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The Al-basic sacrificial anode is widely used to protect steel construction from corrosion in seawater,but is not suitable for protecting steel in freshwater. In the estuary area, seawater and freshwater mix anddifferent seawater salinity can be formed in different mixing sites between freshwater and seawater. Basedon the requirements of the Shengli Petroleum Administrative Bureau of China, the effect of seawatersalinity on electrochemical properties of Al-basic anode was studied under laboratory conditions by themethod given in National Standard GB 4948-85 (China Starndard Bureau, 1985). No obvious effectwas found when seawater salinity was 30 to 10, but obvious effect on anodic open circuit potential, closedcircuit potential and current efficiency was found when seawater salinity was 5. These values are lowerthan those given in the Naional Standard. 相似文献
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Heavy paint coating loss and localized corrosion of the Al alloy hull occur red after less than a year's service of a ship at sea.Examination and analysis showed that the Mg-basic sacrificial anodes originally used for cathodic protection were not suitable as the resulting -1.3V-plus (vs Ag/AgCl) protection potential for the hull was too negative for the purpose .A new protection system was designed in which the protection current densities were 15mA/m2 for the hull and 350mA/m2 for the propeller - The hull protection potential under actual condition at sea was between -920mV and - 1100mV (Ag/AgCl) and the protection efficiency was over 90% . The protection areas were calculated by using the formulas A=1.8×LBP×D+ BC× LB×B for the hull and As=2Aas for the propeller. 相似文献
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海洋工程用铝基牺牲阳极发展概况 总被引:5,自引:0,他引:5
阴极保护是一种重要的腐蚀防护方法,它分为外加电流保护和牺牲阳极保护。其中 ,用牺牲阳极保护金属构件是一种简单易行 ,投资较少的阴极保护方法。因此 ,在船舶、码头、海洋平台及其他海上大型钢结构的保护上 ,得到了广泛的应用[3]。阴极保护用的牺牲阳极材料有铝、镁、锌三大系列。张经磊1986年指出 ,与镁基、锌基牺牲阳极相比 ,铝阳极的最突出优点是单位重量的输出电量大 ,是锌阳极的3.6倍 ,镁阳极的1.3倍 ;铝资源充足 ,价格便宜 ,重量轻 ;工作电位足够负 ,发生电流量大 ,寿命长 ,在海水和含Cl-的环境中应用性能良好。而… 相似文献
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在我国,滨海城市的工业用水以冷却水用量占的比重最大,约占总用水量的一个半以上。有的城市因久旱不雨,淡水水源干涸,虽面临大海,仍不得不停工停产。其原因就是海水的侵蚀性很强,不能用。钢铁在海水中的腐蚀速度一般为0.06—0.17mm/yr.。而当流速增至1m/s时,其腐蚀速度增至3倍;2m/s时增 相似文献
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The effect of trace elements Bi and Ti on the electrochemical property of aluminium sacrificial anode in seawater was studied . Different amounts of Bi and Ti were alloyed with Al-Zn-In to make 9 types of aluminium sacrificial anodes . Anode closed circuit potential, discharge capacities and current efficiencies were measured in the laboratory . The results show that the effect of Bi is greater than that of Ti. 相似文献
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电连接模拟法十年腐蚀试验研究 总被引:2,自引:0,他引:2
在开发海洋所需要的设施中,例如海上采油平台,海上输油码头,海底管线,海上观察测量仪器,海上运输船舶等大都使用钢材来制造。但是由于海水是一种强电介质溶液,使得钢材在海洋环境中遭受着严重腐蚀,这直接影响着海上设施的使用寿命。为了研究钢铁本身的耐腐蚀性能,腐蚀试验方法越来越被腐蚀工作者所重视。即用什么样的腐蚀试验方法来比较、评定所研制钢种的耐腐蚀性能是一项重要工作。室内的电化学测试及加速腐蚀试验等方法为海洋用钢的研制起到了积极作用,它可以较快地对钢铁的耐腐蚀性能进行相对评定[16,20,21],但有些… 相似文献
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