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碳酸岩生油岩中沥青变质程度和沥青热变质实验 总被引:4,自引:0,他引:4
Natural asphalts from carbonate rocks in South China have been studied by using microscopy, X-ray diffraction, ESR and C^-, H^- analysis and subjeeted to thermal alteration experiments under 250℃/1000 atm--500℃/1000atm. It is shown that asphalt and vitriolic behave differently under conditions of thermal alteration. In compariseu with vitriuite, asphalt is of higher reflectivity, more apparemt anisotropy,lower values of d002 and H/C ratio above 350℃. The mierostructure and charaeter of protoasphalt disseminated in carbonate rocks and diagenetic asphalt reflect the thermal history and the maximum paleotemperature to which they haxt been subjected. Reflectivity, H/C ratio, d002 etc. of the asphalts in carbonate rocks may be used as indicators for the extent of maturity of earbenate source rocks. Based on measurements carried on asphalts of pertinent occurrences. R^0=1.65.H/C=0.75, d002=3.53 A are suggested as creteria for the distinction between Oil and natural gas field in carbonate terrains in China. 相似文献
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碳酸盐岩生油岩的有机地球化学、岩石学特征 总被引:13,自引:1,他引:13
Features of oil-generating carbonate rocks are studied in terms of petrology and organic geochemistry of fluorescent materials in rocks. It is postulated by the authors that the organic carbon content in oil-generatlng carbonate rocks is necessarily lower than that in shales, and the possible cause of this observation is discussed. The quality of oil-ganerating carbonate rocks may be judged by aromatic structure index,amino acid, pigment index, and DTA data on organic matter. However, the application of presently available organic geochemical criteria to non-oil-generating reservoir rocks may always give misleading results. To circumvent this difficulty, it is necessary first to make distinction between primary and secondary organic matter by cxamining the fluorescent materials under a fluorescence microscope. Measurementof radical content of the organic substances and DTA are useful techniques to determine the degree of maturation. The maturation of organic substances proceeds at a lower rate in carbonate rocks than in shales. It is likely, therefore, that some older carbonate strata can also be promising areas for petroleum exploration. Oil-generating carbonate rocks consist mainly of mierite limestones rich in organic matter and are thought to be formed under low-encrgy environment. Consequently, petrological(especially mierolithofacies) studies are very important in evaluating carbonate source rocks. 相似文献
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碳酸盐矿物的包裹有机质及其生油意义 总被引:5,自引:3,他引:5
Fluorescent slice observations have revealed a considerable amount of organic matter enclosed in carbonate minerals, most of it giving off yellow-brown fluorescence and being zonally distributed in calcite and dolomite. The amount of enclosed organic matter released from the enclosure when treated with HCl is two times higher than that of extractable organic mattes in the same rock sample. In comparison to the extractable organic matter, the enclosed organic matter is possessed of some compositional characters of its own. In terms of the distribution of biological markess, it is suggested that the enclosed organic matter may be low in maturity relative to the extractable organic matter in the same source rock.Results of the simulating experiments under high temperatures and pressures show that this kind of organic matter enclosed in carbonate minerals can be converted into oil-generating substances. Therefore, detailed studies of the enclosed organic matter are of much help to the evaluation of oil-generating potentiality of carbonate source rocks. 相似文献
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东胜砂岩型铀矿床中烃类流体与成矿关系研究 总被引:6,自引:0,他引:6
东胜砂岩型铀矿床定位于灰绿色岩石与灰色岩石的接触部位,主要受古层间氧化带控制.矿体以板状为主.铀主要以铀矿物和吸附铀形式存在.铀矿物主要为铀石, UO2含量为 46.72%~ 74.60%.吸附铀及 U6 、U4 在铀矿床的不同地段所占比例存在明显差别.该铀矿床与世界上其他砂岩型铀矿床在成因上具有明显的不同,表现在矿床特征、岩石地球化学环境及控矿因素等方面具有很强的特殊性.晚侏罗世-早白垩世的构造热事件形成的含烃热流体参与了成矿作用,不仅为铀的活化、迁移、富集提供了有利条件,而且使铀矿床完全隐伏在还原环境中,对矿床的保存起到了重要作用.由烃类流体产生的后生还原作用所形成的灰绿色砂岩可作为铀矿床的岩石地球化学勘查标志. 相似文献
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1986年8月18日至31日—我们随同以叶连俊先生为团长的中国科学院代表团赴澳大利亚出席十二届国际沉积学大会,并应邀参船了澳大利亚第四届有机地球化学会议。这次有机地球化学会议是澳大利亚的专业性例会,由矿物资源局T·G·Powell博士主持,会议历时两天,宣读论文二十多篇。我们根据这些论文及在参观中所了解的情况,对澳大利亚在石油地球化学方面的研究状况作一概要的介绍。 相似文献
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The comparative study of organic matter in carbonate rocks and argillaceous rocks from the same horizon indicates that the organic thermal maturities of carbonate rocks are much lower than those of argillaceous rocks .Ana extensive analysis of extracted and inclused organic matter from the same sample shows that inclused organic matter is different from extracted organic matter,and the thermal maturity of the former is usually lower than that of the latter in terms of biomarker structural parameters.It seems that carbonate mineras could preserve organic matter and retard organic maturation.The inclused organic matter,abundant in most carbonate rocks,will be released from minerals and transformed into oil and gas during the high-thermal maturity stage. 相似文献
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周中毅 《矿物岩石地球化学通报》1985,(1)
近十几年来,石油成因研究及勘探实践证明,在一般情况下,石油是在50—160℃的地温区间内由沉积岩中的有机质转化而成;地温过高的深部地层,只能产生天然气。因此,古地温的研究资料已成为寻找工业油气藏的重要依据。 相似文献