Paleosols in Central Illinois as Potential Sources of Ammonium in Groundwater     

Justin J. G. Glessner  William R. Roy 《Ground Water Monitoring & Remediation》2009,29(4):56-64

Glacially buried paleosols of pre-Holocene age were evaluated as potential sources for anomalously large concentrations of ammonium in groundwater in East Central Illinois. Ammonium has been detected at concentrations that are problematic to water treatment facilities (greater than 2.0 mg/L) in this region. Paleosols characterized for this study were of Quaternary age, specifically Robein Silt samples. Paleosol samples displayed significant capacity to both store and release ammonium through experiments measuring processes of sorption, ion exchange, and weathering. Bacteria and fungi within paleosols may significantly facilitate the leaching of ammonium into groundwater by the processes of assimilation and mineralization. Bacterial genetic material (DNA) was successfully extracted from the Robein Silt, purified, and amplified by polymerase chain reaction to produce 16S rRNA terminal restriction fragment length polymorphism (TRFLP) community analyses. The Robein Silt was found to have established diverse and viable bacterial communities. 16S rRNA TRFLP comparisons to well-known bacterial species yielded possible matches with facultative chemolithotrophs, cellulose consumers, nitrate reducers, and actinomycetes. It was concluded that the Robein Silt is both a source and reservoir for groundwater ammonium. Therefore, the occurrence of relatively large concentrations of ammonium in groundwater monitoring data may not necessarily be an indication of only anthropogenic contamination. The results of this study, however, need to be placed in a hydrological context to better understand whether paleosols can be a significant source of ammonium to drinking water supplies.  相似文献   

Predicting long-term urban growth in Beijing (China) with new factors and constraints of environmental change under integrated stochastic and fuzzy uncertainties     

Qi?Lu  Ni-Bin?ChangEmail authorView author&#;s OrcID profile  Justin?Joyce 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(7):2025-2044

Numerous studies related to the simulation and prediction of urban growth to address land-use and land-cover (LULC) changes have been conducted in recent years, but very few have considered the impact of climate change, flooding impact, government relocation, corridor cities, and long-term rainfall variations simultaneously. To bridge the gap, this study predicts possible future LULC changes for 2030 and 2050 in Beijing (China), since Beijing is one of the fastest-growing megacities in the world. The proposed integrated modeling analysis covers four key scenarios to reflect the influences of different factors and constraints on LULC changes, in which cellular automata, Markov chain, and multi-criteria evaluation are fully coupled. While fuzzy membership function was used to address the uncertainty associated with the decision analysis, Markov chain, which is regarded as a stochastic process, was applied to predict future urban growth pathways. In addition, a statistical downscaling model driven by possible climate change scenarios was employed to address long-term rainfall variations in Beijing, China. This study differs from previous ones for Beijing in terms of not only the effects of climate change and flooding impact but also the newly-developed economic free trade zone in Xiong’an and the central government’s plan to relocate to the Tongzhou district. Findings indicate that there is no marked difference in LULC over the four key scenarios. Compared to the baseline LULC in 2010, the predicted results indicate that urban expansion is expected to increase more than 6 and 11% in 2030 and 2050, respectively.  相似文献   

Debris-flow-dominated sediment transport through a channel network after wildfire     

Petter Nyman  Walter A.C. Box  Justin C. Stout  Gary J. Sheridan  Saskia D. Keesstra  Patrick N.J. Lane  Christoph Langhans 《地球表面变化过程与地形》2020,45(5):1155-1167

Field studies that investigate sediment transport between debris-flow-producing headwaters and rivers are uncommon, particularly in forested settings, where debris flows are infrequent and opportunities for collecting data are limited. This study quantifies the volume and composition of sediment deposited in the arterial channel network of a 14-km² catchment (Washington Creek) that connects small, burned and debris-flow-producing headwaters (<1 km²) with the Ovens River in SE Australia. We construct a sediment budget by combining new data on deposition with a sediment delivery model for post-fire debris flows. Data on deposits were plotted alongside the slope–area curve to examine links between processes, catchment morphometry and geomorphic process domains. The results show that large deposits are concentrated in the proximity of three major channel junctions, which correspond to breaks in channel slope. Hyperconcentrated flows are more prominent towards the catchment outlet, where the slope–area curve indicates a transition from debris flow to fluvial domains. This shift corresponds to a change in efficiency of the flow, determined from the ratio of median grain size to channel slope. Our sediment budget suggests a total sediment efflux from Washington Creek catchment of 61 × 10³ m³. There are similar contributions from hillslopes (43 ± 14 × 10³ m³), first to third stream order channel (35 ± 12 × 10³ m³) and the arterial fourth to fifth stream order channel (31 ± 17 × 10³ m³) to the total volume of erosion. Deposition (39 ± 17 × 10³ m³) within the arterial channel was higher than erosion (31 ± 17 × 10³ m³), which means a net sediment gain of about 8 × 10³ m³ in the arterial channel. The ratio of total deposition to total erosion was 0.44. For fines <63 μm, this ratio was much smaller (0.11), which means that fines are preferentially exported. This has important implications for suspended sediment and water quality in downstream rivers. © 2019 John Wiley & Sons, Ltd.  相似文献   

Reaction pathways for quartz dissolution determined by statistical and graphical analysis of macroscopic experimental data     

Barry R. Bickmore  Justin C. Wheeler  Kathryn L. Nagy 《Geochimica et cosmochimica acta》2008,72(18):4521-4536

In light of recent work on the reactivity of specific sites on large (hydr)oxo-molecules and the evolution of surface topography during dissolution, we examined the ability to extract molecular-scale reaction pathways from macroscopic dissolution and surface charge measurements of powdered minerals using an approach that involved regression of multiple datasets and statistical graphical analysis of model fits. The test case (far-from-equilibrium quartz dissolution from 25 to 300 °C, pH 1-12, in solutions with [Na⁺] ? 0.5 M) avoids the objections to this goal raised in these recent studies. The strategy was used to assess several mechanistic rate laws, and was more powerful in distinguishing between models than the statistical approaches employed previously. The best-fit model included three mechanisms—two involving hydrolysis of Si centers by H₂O next to neutral (>Si-OH⁰) and deprotonated (>Si-O⁻) silanol groups, and one involving hydrolysis of Si centers by OH⁻. The model rate law is