Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Geological and geomorphological characteristics of landslides triggered by the 2004 Mid Niigta prefecture earthquake in Japan   总被引：8，自引：0，他引：8  

Masahiro Chigira  Hiroshi Yagi 《Engineering Geology》2006,82(4):202-221

The 2004 Mid Niigta prefecture earthquake (M_JMA 6.8) triggered more than one thousand landslides in the Miocene to Quaternary sedimentary rocks in Japan. The most common landslides were shallow disrupted landslides on steep slopes, which has been common in many previous disastrous earthquakes in the world. The Mid Niigta prefecture earthquake also triggered more than one hundred deep landslides, providing valuable information on the conditions for their occurrence. A field investigation and the interpretation of aerial photographs taken before and after the earthquake suggest that reactivation of existing landslides and undercutting of slopes are the most important factors for deep landslides to be triggered by earthquakes. In addition, planar sliding surfaces seem to be essential for the generation of catastrophic landslides triggered by this earthquake. Planar bedding–parallel sliding surfaces were formed at the boundary between the overlying permeable sandstone and underlying siltstone or along the bedding planes of alternating beds of sandstone and siltstone. Sliding surfaces along the slope-parallel oxidation front were formed in the area of black mudstone. New landslides (rockslide-avalanches) occurred with the sliding surfaces in a several-cm thick tuff interbedded in siltstone. One rockslide-avalanche occurred on a slope where buckling deformation preceded the earthquake. Gentle valley bottom sediments were mobilized in many locations, probably because they were saturated and partial liquefaction had occurred due to the earthquake shaking.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

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韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献   

新时期我国区域经济地理学发展问题初探   总被引：4，自引：0，他引：4  

刘曙光 《地域研究与开发》2002,21(2):1-4

我国新时期的区域经济地理学在取得全面发展的同时，在理论体系，研究方法和实践领域等方面还需要进一步的发展，文章根据学习和实践区域经济地理学的体会，初步提出基础理论和应用理论，思维方法和技术方法等方面发展见解，并指出区域创新系统和国际经济技术合作等学科应注意拓展的重要实践领域，最后提出我国区域经济地理学科发展的建议。  相似文献   

华南地区凉果加工业与凉果资源的匹配关系分析——以广东省新兴县为例     

刘一明  胡新艳  牛宝俊 《地域研究与开发》2002,21(2):60-63

文章以广东省新兴县为例，从凉果资源分布与加工能力的匹配关系角度对华南地区凉果资源的分布，凉果加工业的分布与布局，凉果市场分布与竞争力，凉果加工业与资源的匹配关系等进行了分析，并针对华南地区凉果加工业面临的主要问题提供了一些建议。  相似文献   

成都市民消费结构与休闲活动关系研究   总被引：6，自引：0，他引：6  

杨国良 《地域研究与开发》2002,21(2):77-80

城市居民消费水平，消费结构会影响其休闲消费能力，消费意愿，消费方式，消费态度和休闲时空结构，文章以成都市7个城区歌舞，茶棋牌，电影及城市公园休闲活动调查为基础，探讨了城市居民消费结构及其变化与休闲活动特征的关系。研究结果表明，城市居民消费结构的改变对歌舞，茶棋牌娱乐活动影响最大。  相似文献   

南水北调中线工程建设与河南水资源可持续利用   总被引：2，自引：0，他引：2  

赵永江  刘荷芬  贾虎 《地域研究与开发》2002,21(2):85-88

文章通过对河南省水资源开发利用现状，存在的主要问题，水资源供需平衡以及南水北调工程对河南省水资源利用的影响论述，提出了在拟定南水北调工程供水方案中，应通过强化节水，加强水资源保护，严格控制地下水开采，将水资源作为商品等措施，促进河南省水资源的可持续开发利用。  相似文献   

区域视觉形象识别系统设计的理论与实践   总被引：6，自引：0，他引：6  

禹贡 《地域研究与开发》2002,21(4):7-9

目前，全国各地正在兴起区域形象设计与建设的浪潮，但如何把区域形象信息系统地传递出去，这方面的理论研究大大落后于实践。文章就区域形象信息传递的有效工具－区域视觉识别系统设计的主要内容，设计的原则，设计的基本流程等在理论与实践上作了较为详细的探讨，并就区域视觉识别系统设计方案的经济学论证作了一些有益探讨。  相似文献