凡河元古宙坳拉谷关门山铅锌矿床铅同位素研究     

张国武 《国土资源》1993,(1)

凡河元古宙坳拉谷关门山铅锌矿床及外围铅矿点,矿石中的铅是以正常铅为主,单阶段模式年龄为1807—1995Ma,铅质来源主要是造山带铅,铅源岩为大于2000Ma的太古宙结晶基底。矿石中异常铅具有线性关系,它是由矿石中的正常铅与放射成因铀铅组成的。结合地质观察认为1807—1995Ma是正常铅受到均一化时间,不是成矿时间。该时间大于容矿条带状白云岩的年龄1526—1600Ma。矿体受断裂构造控制,具有穿层性,矿体生成于容矿岩石成岩以后。矿床成因是属后生的。成矿时间(主矿化期)为1400—1500Ma左右,最晚矿化时间为294Ma。矿床成因属元古宙坳拉谷碳酸盐岩密西西比河谷型(MVT)后生铅锌矿床。  相似文献   

Application of lead stable isotopes to the Guadiamar Aquifer study after the mine tailings spill in Aznalcóllar (SW Spain)     

I. Fernández  M. Olías  J. C. Cerón  J. De la Rosa 《Environmental Geology》2005,47(2):197-204

On 25 April 1998 the tailings dam of the Aznalcóllar mine burst, a great quantity of pyrite waste sludge and acid water was spilled reaching the vicinity of the Doñana National Park. In surface and ground water samples taken a week after dam breaking, metals, trace elements and Pb isotopic ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) were analysed. In September 1998 a second sampling survey was carried out. The surface waters have a similar isotopic composition as the lead contained in the pyrite from the Aznalcóllar mine. The polluted groundwater of the Guadiamar aquifer also shows the influence of the mining origin of the lead. Lead isotope ratios (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) in the groundwater of the Almonte-Marismas are very low and they differ clearly from the rest of groundwater samples. A further group of wells has a lead isotope composition intermediate between the Aznalcóllar mine and the atmospheric aerosols of the Iberian Peninsula.  相似文献   

Investigation on piezoelectric lead zirconate titanate detector bombarded obliquely with hypervelocity iron particles     

S. Takechi  T. Onishi  T. Miyachi  N. Hasebe  K. Nogami  S. Sasaki  T. Iwai  R. Srama 《Planetary and Space Science》2008,56(9):1309-1313

A cosmic dust detector for use onboard a satellite is currently being constructed from piezoelectric lead zirconate titanate (PZT). The characteristics of the PZT detector were studied by bombarding it with hypervelocity iron particles, which were supplied by a Van de Graaff accelerator. There was a linear relationship between the rise time of the signal observed from the detector and the particle's velocity, which was above 10 km/s on impact. It was also found that the rise time was almost independent of the collisional angle between the particles and the PZT surface within the limits of the particle's parameters used in this experiment.  相似文献   

The distribution of dissolved lead in the coastal waters of the East China Sea     

Yan Li  Rujun Yang  Aibin Zhang  Shirong Wang 《Marine pollution bulletin》2014

The distribution of dissolved lead in the coastal waters of the East China Sea was investigated seasonally. The average concentrations in surface waters during the spring and autumn were 0.52 nM and 0.27 nM, respectively. In the spring, the concentration of dissolved Pb in the surface waters and bottom waters ranged from 0.13 to 1.86 nM and from 0.15 to 0.94 nM, respectively. For both the surface water and the bottom water, the highest values were observed at the Yangtze River Estuary. Seasonal variability of D-Pb between spring and autumn in the ECS was observed. These results suggested that riverine inputs and atmospheric inputs may be the main sources of lead in this area, while adsorption and co-precipitation on suspended particles at the river estuary and biological process may be the major sinks.  相似文献   

Anthropogenic lead concentrations and sources in Baltic Sea sediments based on lead isotopic composition     

Agata Zaborska 《Marine pollution bulletin》2014

The Gulf of Gdańsk is influenced by heavy metals of anthropogenic origin. In this study, temporal concentration changes of Pb, Zn, Cd, and Cu were studied in six, 50 cm long sediment cores. The main aim of the study was to concentrate on the history of Pb fluxes and Pb isotopic composition (²⁰⁶Pb/²⁰⁷Pb and ²⁰⁸Pb/²⁰⁶Pb) to trace Pb sources. The lowest Pb concentrations (19 μg g⁻¹) were measured in sediments deposited circa 1860, while the highest Pb concentrations (63–147 μg g⁻¹) were measured in sediments deposited between 1960s and 70s. Pre-industrial Pb fluxes were 7 Pb m² year⁻¹, while after WWII they reached 199 Pb m² year⁻¹. Highest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.22) were measured in the oldest sediment layers, and the lowest ²⁰⁶Pb/²⁰⁷Pb ratios (∼1.165) were measured in the sediments deposited in 1970s–90s. During the period of highest Pb contamination, the anthropogenic Pb fraction reached up to 93%. A general discussion of the Pb sources, emissions, and loads for Poland is included.  相似文献   

Dissolution,transport, and fate of lead on a shooting range in the Jefferson National Forest near Blacksburg,VA, USA     

Caleb D. Scheetz  J. Donald Rimstidt 《Environmental Geology》2009,58(3):655-665

Samples taken from a shooting range near Blacksburg, VA, USA provide information about the reservoirs and pathways of lead at shooting ranges in an upland setting and humid environment. The metallic lead shot corrodes rapidly and develops a coating of hydrocerussite (Pb₃(CO₃)₂(OH)₂). Hydrocerussite dissolution releases soluble lead at concentrations ranging from 2 ppb to 2 ppm depending the soil pH values at this site. This soluble lead is captured by the Fe and Mn oxides and carbonates soil fractions. The highest concentration of extractable lead contained in the soil was directly correlated with the highest concentration of lead shot and bullets measured on the shotgun range surface. Eh-pH and hydrolysis diagrams provide a useful geochemical framework for understanding the corrosion process, recognizing the corrosion product(s), understanding their solubility, and identifying the geochemical barriers to lead migration that provides a basis for selecting best management practices for this and other shooting range.  相似文献   

铅锌产业链结构状况及海外资源战略   总被引：1，自引：0，他引：1       下载免费PDF全文

陈甲斌 《江苏地质》2009,33(1):102-107

我国铅锌产业发展虽然成绩显著,但资源问题是制约铅锌产业链协调发展的重要因素,开发利用海外铅锌资源是促进我国铅锌产业健康发展的长期战略方针。在总结国外海外资源开发经验的基础上,阐述了我国铅锌资源海外战略的基本原则及近期与中长期的战略目标,并对战略重点做了详细部署。  相似文献   

Effect of Natural Zeolite Application on Nitrite Concentrations in Rape (Brassica campestris L.) in Pb‐Contaminated Soils in Peri‐Urban Areas          下载免费PDF全文

Wei‐yu Shi  Hua Li  Sheng Du  Yiping Chen  Kaibo Wang 《洁净——土壤、空气、水》2015,43(3):408-413

  相似文献   

Chelant‐assisted Phytostabilization of Paint‐contaminated Residential Sites     

Syam S. Andra  Dibyendu Sarkar  Sumathi K. M. Saminathan  Rupali Datta 《洁净——土壤、空气、水》2010,38(9):803-811

Following the basic incubation study, a greenhouse experiment was conducted to elucidate the efficiency of vetiver grass (Vetiveria zizanioides L.), with or without chelating agents, in remediating lead (Pb)‐contaminated soils from actual residential sites where Pb‐based paints were used. Because the primary factor affecting Pb phytoavailability in soils is soil pH, we used two soil types widely varying in pH that have total Pb concentrations above 1500 mg kg^?1 soil. Lead‐contaminated, low pH, acidic soils were collected from residential sites in Baltimore, MD and high pH, alkaline soils were collected from residential sites in San Antonio, TX. Based on the soil characterization results, two most appropriate soils (one from each city, having similar Pb levels but variable soil physico‐chemical properties) were selected for this study. Ethylenediaminetetraacetic acid (EDTA) and [S,S′]ethylenediaminedisuccinate (EDDS) were applied at 5, 10, and 15 mmol kg^?1 soil. Lead uptake and translocation in vetiver was determined on day 10 after chelants addition. Plant and soil analysis show that EDTA treated soils have maximum Pb uptake and lower total soil Pb levels. Prediction models developed for exchangeable Pb show a strong correlation for total Pb accumulated in vetiver grass. Results of the sequential chemical extraction of the soils at both initial and final time‐points, indicates a significant mobilization of Pb by the two chelants from carbonate‐bound fraction to exchangeable pool. Information on physico‐chemical properties of contaminated residential soils help in predicting Pb phytoextraction and thus further help in calibrating a successful chelant‐assisted phytoremediation model.  相似文献   

黔北桑木背斜铅锌成矿带S、Pb同位素特征及成矿物质来源探讨     

朱华利  王波  谯常  张晗彬  韩雪 《贵州地质》2021,38(1):59-64

本文以S、Pb同位素作为示踪元素研究黔北桑木背斜铅锌成矿带成矿物质来源。桑木背斜铅锌成矿带矿石矿物中硫化物的δ~(34)S值变化范围较大最小值为16.1‰,最大值为31.5‰,平均值为25.6‰,极值为15.4‰;矿石矿物为相对富集重硫型;据此判断其硫的来源可能为沉积岩。研究区内来自不同矿区、不同矿物的Pb同位素变化均很小。~(206)Pb/~(204)Pb介于18.25～18.57 之间,~(207)Pb/~(204)Pb 介于 15.63 ～15.92 之间,~(208)Pb/~(204)Pb 介于 37.82 ～38.93 之间,三者变化范围均很小,且不同硫化物样品之间的Pb同位素组成也不存在明显的差异,表明桑木背斜地区的铅锌矿床可能具有较为单一的铅金属来源。通过投图分析,笔者认为桑木铅锌矿成矿带的铅金属可能来源于下伏基底地层。  相似文献