Composition and quality of coals in the Huaibei Coalfield, Anhui, China   总被引：3，自引：0，他引：3  

Liugen Zheng  Guijian Liu  Lei Wang  Chen-Lin Chou 《Journal of Geochemical Exploration》2008,97(2-3):59-68

The Huaibei Coalfield, Anhui Province, China, is one of the largest coalfields in China. The coals of Permian age are used mainly for power generation. Coal compositions and 47 trace elements of the No. 10 Coal of the Shanxi Formation, the No. 7, 5, and 4 Coals of the Lower Shihezi Formation, and the No. 3 Coal of the Upper Shihezi Formation from the Huaibei Coalfield were studied. The results indicate that the Huaibei coals have low ash, moisture, and sulfur contents, but high volatile matter and calorific value. The ash yield increases stratigraphically upwards, but the volatile matter and total sulfur contents show a slight decrease from the lower to upper seams. Magmatic intrusion into the No. 5 Coal resulted in high ash, volatile matter, and calorific value, but low moisture value in the coal. Among the studied 47 trace elements, Ba, Co, Cr, Cu, Hg, Mo, Ni, Pb, Sb, Th, U, V, and Zn are of environmental concerns. Four elements Hg, Mo, Zn, and Sb are clearly enriched in the coals as compared with the upper continental crust.  相似文献   

北大别白垩纪镁铁－超镁铁岩的铂族元素地球化学研究   总被引：2，自引：0，他引：2       下载免费PDF全文

刘 庆侯泉林  周新华谢烈文 《中国地质》2008,35(5):859-868

采用镍锍火试金法结合ICP-MS分析了12个北大别白垩纪镁铁-超镁铁岩样品的Ir,Ru,Rh,Pt和Pd的含量,结果显示铂族元素（PGE）的含量较低,原始地幔标准化后的PGE分布模式呈正斜率型,PPGE相对原始地幔略微亏损,而IPGE强烈亏损,Pd/Ir值远高于相应的地幔比值。这些镁铁-超镁铁岩中PGE的强烈分异是地幔低程度的部分熔融过程中,PPGE主要受硫化物控制,而Ir则存在于非硫化物相如尖晶石,可能还有合金之中造成的。同时,铂族元素的分布特征表明这些镁铁-超镁铁岩是岩浆结晶分异的产物。  相似文献   

大亚湾沉积物中重金属元素背景值研究     

张银英 《热带海洋学报》1991,(3)

根据大亚湾的自然条件认为,大亚湾沉积物的物质来源是其周围集水区的岩石风化壳,并计算了其风化壳中重金属元素的平均丰度值;又根据沉积物的粒度和深层沉积物重金属元素的含量资料,列方程计算出湾内沉积物中重金属元素的平均含量,根据这两组数据,确定该区域内重金属元素的平均背景值。再通过粒度关系,计算得出大亚湾内各站沉积物中重金属元素的背景值。应用此结果和大亚湾沉积物重金属元素实测结果,计算了由人为影响带入沉积物中的重金属元素含量,了解其受污染的程度。  相似文献   

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea     

Florian Scholz  Thomas Neumann 《Marine Chemistry》2007,107(4):516-532

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.  相似文献   

大别山地区石榴石橄榄岩的岩石学和地球化学     

韩宗珠 《中国海洋大学学报(自然科学版)》1989,(4)

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。  相似文献   

柴达木盆地昆特依盐湖的地球化学演化与古气候变化   总被引：9，自引：1，他引：9  

韩凤清  黄麒  王克俊  王华安  原力 《海洋与湖沼》1995,26(5):502-508

１９９０年用铀系年代学及古地磁对昆特依盐湖沉积物进行年代测定，探讨该湖区地球化学演化与古气候变化关系。结果表明，该区最老的盐层形成于早更新世晚期（大于７３０ｋａ），大量的盐类沉积则始于３００ｋａ左右；盐湖沉积物中元素含量变化主要受古盐度、矿物、类质同象和吸附控制；沉积物水溶Ｆ／Ｃｌ比值与古盐度成反比关系；该湖２０００ｋａ以来的古环境演变：盐层形成于干冷、偏酸性的氧化环境，泥岩层形成于湿暖、偏碱性的  相似文献   

Relationship between biogeochemical features of biogenic elements and flocculation in the Changjiang Estuary   总被引：1，自引：3，他引：1  

Lin Yi''an  Tang Renyou  Li Yan  Dong Henglin  Guan Xuwei  Chen Yinzu 《海洋学报(英文版)》1995,14(2):225-234

ＲｅｌａｔｉｏｎｓｈｉｐｂｅｔｗｅｅｎｂｉｏｇｅｏｃｈｅｍｉｃａｌｆｅａｔｕｒｅｓｏｆｂｉｏｇｅｎｉｃｅｌｅｍｅｎｔｓａｎｄｆｌｏｃｃｕｌａｔｉｏｎｉｎｔｈｅＣｈａｎｇｊｉａｎｇＥｓｔｕａｒｙ￥ＬｉｎＹｉ＇ａｎ；ＴａｎｇＲｅｎｙｏｕ；ＬｉＹａｎ；Ｄｏ...  相似文献   

两次大风过程的对比分析   总被引：1，自引：0，他引：1  

王雷 《海洋预报》2006,23(3):36-41

文章对两次冷空气结合低气压大风过程进行了对比分析,揭示了海上低压轴向的突然向西北转变而引起的地面气压梯度的迅速加大是造成浙北沿海大风的重要原因之一。同时,揭示了两次过程由于高低层辐合辐散差异而引起的大风区上空两类不同的高低空垂直下沉速度分布特征,指出动量下传作用在地面造成风速的加大主要决定于对流层低层下沉速度(而非中层),这可能是两次大风过程地面气压梯度接近,而实际风力却差一级的原因。  相似文献   

Reanalysis of the Atmospheric Flux of Nutrient Elements to the Southern Yellow Sea and the East China Sea     

万小芳吴增茂  常志清 《海洋通报(英文版)》2003,5(1):45-51

Based on the recent research results on dry and wet deposition of nutrient elements and sulphate,we estimate the atmospheric flux of nutrient elements and sulphate to the southern Yellow Sea and the East China Sea in each season.The results suggest that the concentrations of nutrient elements and sulphate in aerosol and precipitation show an apparent seasonal cycle with the maximum values in winter and the minimum values in summer.Depositions of nitrate and sulphate are dominated by wet deposition,while the deposition for phosphate is mainly dry deposition.Moreover,compared with the riverine inputs,the atmospheric deposition may be the main source of dissolved inorganic nutrients in the southern Yellow Sea and the East China Sea.  相似文献   

福建罗源湾海滩互花米草盐沼中18种金属元素的分布   总被引：13，自引：0，他引：13  

钦佩  谢民  仲崇信 《海洋科学》1989,13(6):23-27

本文对福建罗源湾可湖海滩互花米草盐沼中的18种金属进行了测试,结果表明,罗源湾可湖海滩的环境质量基本是好的,并探讨了开发利用互花米草的新途径。  相似文献