A natural gas hydrate-oil-gas system in the Qilian Mountain permafrost area,northeast of Qinghai-Tibet Plateau     

《China Geology》2020,3(4):511-523

Natural gas hydrate, oil and gas were all found together in the Qilian Mountain permafrost area, northeast of Qinghai-Tibet Plateau, China. They are closely associated with each other in space, but whether they are in any genetic relations are unknown yet. In this paper, a hydrocarbon gas-generation series, gas-fluid migration series and hydrocarbon gas-accumulation series are analyzed to probe the spatial, temporal and genetic relationships among natural natural gas hydrate, oil and gas. The subsequent results show that natural gas hydrate, oil and gas actually form a natural gas hydrate-oil-gas system. Based on the Middle Jurassic and the Upper Triassic hydrocarbon gas-generation series, it is divided into four major sub-systems in the study area: (1) A conventional Upper Triassic gas-bearing sub-system with peak hydrocarbon gas-generation in the late Middle Jurassic; (2) a conventional Middle Jurassic oil-bearing sub-system with low to mature hydrocarbon gas-generation in the late Middle Jurassic; (3) a natural gas hydrate sub-system with main gas source from the Upper Triassic gas-bearing sub-system and minor gas source from the Middle Jurassic oil-bearing sub-system as well as little gas source from the Middle Jurassic coal-bed gas and the microbial gas; (4) a shallower gas sub-system with microbial alteration of the main gas source from the Upper Triassic gas-bearing sub-system. This natural gas hydrate-oil-gas system and its sub-systems are not only theoretical but also practical, and thus they will play an important role in the further exploration of natural gas hydrate, oil and gas, even other energy resources in the study area.  相似文献   

Petrogenesis of multistage S-type granites from the Malay Peninsula in the Southeast Asian tin belt and their relationship to Tethyan evolution     

《Gondwana Research》2020

The relationship between plate tectonics and the reworking of continental crust remains controversial. Multistage, hornblende-free, S-type granites across the Malay Peninsula Sn belt are ideal for investigating this research question. Here we present zircon U-Pb ages, in-situ apatite Nd and zircon Hf isotope data, and whole-rock major and trace element data for these S-type granites and spatially associated dykes. Four generations of Permian–Triassic (276–272, 262–260, 231–222, and 202 Ma) S-type granites were identified. The different S-type granites show distinct in-situ zircon Hf and apatite Nd isotopic compositions, implying generation from different sedimentary protoliths. Input of mantle-derived components for the formation of all these S-type granites, further indicating that both continental crustal reworking and growth occurred in the Malay Peninsula during the Permian–Triassic. A 250 Ma dolerite dyke in the Eastern Province was derived from an E-MORB-like mantle source. However, a 202 Ma monzonite dyke in the Western Province, was derived from mafic magmas produced by the melting of enriched mantle, followed by subsequent incorporation of crustal materials. All these S-type granitic magmas were reduced that inherited from sedimentary protoliths, which were favourable for Sn mineralization. Apatite F-Cl concentrations and F/Cl ratios in the S-type granites and related dykes changed systematically through time. We infer that the formation of these S-type granites and related dykes corresponds to the Palaeo-Tethyan evolution (i.e., early subduction of Palaeo-Tethyan oceanic lithosphere and subsequent collision between the Sibumasu and Indochina blocks). Our study also support that multistage S-type granites can be generated in distinct tectonic environments at different times in the same region.  相似文献   

Mineral Deposit Model of Cu–Fe–Au Skarn System in the Edongnan Region, Eastern China     

XIE Guiqing  MAO Jingwen  ZHU Qiaoqiao  HAN Yingxiao  LI Wei  DUAN Chao  YE Hui 《《地质学报》英文版》2020,94(6):1797-1807

Cu and Fe skarns are the world’s most abundant and largest skarn type deposits, especially in China, and Au-rich skarn deposits have received much attention in the past two decades and yet there are few papers focused on schematic mineral deposit models of Cu–Fe–Au skarn systems. Three types of Au-rich deposits are recognized in the Edongnan region, Middle–Lower Yangtze River metallogenic belt: ~140 Ma Cu–Au and Au–Cu skarn deposits and distal Au–Tl deposits; 137–148 Ma Cu–Fe; and 130–133 Ma Fe skarn deposits. The Cu–Fe skarn deposits have a greater contribution of mantle components than the Fe skarn deposits, and the hydrothermal fluids responsible for formation of the Fe skarn deposits involved a greater contribution from evaporitic sedimentary rocks compared to Cu–Fe skarn deposits. The carbonate-hosted Au–Tl deposits in the Edongnan region are interpreted as distal products of Cu–Au skarn mineralization. A new schematic mineral deposit model of the Cu–Fe–Au skarn system is proposed to illustrate the relationship between the Cu–Fe–Au skarn mineralization, the evaporitic sedimentary rocks, and distal Au–Tl deposits. This model has important implications for the exploration for carbonate–hosted Au–Tl deposits in the more distal parts of Cu–Au skarn systems, and Fe skarn deposits with the occurrence of gypsum-bearing host sedimentary rocks in the MLYRB, and possibly elsewhere.  相似文献   

新疆别也萨麻斯矿区钽锰矿的矿物学特征及其TIMS U-Pb定年     

何晗晗  艾尔肯&#;吐尔孙  王登红  王瑞江  陈振宇 《岩矿测试》2020,39(4):609-619

钽矿是我国的紧缺资源,近年来对别也萨麻斯地区钽矿取得了找矿新进展,包括新矿点的发现以及花岗伟晶岩型稀有金属资源的找矿突破。区内伟晶岩脉广泛发育,为探究含矿脉体的成矿时代、查明区内典型铌钽矿物的矿物学特征,本文以L18号伟晶岩脉中的钽锰矿为研究对象,对其物理性质、化学成分、地质年代等进行了分析。应用电子探针测试钽锰矿的化学组成,热电离质谱法(TIMS)测定其U-Pb年龄,确定含矿脉体的形成年代。结果表明,研究区钽锰矿中Ta_2O_5含量为51.58%～74.80%,均值68.49%,Nb_2O_5含量为6.15%～27.63%;部分主量元素分布不均,未表现出规律的分带性,但矿物颗粒中心部位的CaO含量较边部低,横剖面上SiO_2含量相对稳定,TiO_2与WO_3显示不规律波动。这种特征表明钽锰矿并非单纯由结晶分异作用形成,而是可能受到了后期交代作用的影响。钽锰矿的U-Pb年龄为160Ma,说明钽锰矿化发生于晚侏罗世早期,与围岩海西期二云母花岗岩相差甚远,后者并非L18号脉体的成矿母岩。  相似文献   

甘肃柳园地区早二叠世正长花岗斑岩脉锆石U-Pb年代学、岩石地球化学特征——对北山造山带晚古生代构造背景的指示     

孙海瑞  吕志成  于晓飞  李永胜  杜泽忠  吕鑫  公凡影 《吉林大学学报(地球科学版)》2020,50(5):1433-1449

甘肃北山地区位于中亚造山带中段，是诠释中亚造山带构造演化的关键区域之一，长期以来受到地质学界的广泛关注。柳园地区位于甘肃北山南带，区内脉岩发育，这些岩脉的研究可以为阐释北山造山带晚古生代构造背景提供更多证据。基于此，本文选取位于甘肃柳园地区的正长花岗斑岩脉开展了系统的锆石U-Pb-Hf同位素和全岩主量、微量元素分析。LA-ICP-MS锆石U-Pb分析显示，岩脉侵位于早二叠世（（288.5±1.4）Ma）。全岩地球化学分析显示，正长花岗斑岩脉的SiO₂和全碱质量分数较高，Fe、Mg、Ca、Al和P质量分数较低，Rb、Th、U和Pb相对富集，Ba、Nb、La、Ce、Sr和Ti等元素相对亏损，Eu负异常显著，具有较高的Rb/Sr值和较低的K/Rb值及锆石饱和温度（730~844℃，集中于740℃左右），显示该岩脉为高钾钙碱性高分异I型花岗岩，并具有俯冲带岩浆活动的地球化学特征。正长花岗斑岩脉具有较低的Zr/Hf值（18.42~28.01，平均值为22.37）和Th/U值（3.82~7.99，平均值为5.34），与平均地壳组分接近，锆石ε_Hf（t）值为2.94~9.66，平均值为5.72，T_DM2值为955~611 Ma，指示源区主体为新元古代地壳的部分熔融，并存在幔源物质加入。根据构造判别图解并结合前人关于二叠纪区域构造变形、盆地沉积物源、岩浆演化等方面的研究结果，笔者认为该正长花岗斑岩脉形成于俯冲作用过程中的局部伸展环境，并认为北山地区增生造山事件至少持续到早二叠世。  相似文献   

湖南仁里超大型钽铌矿床工作进展及找矿思路     

杨世珍  周芳春  李建斌  刘翔  李建康  黄志飚  苏俊男  李鹏 《中国地质调查》2020,7(4):28-36

湖南仁里超大型钽铌矿床钽铌铍矿资源丰富,Ta₂O₅资源量达到了超大型规模,BeO资源量达到了大型规模。为进一步研究湖南仁里超大型钽铌矿床稀有金属的赋存特征、成矿规律及矿产资源综合利用前景,开展了地球化学分析、电子探针、包裹体、同位素测年及可选性试验等研究工作,通过系统梳理仁里超大型钽铌矿床的工作进展,进一步探讨了该矿床的下一步找矿思路。仁里钽铌矿床共(伴)生矿种多,稀有金属综合回收率及矿产资源采选综合利用率高,具有极大的开发利用价值,可作为绿色、环保、无尾矿范例进行高效勘查与开发。仁里矿区钽铌铍矿资源丰富,具有较好的找矿潜力,加大地质勘查资金投入有望取得钽铌铍锂等稀有金属找矿新进展。下一步应对矿区2、3、5、6号主矿脉深部矿体进行控制,力争取得钽铌铍矿找矿突破,同时加强对矿区西部或西南部隐伏锂辉石白云母钠长石伟晶岩的研究工作,力争取得锂辉石白云母钠长石伟晶岩型锂矿找矿突破。  相似文献   

LA-ICP-MS in situ analyses of the pyrites in Dongyang gold deposit,Southeast China: Implications to the gold mineralization     

《China Geology》2020,3(2):230-246

The Dongyang gold deposit is a newly discovered epithermal deposit in Fujian Province, Southeast China, along the Circum-Pacific metallogenic belt. Herewith, the authors present mineralogical, scanning electron microscope, and laser ablation inductively coupled clasma mass spectrometry analysis to reveal the relations between Au and Te, As, S, Fe, etc., and discuss the gold precipitation process. The pyrites in this deposit are Fe-deficient, and are enriched in Te and As. The authors infer that As was mainly in form of As-complexes, and Te-Au-Ag inclusions/solid solution also exsits in the Py I. Along with the depletion of Te and As, they were less active chemically in the Py II, and Au may be incorporated into As-rich and Fe-deficient surface sites by chemisorption onto As-rich growth surfaces. Because of the incorporation of new fluid, Te and As became the most active chemically in the Py III, which was the main elements precipitation stage, and As dominantly substituted for S in the lattice of pyrite, due to the more reducing condition. The authors propose Au was in form of invisible gold, and the incorporation of gold can be considered as post-pyrite event, while the Au-bearing minerals were result of post incorporation of gold in arsenian pyrite.  相似文献   

Middle Permian organic carbon isotope stratigraphy and the origin of the Kamura Event     

《Gondwana Research》2020

Large carbon cycle perturbations associated with the Middle Permian (Capitanian) mass extinction have been widely reported, but their causes and timing are still in dispute. Low resolution carbon isotope records prior to this event also limit the construction of a Middle Permian chemostratigraphic framework and global or local stratigraphic correlation, and hence limit our understanding of carbon cycle and environmental changes. To investigate these issues, we analyzed the ¹³C_org values from the Middle Permian chert-mudstone sequence (Gufeng Formation) in the Lower Yangtze deep-water basin (South China) and compared them with published records to build a chemostratigraphic scheme and discuss the underlying environmental events. The records show increased δ¹³C_org values from late Kungurian to early Guadalupian, followed by a decrease to the late Wordian/early Capitanian. The early-mid Capitanian was characterized by elevated δ¹³C_org values suggesting the presence of the “Kamura Event”: an interval of heavy positive values seen in the δ¹³C_carb record. We propose that these heavy Capitanian δ¹³C values may be a response to a marked decline in chemical weathering rates on Pangea and associated reduction in carbonate burial, which we show using a biogeochemical model. The subsequent negative δ¹³C excursion seen in some carbonate records, especially in shallower-water sections (and in a muted expression in organic carbon) coincide with the Capitanian mass extinction may be caused by the input of isotopically-light carbon sourced from the terrestrial decomposition of organic matter.  相似文献   

语义尺度影响的相离区域合并与拓扑关系计算          下载免费PDF全文

王占刚  吴自兴  王想红 《武汉大学学报(信息科学版)》2018,43(11):1712-1718

拓扑关系随着语义尺度的变化需要重新推理或者计算。当粗略语义尺度下的区域对象由详细尺度下的有限个区域合并而成时, 区域对象间的拓扑关系可采用已有的组合推理方法得到, 然而这些方法只适用于简单对象并存在多解性。针对此问题, 提出了基于9交模型的拓扑关系多尺度计算方法, 分别针对相离区域合并和相邻区域合并定义了9交矩阵操作算子, 可利用详细语义尺度的拓扑关系直接计算出合并区域间的9交矩阵。利用9交矩阵操作算子得到的计算结果值域为复杂区域对象间所有可能的拓扑关系, 且不存在多解性, 通过消除歧义性还可扩展9交矩阵操作算子, 适用于多个相离简单区域组合的复杂区域。  相似文献   

The geothermal formation mechanism in the Gonghe Basin: Discussion and analysis from the geological background     

《China Geology》2018,1(3):331-345

The Gonghe Basin, a Cenozoic down-warped basin, is located in the northeastern part of the Qinghai-Xizang (Tibetan) Plateau, and spread over important nodes of the transfer of multiple blocks in the central orogenic belt in the NWW direction. It is also called “Qin Kun Fork” and “Gonghe Gap”. The basin has a high heat flow value and obvious thermal anomaly. The geothermal resources are mainly hot dry rock and underground hot water. In recent years, the mechanism of geothermal formation within the basin has been controversial. On the basis of understanding the knowledge of predecessors, this paper proposes the geothermal formation mechanism of the “heat source–heat transfer–heat reservoir and caprock–thermal system” of the Gonghe Basin from the perspective of a geological background through data integration-integrated research-expert, discussion-graph, compilation-field verification and other processes: (1) Heat source: geophysical exploration and radioisotope calculations show that the heat source of heat in the basin has both the contribution of mantle and the participation of the earth’s crust, but mainly the contribution of the deep mantle. (2) Heat transfer: The petrological properties of the basin and the exposed structure position of the surface hot springs show that one transfer mode is the material of the mantle source upwells and invades from the bottom, directly injecting heat; the other is that the deep fault conducts the deep heat of the basin to the middle and lower parts of the earth’s crust, then the secondary fracture transfers the heat to the shallow part. (3) Heat reservoir and caprock: First, the convective strip-shaped heat reservoir exposed by the hot springs on the peripheral fault zone of the basin; second, the underlying hot dry rock layered heat reservoir and the upper new generation heat reservoir and caprock in the basin revealed by drilling data. (4) Thermal system: Based on the characteristics of the “heat source-heat transfer-heat reservoir and caprock”, it is preliminarily believed that the Gonghe Basin belongs to the non-magmatic heat source hydrothermal geothermal system (type II2₁) and the dry heat geothermal system (type II2₂). Its favorable structural position and special geological evolutionary history have given birth to a unique environment for the formation of the geothermal system. There may be a cumulative effect of heat accumulation in the eastern part of the basin, which is expected to become a favorable exploration area for hot dry rocks.  相似文献