无水氯化锶的制备工艺研究   总被引：1，自引：1，他引：0       下载免费PDF全文

邹兴武  王树轩  杨占寿  王舒娅  祁米香 《盐湖研究》2012,20(2):39-43

依托青海锶资源优势,以次等品碳酸锶和工业盐酸为原料,制备了无水氯化锶。并对除钡、除铁、除硫、脱水干燥等工艺进行了研究。产品能达到一般工业品的要求。氯化锶的制备不仅丰富我省锶产品的种类,而且增加了锶资源企业的抗风险能力。  相似文献   

New Reference Materials,Analytical Procedures and Data Reduction Strategies for Sr Isotope Measurements in Geological Materials by LA-MC-ICP-MS     

Jacob Mulder  Graham Hagen-Peter  Teresa Ubide  Rasmus Andreasen  Ellen Kooijman  Melanie Kielman-Schmitt  Yue-Xing Feng  Bence Paul  Andreas Karlsson  Christian Tegner  Charles Lesher  Fidel Costa 《Geostandards and Geoanalytical Research》2023,47(2):311-336

Laser ablation multi-collector mass spectrometry (LA-MC-ICP-MS) has emerged as the technique of choice for in situ measurements of Sr isotopes in geological minerals. However, the method poses analytical challenges and there is no widely adopted standardised approach to collecting these data or correcting the numerous potential isobaric inferences. Here, we outline practical analytical procedures and data reduction strategies to help establish a consistent framework for collecting and correcting Sr isotope measurements in geological materials by LA-MC-ICP-MS. We characterise a new set of plagioclase reference materials, which are available for distribution to the community, and present a new data reduction scheme for the Iolite software package to correct isobaric interferences for different materials and analytical conditions. Our tests show that a combination of Kr-baseline subtraction, Rb-peak-stripping using βRb derived from a bracketing glass reference material, and a CaCa or CaAr correction for plagioclase and CaCa or CaAr + REE²⁺ correction for rock glasses, yields the most accurate and precise ⁸⁷Sr/⁸⁶Sr measurements for these materials. Using the analytical and correction procedures outlined herein, spot analyses using a beam diameter of 100 μm or rastering with a 50–65 μm diameter beam can readily achieve < 100 ppm 2SE repeatability ("internal") precision for ⁸⁷Sr/⁸⁶Sr measurements for materials with < 1000 μg g^-1 Sr.  相似文献   

Chronology of Early to Mid-Pleistocene sediments in the northern North Sea: New evidence from amino acid and strontium isotope analyses     

《Quaternary Geochronology》2022

Sediments deposited during glacial-interglacial cycles through the Early to Mid-Pleistocene in the North Sea are chronologically poorly constrained. To contribute to the chronology of these units, amino acid racemization (AAR) and strontium (Sr) isotope analyses have been performed on samples from four shallow borings and one oil well along a transect in the northern North Sea. D/L Asp (aspartic acid) values obtained through reverse-phase liquid chromatography in the benthic foraminiferal species Elphidium excavatum is focused on because of consistent results and a good stratigraphic distribution of this benthic species. For the Early Pleistocene, an age model for the well 16/1–8, from the central part of the northern North Sea based on Sr ages allows for dating of the prograding wedges filling the pre-Quaternary central basin. A regional calibration curve for the racemization of Asp in Elphidium excavatum is developed using published ages of radiocarbon-dated samples and samples associated with the previously identified Bruhnes/Matuyama (B/M) paleomagnetic boundary and a Sr age from this study. Based on all the available geochronological evidence, samples were assigned to marine oxygen isotope stages (MIS) with uncertainties on the order of 10–70 ka.Sr ages suggest a hiatus of <2 million years (Ma) possibly due to non-deposition or low sedimentation between the Utsira Formation (Pliocene) and the Early Pleistocene. An increase in sedimentation rates around 1.5 ± 0.07 Ma (∼MIS 51) may partly be due to sediment supply from rivers from the south-east and partly due to the extension of ice sheet around 1.36 ± 0.07 Ma from the Norwegian coast to the central North Sea. A possible basin-wide glaciation occurred around 1.1 Ma (∼ MIS 32) (upper regional unconformity/top of unit Q4 in this study), resulting in erosion and regional unconformity. Two interglacials in the Norwegian Channel have been dated: the Radøy Interglacial to 1.07 ± 0.01 Ma (possibly MIS 31, the ‘super interglacial’), and the Norwegian Trench Interglacial to 0.50 ± 0.02 Ma (possibly MIS 13). A massive till unit identified at the same stratigraphic level in all shallow borings may partly represent an extensive MIS 12 glaciation. This study shows that the combined use of amino acid racemization data and Sr isotope chronology can refine the chronological ambiguities of Quaternary North Sea sediments related partly to the impact of glacial processes.  相似文献   

新疆库米什盆地硝酸盐型盐湖中锶离子迁移富集规律研究          下载免费PDF全文

李长忠  程怀德  张西营  宋建国  马学海  蒋天明  李俊  海擎宇 《岩石矿物学杂志》2021,40(1):89-98

新疆库米什盆地是典型的硝酸盐型盐湖分布区,盆内盐湖中Sr2+的含量明显比新疆其他盐湖要高,但对该地区盐湖中Sr2+的迁移富集规律尚未开展深入研究。本文以库米什盆地硝酸盐型盐湖为研究对象,探讨了研究区硝酸盐型盐湖中Sr2+的迁移富集规律。研究结果表明:①库米什盆地水体和沉积物中的Sr2+均具有自北西至南东向逐渐迁移富集的规律,与河水汇聚方向基本一致,表明盐湖中的Sr2+主要随径流逐渐汇集至成盐凹陷中;②无论是水体还是沉积物中,Sr2+与Ca2+、SO24-等化学组分之间均具有较好的相关性和变化趋势上的一致性,受它们物质补给源的影响较大。盐湖水体在蒸发浓缩作用下,其矿化度逐渐增高,Sr2+含量也随之升高,表明Sr2+的富集与蒸发浓缩作用过程有关;③库米什盆地硝酸盐型盐湖中Sr2+的补给源与盆地北西部的天青石矿床、北东部及北西部的碳酸盐岩(以泥盆系灰岩为主)、盆缘的侵入岩有关。综合分析表明,库米什盆地硝酸盐型盐湖中Sr2+的迁移富集具有多源、多方向补给的特征。  相似文献