16ka以来青海湖湖相自生碳酸盐沉积记录的古气候   总被引：33，自引：1，他引：32  

刘兴起  沈吉  王苏民  张恩楼  蔡元峰 《高校地质学报》2003,9(1):38-46

研究了青海湖沉积物碳酸盐的组成、来源及其同湖水物理化学性质的关系,建立了文石饱和指数同温度和湖水Mg/Ca比值（可指示盐度）的关系,利用碳酸盐的组成探讨了青海湖16ka B.P.以来的古气候环境演化过程。结果表明,青海湖沉积碳酸盐大都是自生的,16ka B.P.以来沉积碳酸盐以文石为主。文石的高含量时段同暖湿气候相对应,低含量则同冷干气候相对应。15.2ka B.P.为末次冰期盛冰阶进入晚冰期的界限,晚冰期气候的冷暖波动频繁,幅度较小,13.4-13ka B.P.,11.6-12ka B.P.和11-10.4ka B.P.之间的冷颤动分别相当于老仙女木、中仙女木和新仙女木事件,12－13ka B.P.和11.6-11ka B.P.之间的暖期则分别对应于博令和阿勒罗得暖期。全新世初期（10.4-10ka B.P.)白云石含量的突然增高和文石的消失,可能同淡水快速补给前期盐度较高的湖水有关,反映了全新世开始时气温和降水的增加具有突变性的特点。全新世大暖期的鼎盛期,即6.7ka B.P.左右时湖水的盐度较低。6.7-4ka B.P.为气候转型过程中的冷暖和干湿的快速波动期。4ka B.P.以后碳酸盐含量急剧降低,气候逐步向冷干化方向发展。  相似文献   

环境因素对蜗牛Achatina fulica壳体碳酸盐δ13C 组成影响的实验研究          下载免费PDF全文

朱莉莉  鲍睿  盛雪芬 《高校地质学报》2015,21(2):357

陆生蜗牛化石稳定同位素组成是一种良好的古环境信息载体,常被用于古环境古气候的重建。由于缺少古环境因子 对蜗牛壳体稳定同位素组成机理性的结论,因此越来越多的研究侧重于对现代蜗牛壳体的环境效应进行探讨。实验室蜗牛 饲养实验则可以通过控制环境因素来确定其对壳体碳酸盐稳定同位素组成的影响程度,从而得到较为确切的结果。该文在 前人的研究基础上,利用Achatina fulica 进行实验室饲养实验。结果表明,在相同的温、湿度下,同种食物喂养的蜗牛壳体 有非常稳定的分馏值,不同食物类型的结果有一定的差异,莴苣叶、玉米粉和饲料喂养的蜗牛壳体相对于食物的分馏值分 别为16.70‰±0.2‰,10.57‰±0.2‰和10.65‰±0.2‰;在20~30℃实验条件下,壳体δ13C并不受环境温度的影响,主要受食 物的影响,并得到两者之间的回归方程为δ13Cs=0.6665δ13Cv+6.2302（n=26）;无机碳酸盐对Achatina fulica 壳体文石δ13C值影 响很少;根据端元组分分析方法的统计结果显示,食物是Achatina fulica 壳体碳同位素组成的主要影响因素,贡献值约为 80％±5％,除此以外,大气CO2的贡献值约为20％±5％。  相似文献   

河蚬壳体矿物组成及其对环境的适应性变化     

周会  刘丛强  王兵  闫慧  江伟  龚国洪  赵彦龙  丁文慈 《矿物学报》2011,31(2):243-249

河蚬是原产于我国和东南亚地区的一种淡水双壳类底栖动物,极强的环境适应能力使其在世界越来越多的淡水环境中成为优势动物种类,为研究生物对环境变化的适应性提供了一个范例。壳体是河蚬适应外部环境的重要器官,长期以来被认为由文石矿物组成。通过对我国黄河下游、淮河流域、长江和西江流域河蚬壳体显微结构观察和矿物成分X射线衍射分析,我们发现文石仅占壳体矿物质平均组成的95.5%,其余为方解石、蒙脱石、高岭石和伊利石等,平均含量各为1%左右。壳体棱柱层和薄片层中文石矿物的含量也存在系统差异,后者高出前者11%左右。河蚬壳体相同部位棱柱层文石含量表现出显著的区域变化特征,淮河和长江流域文石含量较高,分别达到96.1%和97.8%。而汉水和西江流域壳体中文石矿物含量较低,平均分别为94.5%和94.2%。黄河下游和珠江流域的数据较少,但已有数据显示前者文石含量低至92.7%而后者高达98.4%。壳体文石矿物含量的变化与区域气候变化和环境污染之间存在较好的对应关系,是河蚬适应环境变化的结果。本研究结果有助于在全球变化背景下利用生物的适应特点保护陆地水环境的生物多样性。  相似文献   

Partial high-pressure aragonitization of micritic limestones in an accretionary complex, Tavşanlı Zone, NW Turkey     

G. TOPUZ  A. I. OKAY  R. ALTHERR  H.-P. MEYER  L. NASDALA 《Journal of Metamorphic Geology》2006,24(7):603-613

Pelagic micritic limestones within an upper Cretaceous accretionary complex in the Tavşanlı Zone, NW Turkey, preserve textures indicating incomplete prograde transformation of micritic calcite to aragonite, representing the only known example of this type. Aragonitization starts at the central parts of the micritic limestone beds and advances towards the lower and upper parts of the layers at the expense of micrite. Micrite is very fine grained (<0.003 mm) and contains radiolaria, foraminifera and thin shell fragments. Aragonite forms large crystals, up to 3 cm across, with straight grain boundaries and c-axis mostly subparallel to the carbonate beds. Relict micritic portions are devoid of any aragonite grain. Stylolites characterized by the accumulation of clay minerals, Fe-Mn-hydroxides and quartz are concentrated in the upper and lower parts of the beds. Stylolite formation precedes aragonitization. Conditions of aragonitization are estimated as 200 ± 50 °C and 0.45–0.65 GPa, based on metamorphic mineral assemblages observed in associated basalts. Several features such as (i) constant composition of micritic calcite (98–99 mol.% CaCO₃) throughout individual beds, (ii) enormous grain size difference between micritic calcite and aragonite (up to 1200 times), and (iii) absence of any aragonite grains within the relict micritic portions suggest that kinetic rather than thermodynamic factors controlled selective aragonite formation in the central portions of carbonate layers.  相似文献   

Effect of anthropogenic CO2 on the pH and the saturation states of calcite and aragonite of seawater     

Chen-Tung Arthur Chen  Wang Shu-lun 《中国海洋湖沼学报》1997,15(2):145-149

Growth of phytoplankton, zooplankton and probably most other marine organisms as well, is likely to be affected by the pH of seawater. Growth of calcareous shells and skeletons is less likely to be affected by the saturation states of calcite and aragonite but the dissolution is. The increase of CO₂ in the oceans due to burning of fossil fuel and clearing of forests is decreasing the pH of seawater and the degrees of saturation for calcite and aragonite wordwide. This paper presents the results of the first attempt to estimate the vertical distribution of anthropogenic CO₂, and the decreases in pH and the degrees of saturation of calcite and aragonite in seawater near Taiwan. Most effects are very small except for the possible dissolution of aragonite on the upper continental slope starting around 2050 AD.  相似文献   

Carbon and Oxygen Isotopic Composition of Surface‐Sediment Carbonate in Bosten Lake (Xinjiang,China) and its Controlling Factors   总被引：1，自引：1，他引：0  

Steffen MISCHKE  ZHENG Mianping  Alexer PROKOPENKO  GUO Fangqin  FENG Zhaodong 《《地质学报》英文版》2009,83(2):386-395

Bosten Lake is a mid-latitude lake with water mainly supplied by melting ice and snow in the Tianshan Mountains. The depositional environment of the lake is spatially not uniform due to the proximity of the major inlet and the single outlet in the western part of the lake. The analytical results show that the carbon and oxygen isotopic composition of recent lake sediments is related to this specific lacustrine depositional environment and to the resulting carbonate mineralogy. In the southwestern lake region between the Kaidu River inlet and the Kongqi River outlet, carbon isotope composition (δ13C) values of the carbonate sediment (?1‰ to ?2‰) have no relation to the oxygen isotope composition of the carbonate (δ18O) values (?7‰ to ?8‰), with both isotopes showing a low variability. The carbonate content is low (<20%). Carbonate minerals analyzed by X-ray diffraction are mainly composed of calcite, while aragonite was not recorded. The salinity of the lake water is low in the estuary region as a result of the Kaidu River inflow. In comparison, the carbon and oxygen isotope values are higher in the middle and eastern parts of the lake, with δ13C values between approximately +0.5‰ and +3‰, and δ18O values between ?1‰ and ?5‰. There is a moderate correlation between the stable oxygen and carbon isotopes, with a coefficient of correlation r of approximately 0.63. This implies that the lake water has a relatively short residence time. Carbonate minerals constitute calcite and aragonite in the middle and eastern region of the lake. Aragonite and Mg–calcite are formed at higher lake water salinity and temperatures, and larger evaporation effects. More saline lake water in the middle and eastern region of the lake and the enhanced isotopic equilibrium between water and atmospheric CO2 cause the correlating carbon and oxygen isotope values determined for aragonite and Mg–calcite. Evaporation and biological processes are the main reasons for the salinity and carbonate mineralogy influence of the surface-sediment carbonate in Bosten Lake. The lake water residence time and the CO2 exchange between the atmosphere and the water body control the carbon and oxygen isotope composition of the carbonate sediment. In addition, organic matter pollution and decomposition result in the abnormally low carbon isotope values of the lake surface-sediment carbonate.  相似文献   

Aragonite and omphacite-bearing metapelite from Besshi region, Sambagawa belt in central Shikoku, Japan and its implication     

Yui  Kouketsu  Masaki  Enami 《Island Arc》2010,19(1):165-176

Aragonite and omphacite-bearing metapelite occurs in the albite–biotite zone of the Togu (Tohgu) area, Besshi region, Sambagawa metamorphic belt, central Shikoku, Japan. This metapelite consists of alternating graphite-rich and graphite-poor layers that contain garnet, phengite, chlorite, epidote, titanite, calcite, albite, and quartz. A graphite-poor layer contains a 1.5-cm ivory-colored lens that mainly consists of phengite, calcite, albite, and garnet. Aragonite, omphacite, and paragonite occur as inclusions in the garnet of the ivory lens. The aragonite has a composition that is close to the CaCO₃ end-member: the FeCO₃ and MnCO₃ components are both less than 0.3 mol% and the SrCO₃ component is about 1 mol%. The aragonite + omphacite + quartz assemblage in garnet indicates equilibrium conditions of P  > 1.1–1.3 GPa and T  = 430–550°C. Quartz grains sealed in garnet of the aragonite and omphacite-bearing sample and other metapelites in the Togu area preserve a high residual pressure that is equivalent to the Sambagawa eclogite samples. These facts suggest that: (i) the Togu area experienced eclogite facies metamorphism; and (ii) thus, eclogite facies metamorphism covered the Sambagawa belt more extensively than previously recognized.  相似文献   

Quantifying and testing differences among means of compositional data suites   总被引：1，自引：0，他引：1  

Alex Woronow  Karen M. Love 《Mathematical Geology》1990,22(7):837-852

Commonly, geological studies compare mean values of two or more compositional data suites in order to determine if, how, and by how much they differ. Simple approaches for evaluating and statistically testing differences in mean values for open data fail for compositional (closed) data. A new parameter, an f-value, therefore has been developed, which correctly quantifies the differences among compositional mean values and allows testing those differences for statistical significance. In general, this parameter quantifies only therelative factor by which compositional variables differ across data suites; however for situations where, arguably, at least one component has neither increased nor decreased, anabsolute f-value can be computed. In situations where the compositional variables have undergone many perturbations, arguments based upon thef-values and the central limit theorem indicate that logratios of compositional variables should be normally distributed.  相似文献   

EFFECT OF ANTHROPOGENIC CO_2 ON THE pH AND THE SATURATION STATES OF CALCITE AND ARAGONITE OF SEAWATER     

陈镇东  王树伦 《中国海洋湖沼学报》1997,(2)

unODUcrIONIntereStinthecarboncycehasinamsedbouseoftheobservedincreaseinatmosphericCO,leveIsduetothebumingoffossilfuelandthedearingofforestsre-sultinginlargedhaticandbiogeochdrica1consequenas(ChenandDrake,l986).Experi-mentalstudisofp1antShaveshownresponsesoftypically2O%-4O%highergroWthunderdoubledCo,conditions.Ontheotherhand,theeffedofelevatalCO=conditionsinincreasinggroWth,knownastheCO,fertilimtioneffed,isnotbe1ievedtobetwortantintheoasns(Schimeletal.,1995).Althoughithasbeensuggestedt…  相似文献   

Aragonite stromatolitic buildups from Santorini (Aegean Sea,Greece): Geochemical and palaeontological constraints of the caldera palaeoenvironment prior to the Minoan eruption (ca 3600 yr bp)     

Pere Anadón  Carles Canet  Walter L. Friedrich 《Sedimentology》2013,60(5):1128-1155

The pyroclastic deposits of the Minoan eruption (ca 3600 yr bp ) in Santorini contain abundant xenoliths. Most of these deposits are calcareous blocks of laminated‐botryoidal, stromatolite‐like buildups that formed in the shallow waters of the flooded pre‐Minoan caldera; they consist of (i) light laminae, of fibrous aragonite arranged perpendicular to layering, and (ii) dark laminae, with calcified filaments of probable biological origin. These microstructures are absent in the light laminae, suggesting a predominant inorganic precipitation of aragonite on substrates probably colonized by microbes. Internal cavities contain loose skeletal grains (molluscs, ostracods, foraminifera and diatoms) that comprise taxa typical of shallow marine and/or lagoon environments. Most of these forms are typical of warm water environments, although no typical taxa from hydrothermal vents have been observed. Past gasohydrothermal venting is recorded by the occurrence of barite, pyrolusite and pyrite traces. The most striking features of the stable isotopic data set are: (i) an overall wide range in δ¹³C_PDB (0·16 to 12·97‰) with a narrower variation for δ¹⁸O_PDB (?0·23 to 4·33‰); and (ii) a relatively uniform isotopic composition for the fibrous aragonite (δ¹³C = 12·40 ± 0·43‰ and δ¹⁸O = 2·42 ± 0·77‰, n = 21). The δ¹³C and δ¹⁸O values from molluscs and ostracods display a covariant trend, which reflects a mixing between sea water and a fluid influenced by volcano‐hydrothermal activity. Accordingly, ⁸⁷Sr/⁸⁶Sr from the studied carbonates (0·708758 to 0·709011 in fibrous aragonite and 0·708920 to 0·708991 in molluscs) suggests that the aragonite buildups developed in sea water under the influence of a hydrothermal/volcanic source. Significant differences in trace elements have been detected between the fibrous aragonite and modern marine aragonite cements. The caldera water from which the fibrous aragonite crusts formed received an input from a volcano‐hydrothermal system, probably producing diffuse venting of volcanogenic CO₂ gas and of a fluid enriched in Ca, Mn and Ba, and depleted in Mg and probably in Sr.  相似文献