann  Dieter Kley  Björn Klotz  Hans G. Libuda  Tobias Maurer  Djuro Mihelcic  Geert K. Moortgat  Romeo Olariu  Peter Neeb  Dirk Poppe  Lars Ruppert  Claudia G. Sauer  Oleg Shestakov  Holger Somnitz  William R. Stockwell  Lars P. Thüner  Andreas Wahner  Peter Wiesen  Friedhelm Zabel  Reinhard Zellner  Cornelius Zetzsch 《Journal of Atmospheric Chemistry》2002,42(1):323-357

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.  相似文献   

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene     

Richard Winterhalter  Peter Neeb  Dirk Grossmann  Antje Kolloff  Osamu Horie  Geert Moortgat 《Journal of Atmospheric Chemistry》2000,35(2):165-197

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.  相似文献   

Alternative Validation of a LC-MS/MS-Multi-Method for Pesticides in Drinking Water     

Alexander Müller  Dirk Flottmann  Wolfgang Schulz  Wolfram Seitz  Walter H. Weber 《洁净——土壤、空气、水》2007,35(4):329-338

The development of instrumental analytics such as the LC-MS/MS has made it possible to quickly determine many component concentrations in a single chromatogram. However, the validation of such multi-methods needs new strategies for robustness and optimization. Statistical execution of analytical tests is one tool that can be utilized to meet this requirement. A Central Composite Design (CCD) was utilized for the validation of an LC-MS/MS multi-method for 84 analytes. The experimental design includes six design variables and two non-design variables (response variables). Concentration, ionization temperature, dwell time, gradient, flow (of eluent), and spraying/curtain gas (continuous design variables) were varied on five different levels; the whole design encompassed 91 runs. To investigate the robustness of a LC-MS/MS method both peak sensitivity and chromatographic separation had to be verified. Therefore, two non-design variables were necessary. The distribution of the peaks over analysis time was applied to describe the quality of the chromatographic separation. The sensitivity was described with the signal to noise ratio (S/N). The evaluation of the measured data was accomplished with the Analysis of Variance (ANOVA) and the Response Surface Methodology (RSM). Three main effects (concentration, ionization temperature, dwell time) and no significant interaction effect were found for the response variable “S/N”. The variables of concentration, ionization temperature, and dwell time had no significant effects for the response variable “S/N”. The ANOVA of the response variable chromatographic separation abandoned no significant effects as well. Therefore, robustness of the method can be guaranteed for all non significant design variables.  相似文献   

Solubility of KFe(CrO₄)₂·2H₂O at 4–75°C     

Dirk Baron  Carl D. Palmer 《Applied Geochemistry》1998,13(8):961-973

The solubility of KFe(CrO₄)₂·2H₂O, a precipitate recently identified in a Cr(VI)-contaminated soil, was studied in dissolution and precipitation experiments. Ten dissolution experiments were conducted at 4–75°C and initial pH values between 0.8 and 1.2 using synthetic KFe(CrO₄)₂·2H₂O. Four precipitation experiments were conducted at 25°C with final pH values between 0.16 and 1.39. The log K_SP for the reaction