Evaluating the Effects of Autofluorescence during Raman Hyperspectral Imaging          下载免费PDF全文

Julienne R. Emry  Alison Olcott Marshall  Craig P. Marshall 《Geostandards and Geoanalytical Research》2016,40(1):29-47

Raman hyperspectral imaging is becoming a popular technique to analyse geological materials. Autofluorescence can affect the quality of the spectra that comprise hyperspectral data sets. Few studies have addressed potential misinterpretation of Raman images from hyperspectral data sets affected by autofluorescence. Additionally, little work has been done to develop methods for identifying the spatial distribution of spectra affected by autofluorescence. This study illustrates how autofluorescence may lead to misinterpretation of the distribution of materials based on intensity at a point images. A method is proposed utilising signal to axis analysis to create images that identify regions affected by autofluorescence. Post‐processing baseline correction is often used to address autofluorescence, and most software programs utilise a form of partial least squares regression modelling based on a subjective choice of polynomial order. This study shows that an inappropriate choice of polynomial order can introduce error, which may lead to misinterpretation of Raman images. A signal to axis analysis method is proposed to statistically compare seemingly ‘appropriate’ baseline correction trials. Although post‐processing of hyperspectral data sets and creating Raman images seem simple, data quality issues such as autofluorescence must be considered. If baseline correction is deemed necessary, it should be addressed as an experiment involving statistical comparison.  相似文献   

Sediment velocity estimation using iterative 3-D migrations of short offset seismic reflection data in deep water     

Shipley  Thomas H.  Bangs  Nathan L.  Henning  Alison T. 《Marine Geophysical Researches》1998,20(6):479-494

In deep ocean settings where water depth greatly exceeds the source-to-receiver length, the geometry is insufficient for accurate determinations of velocity from reflection-moveout. However, velocities are crucial for estimates of physical properties and image processing. Focusing analyses with conventional post-stack two-dimensional migration improves images, but does not produce geologically meaningful velocities except in the special case of a two-dimensional earth. For the more general case of the three-dimensional earth there is no a priori method to determine the degree of geometrical complexity. We present a technique using a short-offset three-dimensional (3-D) data set over the 5 km deep trench west of the Lesser Antilles. These data illustrate highly sensitive post-stack 3-D focusing analyses (± 20 m s^–1 interval velocities), and the relationship of these seismically derived velocities to rock velocities. In our Barbados example we were able to establish the presence of a widespread 80-160 m thick low-velocity zone at and above the main low-angle fault. This observation suggests the water-rich décollement leaks water into the overlying sections. Also evident is a low-velocity section associated with turbidite sands. These results are confirmed with sparse logging data and well samples. Deep-water short offset 3-D experiments provide a potentially effective approach for velocity estimation, replacing the operational complexity of long-offsets with simpler short-offset techniques. In areas of structural complications and abundant diffracted energy, it is a surprisingly accurate method, utilizing the high fidelity 3-D wavefield and the information carried in zero-offset diffraction ellipsoids. The velocity used to properly collapse a diffraction ellipsoid is explicitly the velocity of propagation in the media since the travel path is known exactly. Thus, the derived velocities should closely represent rock velocities, unlike the 2-D case where the propagation geometry is not known.  相似文献   

Blue stragglers as stellar collision products: the angular momentum question     

Alison Sills  Tim Adams  Melvyn B. Davies 《Monthly notices of the Royal Astronomical Society》2005,358(3):716-725

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Revised radiocarbon ages on woolly rhinoceros (Coelodonta antiquitatis) from western central Scotland: significance for timing the extinction of woolly rhinoceros in Britain and the onset of the LGM in central Scotland     

Roger M. Jacobi  James Rose  Alison MacLeod  Thomas F.G. Higham 《Quaternary Science Reviews》2009,28(25-26):2551-2556

Woolly rhinoceros bones, from a number of sites in Britain, have been AMS radiocarbon dated following ultrafiltration pre-treatment. These determinations give a coherent set of ages between >50 and c. 35 cal ka BP. The youngest (35,864–34,765 cal BP) come from the area around Bishopbriggs in western central Scotland and are derived from glaciofluvial sand and gravel overlain by till, both deposited during the Last Glacial Maximum (LGM) glaciation. A previous radiocarbon date from the site suggested that woolly rhinoceros lived c. 27 ¹⁴C ka BP and the region was ice-free at the time. This date has had significant influence on the timing of extinction of woolly rhinoceros and the onset of glaciation over Britain during the LGM. The new dates revise this earlier determination and confirm that woolly rhinoceros became extinct in Britain after c. 35 cal ka BP, that central Scotland was ice-free at this time, and glaciation extended across this region sometime after 35 cal ka BP.  相似文献   

A comparison of hydrodynamic techniques for modelling collisions between main-sequence stars     

Hy Trac  Alison Sills  Ue-Li Pen 《Monthly notices of the Royal Astronomical Society》2007,377(3):997-1005

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Saturn in hot water: Viscous evolution of the Enceladus torus     

Alison J. Farmer 《Icarus》2009,202(1):280-286

The detection of outgassing water vapor from Enceladus is one of the great breakthroughs of the Cassini mission. The fate of this water once ionized has been widely studied; here we investigate the effects of purely neutral-neutral interactions within the Enceladus torus. We find that, thanks in part to the polar nature of the water molecule, a cold (∼180 K) neutral torus would undergo rapid viscous heating and spread to the extent of the observed hydroxyl cloud, before plasma effects become important. We investigate the physics behind the spreading of the torus, paying particular attention to the competition between heating and rotational line cooling. A steady-state torus model is constructed, and it is demonstrated that the torus will be observable in the millimeter band with the upcoming Herschel satellite. The relative strength of rotational lines could be used to distinguish between physical models for the neutral cloud.  相似文献   

The DEEP2 Galaxy Redshift Survey: the red sequence AGN fraction and its environment and redshift dependence     

Antonio D. Montero-Dorta  Darren J. Croton  Renbin Yan  Michael C. Cooper  Jeffery A. Newman  Antonis Georgakakis  Francisco Prada  Marc Davis  Kirpal Nandra  Alison Coil 《Monthly notices of the Royal Astronomical Society》2009,392(1):125-134

We measure the dependence of the active galactic nuclei (AGN) fraction on local environment at   z ∼ 1  , using spectroscopic data taken from the DEEP2 Galaxy Redshift Survey, and Chandra X-ray data from the All-Wavelength Extended Groth Strip International Survey (AEGIS). To provide a clean sample of AGN, we restrict our analysis to the red sequence population; this also reduces additional colour–environment correlations. We find evidence that high-redshift LINERs in DEEP2 tend to favour higher density environments relative to the red population from which they are drawn. In contrast, Seyferts and X-ray selected AGN at   z ∼ 1  show little (or no) environmental dependencies within the same underlying population. We compare these results with a sample of local AGN drawn from the Sloan Digital Sky Survey (SDSS). Contrary to the high-redshift behaviour, we find that both LINERs and Seyferts in the SDSS show a slowly declining red sequence AGN fraction towards high-density environments. Interestingly, at   z ∼ 1  red sequence Seyferts and LINERs are approximately equally abundant. By   z ∼ 0  , however, the red Seyfert population has declined relative to the LINER population by over a factor of ∼4.5. We speculate on possible interpretations of our results.  相似文献   

Making local futures tangible—Synthesizing, downscaling, and visualizing climate change scenarios for participatory capacity building   总被引：1，自引：0，他引：1  

Alison Shaw  Stephen Sheppard  Sarah Burch  David Flanders  Arnim Wiek  Jeff Carmichael  John Robinson  Stewart Cohen 《Global Environmental Change》2009,19(4):447-463

Local in its causes and global in its impacts, climate change still poses an unresolved challenge for scientists, politicians, entrepreneurs, and citizens. Climate change research is largely global in focus, aims at enhanced understanding, and is driven by experts, all of which seem to be insufficient to anchor climate change action in regional and local contexts. We present results from a participatory scenario study conducted in collaboration with the municipality of Delta in SW British Columbia, Canada. This study applies a participatory capacity building approach for climate change action at the local level where the sources of emissions and the mechanisms of adaptation reside and where climate change is meaningful to decision-makers and stakeholders alike. The multi-scale scenario approach consists of synthesizing global climate change scenarios, downscaling them to the regional and local level, and finally visualizing alternative climate scenarios out to 2100 in 3D views of familiar, local places. We critically discuss the scenarios produced and the strengths and weaknesses of the approach applied.  相似文献   

Wheat as food, wheat as industrial substance; comparative geographies of transformation and mobility   总被引：1，自引：0，他引：1  

Jennifer Atchison  Lesley Head  Alison Gates 《Geoforum》2010,41(2):236-246

Wheat is the world’s second largest crop, supplies 19% of human calories, and is the largest volume crop traded internationally. Its uniquely malleable physical properties make it a valued industrial substance, albeit often an invisible one, as well as a food. This combination of transformation, invisibility and mobility demands new ways of thinking about wheat geographies. In this paper we document and analyse several ‘moments’ in the life of Australian wheat; at the supermarket, in the lives of coeliac sufferers, in laboratories, industrial factories and on the farm. We illustrate diverse patterns of interaction with wheat. The major plane of differentiation is between wheat as food and wheat as industrial substance. The explicit connection of food to the human body tends to fix the identity of wheat, whether as healthy staple of the nation, or harmful poison to coeliacs who must negotiate its presence using the regulatory regime of food labelling. This is no small task given the ubiquity of wheat; our survey of 10,235 supermarket items found it in 29.5% of labelled food items. In contrast, when wheat is physically and chemically disassembled to become an industrial substance, its presence and identity become mutable, hidden and often invisible.  相似文献   

Kinetics of the Reactions of IO with HO2 and O(3P)     

Carlos E. Canosa-mas  Mark L. Flugge  Dina Shah  Alison Vipond  Richard P. Wayne 《Journal of Atmospheric Chemistry》1999,34(1):153-162

A discharge-flow tube coupled with resonance fluorescence and chemiluminescence detection has been used to investigate the reactions IO + HO₂ products (1) and IO + O(³P) I + O₂(2), at T = 296 ± 1 K and P = 1.7 - 2 Torr. The rate constants k_-1 and k₂ have been found to be (7.1 ± 1.6) × 10^-11 cm³ molecule^-1 s^-1 and (1.35 ± 0.15) × 10^-10 cm³ molecule^-1 s^-1, respectively.  相似文献