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31.
Laser Ablation ICPMS study of trace element partitioning between plagioclase and basaltic melts: an experimental approach 总被引：3，自引：1，他引：3
Mario Aigner-Torres Jon Blundy Peter Ulmer Thomas Pettke 《Contributions to Mineralogy and Petrology》2007,153(6):647-667
Plagioclase-melt partition coefficients (D) for 34 trace elements at natural concentration levels were determined experimentally in a natural MORB composition at atmospheric
pressure using thin Pt-wire loops. Experiments were carried out at three temperatures (1,220, 1,200, and 1,180°C), and at
three different oxygen fugacities (fO2 = IW, QFM, air) in order to assess the effect of fO2 on the partitioning of elements with multiple valence (Fe, Eu, Cr). Run products were analyzed by laser-ablation ICP-MS.
Most trace element Ds increase slightly as temperature decreases, except for D
Zr, D
Fe, D
Eu and D
Cr that vary systematically with fO2. Applying the Lattice Strain Model to our data suggests the presence of Fe2+ entirely in the octahedral site at highly to moderate reducing conditions, while Fe3+ was assigned wholly to the tetrahedral site of the plagioclase structure. Furthermore, we provide a new quantitative framework
for understanding the partitioning behaviour of Eu, which occurs as both 2+ and 3+ cations, depending on fO2and confirm the greater compatibility of Eu2+, which has an ionic radius similar to Sr, relative to Eu3+ in plagioclase and the higher Eu2+/ Eu3+ under reducing conditions. For petrogenetic basaltic processes, a combined fractionation of Eu2+–Sr and Fe–Mg by plagioclase has considerable potential as an oxybarometer for natural magmatic rocks. 相似文献
32.
Dissolution rates were calculated for a range of grain sizes of anorthite and biotite dissolved under far from equilibrium conditions at pH 3, T = 20 °C. Dissolution rates were normalized to initial and final BET surface area, geometric surface area, mass and (for biotite only) geometric edge surface area. Constant (within error) dissolution rates were only obtained by normalizing to initial BET surface area for biotite. The normalizing term that gave the smallest variation about the mean for anorthite was initial BET surface area. In field studies, only current (final) surface area is measurable. In this study, final geometric surface area gave the smallest variation for anorthite dissolution rates and final geometric edge surface area for biotite dissolution rates. 相似文献
33.
Reaction-induced weakening of plagioclase–olivine composites 总被引：1，自引：0，他引：1
The localisation of strain into natural ductile shear zones is often associated with the occurrence of metamorphic reactions. In order to study the effects of solid–solid mineral reactions on plastic deformation of rocks, we have investigated the shear deformation of plagioclase–olivine composites during the reaction plagioclase + olivine → orthopyroxene + clinopyroxene + spinel (± garnet). Microstructures of plagioclase–olivine composites were studied after shear deformation experiments in a Griggs apparatus. Experiments were performed on anorthite–forsterite (An–Fo) and labradorite–forsterite (Lab–Fo) composites at 900 °C, confining pressures between 1000–1600 MPa and with constant shear strain rates of 5 × 10−5 s−1.In absence of reaction, Lab–Fo composites are stronger than pure olivine and labradorite end-members that deform with a high temperature plasticity mechanism. Lab–Fo composites strain–harden due to the inhibition of extensive recrystallisation by interphase boundaries.In An–Fo composites, the reaction induces strain weakening by a switch from dislocation creep to grain size sensitive deformation mechanisms through the development of fine-grained (size < 0.5 μm) polyphase reaction products. Interconnecting layers of reaction products accommodate most of the applied strain by grain size sensitive creep. Recovery processes are pronounced during syndeformational reaction: original anorthite and olivine dynamically recrystallise by subgrain rotation and bulging recrystallisation. Presumably, the dynamic recrystallisation is caused by reduced stress conditions and partitioning of strain and strain rates between the new reaction products and the relict An–Fo grains. The results of our experiments are in good agreement with natural observations of shear localisation in the lower crust and upper mantle, and imply that anhydrous mineral reactions can be important causes for localisation of deformation. 相似文献
34.
浙江普陀花岗杂岩体中的石英闪长质包体：斜长石内部复杂环带研究与岩浆混合史记录 总被引：11，自引：7，他引：11
浙江普陀花岗杂岩体包含若干石英闪长质包体,该类包体中存在三种不同类型的斜长石:正常环带的斜长石、筛孔构造的斜长石和酸性斜长石为核的“反环带”斜长石。根据斜长石的环带构造特征和成分分析,认为本区的岩浆演化过程大致如下:下部基性岩浆注入到上覆酸性岩浆中并进行混合作用,酸性岩浆中已结晶的富钠质斜长石晶体进入偏基性的混合岩浆中,部分熔融形成筛孔构造;随着端员岩浆的进一步混合,富钠质斜长石晶体与中性混合熔体仅形成粗糙的边界,而保留原先构造特征;同时混合岩浆可以直接结晶出正常环带斜长石,呈单颗粒或以膜的形式包围其它环带构造的长石。本文还通过与平潭甬闪辉长岩杂岩体内筛孔斜长石的对比,认为斜长石的环带构造和成分可以反映岩浆源区特征和岩浆演化历史。 相似文献
35.
The present study aimed to test reliability of luminescence and electron spin resonance (ESR) methods to date tephra. We investigated on three Japanese marker tephras, Ikeda-ko (6.4 ka), Aira-Tn (30 ka) and Aira-Iwato (45–50 ka). A systematic studies were performed using different minerals (quartz and feldspar), different grain fractions (75–250 and 250–500 μm), different luminescence and ESR signals, like optically stimulated luminescence (OSL) of quartz, infrared stimulated luminescence (IRSL) of feldspar, including recently developed least faded post infrared IRSL (pIR-IRSL), and ESR signals from paramagnetic centers Al and Ti–Li of quartz. Ages obtained using pIR-IRSL signal of plagioclase with preheat of 320 °C, 60 s and stimulation at 300 °C are consistent with the reference ages. High dose detection range (up to ∼600 Gy) and accurate age estimation enable pIR-IRSL of feldspar a promising methodology to date quaternary tephra. ESR ages from quartz are grossly correlated with the reference ages but large deviation and large associated errors are observed, possibly due to either low signal to noise ratio or heterogenous dose response of different aliquot in multiple aliquot additive dose (MAAD) approach. 相似文献
36.
胶东早白垩世中-酸性脉岩造岩矿物微区地球化学特征研究 总被引：1，自引：1，他引：0
胶东地区广泛发育早白垩世中-酸性脉岩群,但是其成因演化及成岩地质背景至今仍存在诸多争论。本文利用电子探针(EMPA)与激光剥蚀电感藕合等离子质谱(LA-ICP-MS)技术分析了胶东早白垩世石英闪长脉岩与闪长脉岩中主要造岩矿物(斜长石和黑云母)的主、微量元素组成;并结合岩石地球化学特征,对两者的岩浆源区和岩浆演化进行了研究探讨。石英闪长脉岩与闪长脉岩中黑云母低于检测线的Ca O含量与斜长石主量元素之间良好的线性关系指示两者为未受到后期变质作用影响的原生矿物,进一步说明胶东中生代石英闪长脉岩与闪长脉岩岩浆形成后,在上涌成岩过程中未受到变质作用的影响。石英闪长脉岩中壳源黑云母矿物成分基本一致的,以及斜长石正环带中核边部线性变化的An值与Fe、Mg、Sr、Ba等不相容元素特征指示石英闪长脉岩源于华北克拉通东部古老的加厚下地壳部分熔融作用,并在岩浆演化早期和晚期有一定幔源镁铁质岩浆混入,整个岩浆演化过程并未受到大气、俯冲、变质流体混入或构造作用的影响。闪长脉岩中黑云母矿物较大的Fe2+/(Fe2++Mg)比值范围,Al含量与结晶压力高度正相关以及斜长石中不相容元素特征指示本次研究中胶东闪长脉岩源自俯冲的板片来源的流体或沉积物混入所形成富集岩石圈地幔源区。胶东早白垩世石英闪长脉岩与闪长脉岩形成的大地构造动力学背景为古太平洋板俯冲-回撤引起热-机械侵蚀,进而导致岩石圈地幔减薄。在此情况下软流圈地幔上涌加热导致胶东富集岩石圈地幔部分熔融形成地幔熔体。这些幔源熔体经历分离结晶形成早白垩世闪长脉岩。此外,幔源镁铁质岩浆持续加热导致加厚下地壳部分熔融,形成了石英闪长脉岩。 相似文献
37.
Despite the fact that porphyry Cu deposits contain large amounts of Cu in one or more small stocks, few studies have discussed evidence for significant magma recharge in porphyry Cu deposits. A systematic elemental and Sr isotopic study of plagioclase crystals from mineralized diorite and granodiorite porphyry constrains the processes of crystallization and magma recharge at the Baogutu reduced porphyry copper deposit, western Junggar, NW-China. Large compositional changes in An (12–24 mol%) are observed along with strong positive correlations between An and FeO. Significant resorption textures are also preserved in plagioclase crystals as well as repeated oscillatory zoning in An and FeO, and complex Sr isotope variations. Three types of crystals with different core-to-rim Sr isotope variations are recognized. Type I crystals have core-to-rim increases in (87Sr/86Sr)i that could be explained by diffusion. For example, Sr isotope variations recorded in BCK2-1-2 crystal could be generated by diffusion with simulated maximum crystal residence times of 100–500 years with the proximate value of ∼300 years. Type II crystals with different variation trends in (87Sr/86Sr)i on opposite sides of the core could be produced either by multi-stage crystallization or by analytical uncertainty. Whereas, type III crystals with complex core-to-rim variations in (87Sr/86Sr)i, may record repeated magma recharge events. All these results suggest repeated recharging of the magma chamber by hotter, more mafic and less radiogenic Sr isotope melts. Therefore, more mafic melt injection recorded in plagioclase profiles may provide significant metal contributions to the magma chamber, which ultimately results in Cu mineralization at the Baogutu reduced porphyry copper deposit. 相似文献
38.
Gullu Deniz Dogan-Kulahci Abidin Temel Alain Gourgaud 《Chemie der Erde / Geochemistry》2018,78(1):103-115
The Cemilköy ignimbrite is one of the voluminous ignimbrite deposits in Cappadocia. The Cemilköy ignimbrite contains pumice and lithic clasts of volcanic and ophiolitic origin in an ash matrix. The unwelded Cemilköy ignimbrite is distinguished from other deposits in Cappadocia by flattened pumices, elongate vesicles and a slaty fabric. The mineral assemblage of the Cemilköy ignimbrite is plagioclase, biotite, quartz and oxides (magnetite and Ti-magnetite) and the matrix is glassy. Eutaxitic texture is dominant and all pumice clasts have a vitrophyric-porphyritic texture. The same textural properties were observed throughout the spatial distribution of Cemilköy ignimbrite. Microprobe studies reveal that plagioclase compositions range from albite through oligoclase-andesine. Estimated plagioclase-liquid temperatures (T) and pressures (P) are varying between 806 and 847?°C and 4.2–7.1 (kbar), and the H2O content of the melt is estimated to have been 5?wt.% from the pumice clasts. Based on geochemical data, the Cemilköy ignimbrite is rhyolitic and calc-alkaline in character, and all pumice clasts are enriched in LIL and LRE elements relative to HFS elements. Negative Nb, Ta and Ti anomalies, ratios of Ba/Nb >28 (56–77), Ba/Ta ?450 (590–700) and Th/Yb vs. Ta/Yb are consistent with a subduction-related origin. According to the geochemical and mineralogical-petrographical data, the Cemilköy ignimbrite originated from partial melting of a mantle source which was enriched during previous subduction processes with variable degrees of assimilation fractional crystallization (AFC) through time and Cemilköy ignimbrite erupted from a crustal magma chamber at shallow to intermediate depth. 相似文献
39.
辽西建昌-凌源地区早侏罗世水泉沟组底部英安岩中斜长石和角闪安山岩中的角闪石具有环带结构。对斜长石用电子探针分析方法研究,发现较完整的斜长石晶体是由具反环带特征的核部和5个具正环带特征的振荡环带组成,核部与振荡环带之间存在熔蚀面。采用相图和晶体环带样式理论分析得出,核部的反环带指示岩浆中无水矿物结晶使岩浆房中的P_(H_2O)增大,熔蚀面代表了 P_(H_2O)增大到某一临界值导致岩浆房上覆围岩破裂,5个振荡环带反映岩浆房上覆围岩破裂后在岩浆房中心和边缘之间岩浆发生过强对流并最终喷出地表。具环带结构的角闪石的结晶压力(核部(5.8±0.5)×10~8Pa,边部(4.8±0.5)×10~8 Pa)说明,岩浆房的深度为17.5±1.8km,岩浆房开放前流体超压达到过1×10~8 Pa 左右。推断,辽西建昌-凌源地区早侏罗世早期地壳岩石圈上部处于压应力状态,下部处于张应力状态。 相似文献
40.
Granodiorite from the Gęsiniec Intrusion, Strzelin Crystalline Massif, SW Poland contains complexly zoned plagioclases. Five chemically and structurally distinct zones can be correlated among crystals: ‘cores’ (25–35% An), inner mantles (40–45% An), outer mantles (40–25% An), resorption zones (35–50% An) and rims (35–30% An). Good structural and chemical (major and trace elements) correlation of zones between crystals indicates that zonation was produced by changes in conditions of crystallization on a magma chamber scale. Plagioclase, being the liquidus phase, records a time span from the beginning of crystallization to emplacement and rapid cooling of granodiorite as thin dykes.
Crystallization began with the formation of inner mantles. The paucity and different sizes of inner mantles suggests slow crystallization in high temperature magma. Normally zoned inner mantles were formed under increasing undercooling. Compositional trends in mantles suggest closed system crystallization.
The major resorption zones were caused by injection of less evolved magma as indicated by the strontium increase in plagioclase. The injection triggered a rapid rise of magma and plagioclase crystals facilitating mixing but also inducing fast, kinetically controlled growth of complex multiple, oscillatory zonation within resorption zones. The ascent of magma caused decompression melting of plagioclase and produced melt inclusions within inner mantles—the ‘cores’. The decompression range is estimated at a minimum of 2 kbar. Emplacement of granodiorite as thin dykes allow rapid cooling and preservation of magmatic zonation in plagioclases. Melt inclusions crystallized completely during post-magmatic cooling.
The zonation styles of plutonic plagioclase differ markedly from volcanic ones suggesting different magma evolution. Zones in plutonic plagioclase are well correlated indicating crystallization in quiescent magma where crystals accumulation and compositional magma stratification may occur. Crystals probably did not travel between different regimes. Resorption occurred but as single albeit complex episodes. Good correlation of zones in plutonic plagioclases allows a distinction between the main processes controlling zonation and superimposed kinetic effects. 相似文献