A model-based clustering approach for mass composition analysis of high energy cosmic rays     

《Astroparticle Physics》2013

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Characteristics of bottom dissolved oxygen in Long Island Sound,New York     

Younjoo J. Lee  Kamazima M.M. Lwiza 《Estuarine, Coastal and Shelf Science》2008

The variability of bottom dissolved oxygen (DO) in Long Island Sound, New York, is examined using water quality monitoring data collected by the Connecticut Department of Environmental Protection from 1995 to 2004. Self-organizing map analysis indicates that hypoxia always occurs in the Narrows during summer and less frequently in the Western and the Central Basins. The primary factor controlling the bottom DO, changes spatially and temporally. For non-summer seasons, the levels of bottom DO are strongly associated with water temperature, which means DO availability is primarily driven by solubility. During summer, stratification intensifies under weak wind conditions and bottom DO starts to decrease and deviate from the saturation level except for stations in the Eastern Basin. For the westernmost and shallow (<15 m) stations, bottom DO is correlated with the density stratification (represented by difference between surface and bottom density). In contrast, at deep stations (>20 m), the relationship between oxygen depletion and stratification is not significant. For stations located west of the Central Basin, bottom DO continues to decrease during summer until it reaches its minimum when bottom temperature is around 19–20 °C. In most cases the recovery to saturation levels at the beginning of fall is fast, but not necessarily associated with increased wind mixing. Therefore, we propose that the DO recovery may be a manifestation of either the reduced microbial activity combined with the depletion of organic matter or horizontal exchange. Hypoxic volume is weakly correlated to the summer wind speed, spring total nitrogen, spring chlorophyll a, and maximum river discharge. When all variables are combined in a multiple regression, the coefficient of determination (r²) is 0.92. Surprisingly, the weakest variable is the total nitrogen, because when it is excluded the coefficient r² only drops to 0.84. Spring bloom seems to be an important source of organic carbon pool and biological uptake of oxygen plays a more crucial role in the seasonal evolution of bottom DO than previously thought. Our results indicate that the reassessment phase of the Long Island Sound Total Maximum Daily Load policy on nitrogen loading will most likely fail, because it ignores the contributions of the spring organic carbon pool and river discharge. Also, it is questionable whether the goal of 58.5% anthropogenic nitrogen load reduction is enough.  相似文献   

Physico-chemical Speciation of Lead in South San Francisco Bay     

P.B. Kozelka  S. Sañudo-Wilhelmy  A.R. Flegal  K.W. Bruland 《Estuarine, Coastal and Shelf Science》1997,44(6):649-658

The speciation of lead at a site in the South San Francisco Bay was determined using a combination of physical size fractionation and electrochemical analyses. The ‘ total dissolvable ’ Pb was 8·1 nM from analysis of an acidified unfiltered sample. The ‘ dissolved ’ Pb was equal to 0·20 nM (41 ng l⁻¹), only 2·5% of the ‘ total dissolvable ’ Pb. The difference yielded the ‘ particulate ’ Pb equal to 7·9 nM (1·6 μg l⁻¹). Results from crossflow ultrafiltration indicated that almost all (0·19 nM) of the dissolved Pb was ‘ in solution ’ [<10K nominal molecular weight (MW)] and that colloidal Pb (10K MW to 0·2 μm)accounted for onlyc. 1% of the dissolved Pb at this station. This small concentration (0·01 nM) of colloidal Pb may be attributed to the low amount of organic carbon associated with colloid size fraction as determined by dissolved organic carbon analyses.The chemical speciation of lead was determined in the dissolved sample and ultrafiltered sub-sample. Differential pulse anodic stripping voltammetry (DPASV) on a thin mercury film (TMF) rotating glassy carbon disk electrode (RGCDE) was used to distinguish the kinetically labile inorganic species (Pb′) from the Pb-chelated by organic ligands (PbL_i). Lead titration results were similar for both samples revealing that Pb′, PbL_iand excess unbound ligands were present primarily in the ultrafiltrate, rather than in the colloidal phase. The titration data can be interpreted as dissolved Pb being influenced by two classes of Pb-binding ligands. In the dissolved sample, the concentration of the stronger class of ligands was [L₁]=0·89±0·35 nM, with a conditional stability constant ofK^cond_L1,Pb′=3±1×10¹⁰M⁻¹. The weaker class was [L₂]=12·8±1·9 nM, withK^cond_L1,Pb′=4±1×10⁸ M⁻¹. The presence of these ligands, in excess of the dissolved Pb, resulted in [Pb′]=7±2 pM and [Pb²⁺]=0·3 pM (62 pg l⁻¹). While less than 2·4% of the ambient Pb was ‘ in solution ’, it existed chiefly in the form of organic complexes with [PbL₁]=0·15 nM and [PbL₂]=0·03 nM. More significantly, there were large concentrations of unchelated Pb-binding ligands, (L_i′), available to buffer the free Pb²⁺concentration in the event of perturbations in dissolved Pb.  相似文献   

Getting SMARTS on Novae: Highlights of the Early Evolution of Nova V475 Sct     

Guy S. Stringfellow  Frederich M. Walter 《Astrophysics and Space Science》2006,304(1-4):401-403

There is a disconcerting global trend of retiring telescopes of modest aperture, supplanting them instead with fewer expensive telescopes of quite large aperture. As a consequence, the available time and feasibility of following transient objects in astrophysics is diminishing. We show the utility of having a suite of small to moderate aperture telescopes capable of conducting imaging and spectroscopic observations in a service queue mode. The example we provide is the high-cadence early observations of the classical nova V475 Scuti (2003) carried out with the SMARTS suite of telescopes located at CTIO.  相似文献   

Fe K emission in the ultraluminous infrared galaxy Arp 220     

K. Iwasawa  D. B. Sanders  A. S. Evans  N. Trentham  G. Miniutti  H. W. W. Spoon 《Monthly notices of the Royal Astronomical Society》2005,357(2):565-571

Prominent Fe Kα line emission is detected in the XMM–Newton spectrum of the ultraluminous infrared galaxy Arp 220. The centroid of the line is found at an energy of 6.7 keV and the equivalent width of the line is  EW ∼ 1.9 keV  (at 3.5σ significance). A few other spectral features are found at various degrees of significance in the lower energy range on a hard 2.5–10 keV continuum  (Γ∼ 1)  . The large EW of the Fe K line poses a problem with interpreting the hard X-ray emission as integrated X-ray binary emission. A thermal emission spectrum with a temperature of   kT ∼ 7 keV  modified by absorption of   N _H≃ 3 × 10²² cm⁻²  , can describe the 2.5–10 keV continuum shape and the Fe K emission. A hot bubble that is shocked internally in a starburst region would have a similar temperature and gives a good explanation for the observed X-ray properties with a high star formation rate. An ensemble of radio supernovae in a dense environment, as suggested from VLBI imaging, could be another possibility, if such powerful supernovae are produced continuously at a high rate. However, the apparent lack of emission from X-ray binaries is incompatible with the high supernova rate (∼2 SNe yr⁻¹) required by both interpretations. Highly photoionized, low-density gas illuminated by a hidden Compton-thick active galactic nucleus is a possible alternative for the hard X-ray emission, which can be tested by examining whether radiative recombination continua from highly ionized Ca and Fe are present in better quality data from a forthcoming observation.  相似文献   

Electric charge and magnetic flux on rotating black holes in a force-free magnetosphere     

Hyun KyuLee  Chul H.Lee  Maurice H. P. M.van Putten 《Monthly notices of the Royal Astronomical Society》2001,324(3):781-784

The electric charge on rotating black holes is calculated to be ∼ BJ in the force-free configuration of Ghosh, with a horizon flux of ∼ BM ². This charge is gravitationally weak for B ∼10¹⁵ G , so that the Kerr metric applies. Being similar to the electric charge of a magnetar, both electric charge and magnetic flux should be, in sign and order of magnitude, continuous during stellar collapse into a black hole. Extraction of the rotational energy from newly formed black holes may proceed by interaction with the magnetic field.  相似文献   

Production of organic molecules in the outer solar system by proton irradiation: Laboratory simulations     

Thomas Scattergood  Peter Lesser  Tobias Owen 《Icarus》1975,24(4):465-471

In the past few years considerable attention has been given to the determination of likely compounds that could account for the various colors observed in the outer solar system: and to possible formation mechanisms for these compounds. Many experiments have been done using electrical discharges (Chadha, M. S., et al., 1971, Icarus15, 39) and ultraviolet light (Khare, B. N., and Sagan, C., 1973, Icarus20, 311) on mixtures of CH₄, NH₃, and H₂S, which are most likely the dominant minor constituents of the atmospheres of Jupiter, Saturn, Titan, and possibly the other satellites early in their histories. Colored polymers, usually brownish-red, have been produced in these experiments. With the passage of Pioneer 10 around Jupiter, there is another source of energy worthy of consideration, energetic protons (and electrons). Preliminary experiments to investigate the formation of colored polymers and other interesting molecules by the irradiation of gas mixtures by protons are discussed. Two to four Mev protons were used, with corresponding beam fluxes (as measured at 6R_J from the planet) equivalent to approximately 80 Earth years at Jupiter per hour of exposure. As in the other types of experiments, colored polymers have been produced. An important feature of this work is the presence or absence of absorption at 5 μm in the different materials produced; Titan is quite dark at this wavelength and Io is fairly bright. Such features may provide criteria for accepting or rejecting various materials produced in these experiments as reasonable coloring agents for the outer solar system.  相似文献   

Infrared spectrophotometry of Comet IRAS-Araki-Alcock (1983d): a bare nucleus revealed?     

M.S. Hanner  D.K. Aitken  R. Knacke  S. McCorkle  P.F. Roche  A.T. Tokunaga 《Icarus》1985,62(1):97-109

Spectra of the central core and surrounding coma of Comet IRAS-Araki-Alcock (1983d) were obtained at 8–13 μm on 11 May and 2–4 μm on 12 May 1983. Spatially resolved measurements at 10 μm with a 4-arcsec beam showed that the central core was more than 100 times brighter than the inner coma only 8 arcsec away; for radially outflowing dust, the brightness ratio would be a factor of 8. The observations of the central core are consistent with direct detection of a nucleus having a radius of approximately 5 km. The temperature of the sunlit hemisphere was > 300 K. Spectra of the core are featureless, while spectra of the coma suggest weak silicate emission. The spectra show no evidence for icy grains. The dust producton rate on 11.4 May was ～ 10⁵ g/sec, assuming that the gas flux from the dust-producing areas on the nucleus was ～ 10^?5 g/cm²/sec.  相似文献   

A determination of the composition of the Saturnian stratosphere using the IUE     

Peter Winkelstein  John Caldwell  S.J. Kim  M. Combes  G.E. Hunt  V. Moore 《Icarus》1983,54(2):309-318

We reduced ultraviolet spectra of Saturn from the IUE satellite to produce a geometric albedo of the planet from 1500 to 3000 Å. By matching computer models to the albedo we determined a chemical composition consistent with the data. This model includes C₂H₂ and C₂H₆ with mixing ratios and distributions of (9 ± 3) × 10^?8 in the top 20 mbar of the atmosphere with none below for C₂H₂ and (6 ± 1) × 10^?6 also in the top 20 mbar with none below for C₂H₆. The C₂H₂ and C₂H₆ distributions and the C₂H₆ mixing ratio are taken directly from the Voyager IRIS model [R. Courtin et al., Bull. Amer. Astron. Soc.13, 722 (1981), and private communication]. The Voyager IRIS model also includes PH₃, which is not consistent with the uv albedo from 1800 to 2400 Å. Our model requires a previously unidentified absorber to explain the albedo near 1600 Å. After considering several candidates, we find that the best fit to the data is obtained with H₂O, having a column density of (6 ± 1) × 10^?3 cm-am.  相似文献   

Factors affecting the elimination of PCBs in the marine copepod Acartia tonsa     

George B. McManus  Kevin D. Wyman  William T. Peterson  Charles F. Wurster 《Estuarine, Coastal and Shelf Science》1983,17(4):421-430

The effects of feeding, egg laying, and fecal pellet production on the elimination of polychlorinated biphenyls (PCBs) from the marine copepod Acartia tonsa were studied in a series of experiments. Copepods were exposed to ¹⁴C-labelled Aroclor 1254 and allowed to depurate in clean seawater. Copepods fed during depuration eliminated PCBs more rapidly than unfed copepods whether or not the original PCB exposure medium had contained food. Both eggs and fecal pellets contained PCBs during depuration, with the weight specific concentration of PCB in the eggs (up to 407 ppm, dry weight) exceeding four times that in the females that produced them. Female copepods eliminated PCBs twice as rapidly as males, indicating that egg production is an important route for PCB elimination.  相似文献