南平石(Nanpingite)——一种新的铯矿物   总被引：2，自引：0，他引：2       下载免费PDF全文

杨岳清  倪云祥  王立本  王文瑛  张亚萍  陈成湖 《岩石矿物学杂志》1988,7(1):49-58

南平石是一种新的铯矿物,它产于福建南平31号白云母—钠长石—锂辉石型伟晶岩中,以细脉形式发育在伟晶岩中部铯沸石集合体附近的石英—羟磷铝锂石组石带内。形态酷似白云母,比重为3.11(实测)和3.19(计算)。二轴晶,负光性,折光率,Ng=1.588,Nm=1.584,Np=1.551,b=Ng。结晶化学式:(Cs_(0.83)K_(0.06)Rb_(0.01))_(0.95)(Al_(1.64)Mg_(0.22)Fe_(0.17)Li_(0.15))_(2.18)[(Si_(3.16)Al_(0.84)_4O_(10)][(OH)_(1.78)F_(0.21]_2。南平石属单斜晶系,2M_1多型,空间群为C2/c,晶胞参数:a=5.362(3),b=8.86(1),c=21.42(1),β=95.72(2)°,V=1012.3~3,Z=4。热谱分析表明,吸热谷仅有920℃一处,失重约3.3％。红外吸收谱带波数(cm~(-1))是3634、3429、1625、1083、1018、911、823、788、741、663、515、467、420、350。  相似文献   

Geochemical characteristics and spectrometric prospecting in the muscovite-bearing pegmatites and granites,southeastern Aswan,Egypt     

Gehad M. Saleh Mohamed M. ElGaly Mohamed A. Obeid 《中国地球化学学报》2008,27(1):9-20

Rare metal mineralization of Sn, Nb-Ta and W is encountered in the Gebel Dihmit area （GDA）, southeastern Aswan, Egypt. The mineralization is related to muscovite granites and their pegmatite derivatives. The pegmatites are divided into three types according to their main mineral assemblages： K-feldspar-muscovite-tourmaline, K-feldspar-albite-muscovite and albite-K-feldspar-lepidolite veins. Petrogenetic studies indicate that Sn and Nb-Ta mineralization extends from the late-magmatic stage to the pegmatite and hydrothermal stages of the （GDA） suite. The albite-K-feldspar-lepidolite granite is composed dominantly of albite, lepidolote, and quartz, with topaz, K-feldspar and amblygonite. The accessory minerals are zircon, monazite, pollucite, columbite-tantalite, microlite and Ta-rich cassiterite. Phenocrysts of quartz, topaz and K-feldspar contain abundant inclusions of albite laths and occasional lepidolite crystals along growth zones （snowball texture）, indicating simultaneous crystallization from a subsolvus, residual magma. The origin of the pegmatites is attributed to extreme differentiation by fractional crystallization of a granitic magma. The economic potential for rare metals was evaluated in the geochemical discrimination diagrams. Accordingly, some of the pegmatites are not only highly differentiated in terms of alkalis, but also the promising targets for small-scale Ta and, to a less extent, Sn. The pegmatites also provide the first example of Fe-Mn and Nb-Ta fractionation in successive generations of granites to cassiterite-bearing pegmatites, which perfectly ex- hibit similar fractionation trends established for primary columbite-tantalite in the corresponding categories of pegmatites. Uranium and Th of magmatic origin are indicated by the presence of thorite and allanite, whereas evidence of hydrothermal mineralization is the alteration of rock- foring minerals such as feldspar and the formation of secondary minerals such as uranophane..  相似文献   

阿尔泰可可托海3号脉伟晶岩型稀有金属矿床云母和长石的矿物学研究及意义   总被引：8，自引：4，他引：4  

周起凤  秦克章  唐冬梅  丁建刚  郭正林 《岩石学报》2013,29(9):3004-3022

可可托海3号脉伟晶岩型稀有金属矿床是阿尔泰造山带产出的规模最大的伟晶岩脉,其完美的同心环状结构分带举世闻名。云母和长石作为3号脉9个结构带的贯通性矿物,由外向内表现不同的结构和成分特征。其中,云母由白云母系列向锂云母系列演化,白云母呈黄-绿色中细粒→白色或绿色中粗粒-巨晶→白色或绿色书状集合体→白色或绿色中粗粒-巨晶,锂云母呈玫瑰紫中细粒鳞片状或楔状集合体,BSE图像下云母表现出成分分带及不平衡和交代结构;长石主要为钾长石和钠长石,及少量斜长石,钾长石主要呈块体产出,钠长石呈细粒→叶片状→薄片状产出。本次研究通过电子探针(EMPA)和激光剥蚀等离子质谱(LA-ICP-MS)获得3号脉各结构带云母和长石的主微量成分。3号脉云母具有高Li(249×10^-6~35932×10^-6)、Rb(1240×10^-6~22825×10^-6)、Cs(35.9×10^-6~13980×10^-6)、Ta(13.3×10^-6~447×10^-6)含量、低K/Rb值(4.23~59.4)和K/Cs值(6.53~2368),钾长石具有低K/Rb值(35.4~1865),且由外向内,随K/Rb值降低,云母的Li、Rb、Cs、F、Ta含量升高,表明3号脉是一个由外向内结晶的分异演化程度较高的伟晶岩脉。另外,连续相邻结构带中云母和长石的主微量成分呈振荡变化,该现象主要受熔体不混溶过程的控制,也受矿物结晶不平衡影响,而熔体不混溶过程也是控制3号脉结构分带的机制之一。外部带(I-IV带)和内部带(V-VIII带)的云母和碱性长石在成分(FeO、Li、Rb、Cs、F、Ta含量和K/Rb值及K/Cs值)和结构(不平衡和交代结构)上具有明显差异,内部带演化程度明显加大,流体组分比例升高,表明体系由以熔体为主的阶段(外部带)进入以熔流体为主相对不稳定的阶段(外部带)。结合野外观察的证据,促使体系在IV带和V带间发生突然转变而进入熔流体阶段的是一个泄压事件。  相似文献   

四川米易白马地区伟晶岩元素地球化学特征     

刘君  彭秀红  黄仕宗  项志磊 《四川地质学报》2013,(2):251-256

伟晶岩在米易县白马地区广泛分布,研究岩体的元素地球化学对寻找新矿种具有很强的理论和现实意义。特别是研究岩体常量元素、铂族元素、稀土元素的地球化学特征,对伟晶岩体的找矿具有重要意义。  相似文献   

应用X射线荧光光谱-电感耦合等离子体质谱法研究湖南传梓源地区稀有金属矿床伟晶岩地球化学特征   总被引：2，自引：1，他引：1  

文春华  罗小亚  李胜苗  李建康 《岩矿测试》2015,34(3):359-365

本文利用X射线荧光光谱和电感耦合等离子体质谱分析技术对传梓源地区锂辉石伟晶岩、钠长石伟晶岩和钾长石伟晶岩开展研究,获得三种类型伟晶岩地球化学特征。锂辉石伟晶岩具高Al2O3(16.23%~16.4%)、高K2O(3.05%~5.22%)和高分异指数(DI=91.13~94.9),微量元素富集Rb、K而亏损Ba、Sr、Ti,稀土元素含量低(ΣREEs=2.9×10-6~3.5×10-6);钠长石伟晶岩富Na2O(5.58%~7.41%)而贫K2O(0.98%~2.62%),微量元素Rb/Sr值相对于锂辉石伟晶岩呈降低变化而稀土元素为升高变化;钾长石伟晶岩富K2O(9.13%)而贫Na2O(1.69%),微量元素Zr/Hf和K/Rb值相对于锂辉石伟晶岩和钠长石伟晶岩呈升高变化的特征。表明岩浆在演化过程中发生了不混溶作用、钠长石交代作用和钾长石交代作用,分别形成了Li、Rb矿化锂辉石伟晶岩,Nb、Ta、Be矿化钠长石伟晶岩和无矿化钾长石伟晶岩,这些地球化学特征是稀有金属矿床找矿地球化学标志。  相似文献   

阿尔泰阿斯喀尔特Be-Nb-Mo矿床年代学、锆石Hf同位素研究及其意义   总被引：6，自引：2，他引：4  

王春龙  秦克章  唐冬梅  周起凤  申茂德  郭正林  郭旭吉 《岩石学报》2015,31(8):2337-2352

阿斯喀尔特Be-Nb-Mo矿床位于新疆阿尔泰东段可可托海伟晶岩矿集区,Be储量达大型,产出宝石并伴生Nb、Mo、Ga矿化。该矿床同时发育花岗岩型与伟晶岩型两类稀有金属矿化,晚阶段有辉钼矿、黄铁矿等硫化物发育,在阿尔泰伟晶岩省具有独特性。本文对矿区内的白云母钠长花岗岩、Be矿化白云母钠长花岗岩以及条带状伟晶岩进行锆石LA-ICP-MS U-Pb定年及Hf同位素研究,对伟晶岩中不同产状的辉钼矿进行Re-Os同位素定年。获得的锆石238U/206Pb加权平均年龄分别为219.2±2.9Ma、222.6±4.6Ma与218.2±3.9Ma,辉钼矿Re-Os加权平均年龄为218.6±1.3Ma,表明伟晶岩形成稍晚于花岗岩,花岗-伟晶岩系统的演化时间较短;锆石εHf(t)值分别为-0.72~+1.33、-0.36~+1.99与-0.45~+0.38,t DM C模式年龄分别为1169~1298Ma、1130~1279Ma与1229~1282Ma,表明花岗岩与伟晶岩具有类似的源区,以前寒武纪微陆块的壳源物质为主。花岗岩与伟晶岩形成于后造山板内演化阶段,与加厚地壳的熔融有关。根据矿化组合、源区特征并结合大地构造背景,提出阿斯喀尔特伟晶岩属于LCT型。地质、地球化学及年代学特征表明白云母钠长花岗岩为伟晶岩的成矿母岩。  相似文献   

High-Pressure Melting of Eclogite and the P-T-X History of Tonalitic to Trondhjemitic Zoisite-Pegmatites, Munchberg Massif, Germany     

Liebscher  Axel; Franz  Gerhard; Frei  Dirk; Dulski  Peter 《Journal of Petrology》2007,48(5):1001-1019

Zoisite-bearing high-pressure pegmatites from the MünchbergMassif, Germany, provide an excellent example of the characteristicsof the onset of metabasite melting at eclogite-facies conditions.The pegmatites were derived by partial melting of a mid-oceanridge basalt (MORB)-like eclogite at T 680°C/2·3GPa to 750°C/3·1 GPa, which produced small amountsof tonalitic to trondhjemitic melt. The melt concentrated locallyin isolated, small melt pockets and crystallized primary zoisiteas liquidus phase at P 2·3 GPa/680°C to 2·1GPa/750°C. Compositional zoning of pegmatite zoisite recordsan ensuing multi-stage uplift history with successive, discretecrystallization events at 1·4 ± 0·2 GPa/650–700°Cand 1·0 ± 0·1 GPa/620–650°C.Resorption textures indicate reheating and thermal perturbationof the whole system prior to each successive crystallizationevent. Final solidification of zoisite-pegmatites occurred at0·9 ± 0·1 GPa/620–650°C. Thedata suggest that isolated melt + zoisite crystal mush pocketsformed an integral part of the eclogite throughout uplift frommelt formation at T 680°C/2·3 GPa to 750°C/3·1GPa to final solidification at 0·9 GPa/620–630°C;that is, over a depth range of 45–60 km. The entire pegmatite-formingprocess was probably fluid conserving: fluid present duringmelt formation was trapped by fully or nearly water-saturatedsiliceous melts, whereas fluid liberated during pegmatite crystallizationinteracted with dehydrated eclogite-facies assemblages to formamphibolite-facies hydrous minerals. A set of empirical D^{melt/eclogite}values based on mean zoisite-pegmatite and eclogite compositionwere used to model the onset of partial high-pressure meltingof metabasites. KEY WORDS: adakite; high-pressure melting; pegmatite; trondhjemite; zoisite  相似文献   

湘东北幕阜山地区中生代构造—岩浆特征及其对稀有金属伟晶岩的控制     

柏道远  文春华  黄建中  李彬  周芳春  张立平  陈虎  陈剑锋  陈旭 《地质论评》2023,69(3):855-880

幕阜山地区发育燕山期大型花岗岩体,形成了大量花岗伟晶岩脉及相关稀有金属矿床或矿化体。尽管前人对该地区花岗岩、伟晶岩和稀有金属矿床的地质地球化学特征、形成时代、空间展布和演化过程等进行了系统研究并取得大量成果,但地质构造对花岗岩和稀有金属伟晶岩的控制作用尚缺乏研究。鉴此,笔者等通过跨幕阜山岩体接触带的多个地质剖面调查,结合区域地质和矿产发育特征,对幕阜山地区中生代构造—岩浆演化过程以及构造对花岗岩体、伟晶岩脉和接触变质带的控制作用等进行了研究,形成以下主要认识：(1)中生代—新生代早期,研究区自早至晚经历了早—中三叠世海相盆地、中三叠世后期—晚三叠世印支运动、晚三叠世晚期—中侏罗世早期类前陆盆地、中侏罗世晚期早燕山运动、晚侏罗世—早白垩世早期花岗质岩浆活动与成矿、早白垩世晚期—古近纪中期区域伸展与断陷盆地、古近纪中晚期NE向挤压等7个构造阶段。(2)幕阜山岩体边界主要受NW向、NE向和NEE向等3组断裂控制,其构造机制实质为岩体区断块和岩体外断块对岩浆侵位过程的控制。(3)岩体侵位构造可定性划分为低侵位缓倾接触构造、低侵位陡倾接触构造、高侵位缓倾接触构造和高侵位陡倾接触构造等4类,其中低...  相似文献   

AMT和地电化学测量法在川西雅江木绒锂矿区 深部找矿中的研究及应用     

岳大斌 《地质与勘探》2023,59(4):760-773

川西木绒锂矿区位于雅江穹窿群北东部、甲基卡稀有金属矿田西部外围,有良好的稀有金属成矿前景,但受限于高原地区地形切割深、第四系覆盖层厚,常规物化探方法（土壤测量、大功率电法测量）找矿效果不佳。本文通过在雅江木绒锂矿区进行地电化学测量与AMT测量相配合的综合研究,探寻一套适合于深切割地区深部找矿的技术组合,为在该区域内寻找同类型矿床提供技术方法支撑。通过实验研究,地电化学测量结果显示在500 m以浅Li元素及伴生元素的组合异常对深部锂矿（化）体有良好的指示作用;AMT测量方法的电阻率曲线梯度带能够反映脉状矿化体、伟晶岩的产出部位及大致埋深;通过钻孔验证发现两者异常与矿（化）体位置耦合度非常高,证明该综合手段对深部找矿具有实际意义,可降低找矿风险;同时在矿区外围开展找矿预测,圈定两处找矿靶区,为下一步找矿工作指明方向。  相似文献   

Formation Age and Evolution Time Span of the Koktokay No. 3 Pegmatite,Altai, NW China: Evidence from U–Pb Zircon and 40Ar–39Ar Muscovite Ages          下载免费PDF全文

Qifeng Zhou  Kezhang Qin  Dongmei Tang  Ye Tian  Mingjian Cao  Chunlong Wang 《Resource Geology》2015,65(3):210-231

The Koktokay No. 3 pegmatite is the largest Li–Be–Nb–Ta–Cs pegmatitic rare‐metal deposit of the Chinese Altai orogenic belt, and is famous for its concentric ring zonation pattern (nine internal zones). However, the formation age and evolution time span have been controversial. Here, we present the results of LA‐ICP–MS zircon U–Pb dating and muscovite ⁴⁰Ar–³⁹Ar dating. Four groups of zircon U–Pb ages (～210 Ma, ～193–198 Ma, ～186–187 Ma and ～172 Ma) for Zones II, V, VI, VII, and VIII, and a weighed mean ²⁰⁶Pb/²³⁸U age of 965 ± 11 Ma for Zone IV are identified. Also, Zones II, IV, and VI have muscovite ⁴⁰Ar–³⁹Ar plateau ages of 179.7 ± 1.1 Ma, 182.1 ± 1.0 Ma, and 181.8 ± 1.1 Ma, respectively. Considering previous U–Pb age studies (Zones I, V, and VII), the ages of emplacement, Li mineralization peak, hydrothermal stage of the No. 3 pegmatite are in ranges of 193–198 Ma, 184–187 Ma and 172–175 Ma, with weighted mean ²⁰⁶Pb–²³⁸U ages of 194.8 ± 2.3 Ma, 186.6 ± 1.3 Ma and 173.1 ± 3.9 Ma, respectively. The No. 3 pegmatite formed in the early Jurassic. The results of xenocrysts suggest that there is another pegmatite forming event of around 210 Ma in the mining district and the old zircon U–Pb ages imply that Neoproterozoic crustal rocks pertain to sources of the No. 3 pegmatite. Including the previous muscovite ⁴⁰Ar–³⁹Ar age studies (Zones I and V), a cooling age range of 177–182 Ma is considered as the time of hydrothermal stage and end of formation. The evolution process of the No. 3 pegmatite lasted 16 Ma. Therein, the magmatic stage continued for 9–11 Myr and the magmatic–hydrothermal transition and hydrothermal stages were sustained at 5–7 Ma. These time spans are long because of huge scale, cupola shape, large formation depth, and complex internal zoning patterns and formation processes. Considering some pegmatite dikes in the Chinese Altai, there is an early Jurassic pegmatite forming event.  相似文献