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41.
Thorsten Beitter Thomas Wagner Gregor Markl 《Contributions to Mineralogy and Petrology》2008,156(6):689-707
In this study, we have investigated the formation of quartz–kyanite veins of the Alpe Sponda, Central Alps, Switzerland. We
have integrated field observations, fluid inclusion and stable isotope data and combined this with numerical geochemical modeling
to constrain the chemical processes of aluminum transport and deposition. The estimated P–T conditions of the quartz–kyanite
veins, based on conventional geothermometry (garnet–biotite, white mica solvus and quartz–kyanite oxygen isotope thermometry)
and fluid inclusion data, are 550 ± 30°C at 5.0 ± 0.5 kbar. Geochemical modeling involved construction of aqueous species
predominance diagrams, calculation of kyanite and quartz solubility, and reaction–path simulations. The results of the modeling
demonstrate that (1) for the given chemical composition of the vein-forming fluids mixed Al–Si aqueous species are dominant
in transporting Al, and that (2) fluid cooling along a small temperature gradient coupled with a pH decrease is able to explain
the precipitation of the quartz–kyanite assemblages in the proportions that are observed in the Alpe Sponda veins. We conclude
that sufficient amounts of Al can be transported in typical medium- to high-grade regional metamorphic fluids and that immobile
behavior of Al is not very likely in advection–dominanted fluid–rock systems in the upper and middle crust. 相似文献
42.
Holmes AL Wise SS Goertz CE Dunn JL Gulland FM Gelatt T Beckmen KB Burek K Atkinson S Bozza M Taylor R Zheng T Zhang Y Aboueissa AM Wise JP 《Marine pollution bulletin》2008,56(8):1416-1421
The endangered Western population of the Steller sea lion declined for three decades for uncertain reasons. We present baseline data of metal concentrations in pups as a first step towards investigating the potential threat of developmental exposures to contaminants. Seven metals were investigated: arsenic, cadmium, silver, aluminum, mercury, lead and vanadium. Vanadium was detected in only a single blubber sample. Mercury appears to be the most toxicologically significant metal with concentrations in the liver well above the current action level for mercury in fish. The concentrations of aluminum, arsenic, silver, cadmium and lead were present in one-fourth to two-thirds of all samples and were at either comparable or below concentrations previously reported. Neither gender nor region had a significant effect on metal burdens. Future work should consider metal concentrations in juveniles and adults and toxicological studies need to be performed to begin to assess the toxicity of these metals. 相似文献
43.
Maurice Reille Valrie Andrieu Jacques-Louis de Beaulieu Pascal Guenet Claude Goeury 《Quaternary Science Reviews》1998,17(12):1107-1123
Pollen analysis was carried out on sediments older than the Würm pleniglacial (OIS 4), in two new sequences (H and I) derived from the centre of Lac du Bouchet, Massif Central. The inferred vegetation history enables, for the first time in France, five temperate episodes to be defined which pre-date the last interglacial. These temperate episodes alternate with episodes during which the changes in vegetation are indicative of glacial climates. Comparison of these climatic episodes with the oceanic isotope record shows that the pollen record of sequences H and I from Lac du Bouchet spans the time interval from OIS 9c (Ussel interstadial) to OIS 5e (Ribains/Eemian interglacial). In the organic sediments from the Amargiers interstadial (OIS 9a), a trachytic layer, Ar/Ar dated to ca 275 ka, enables a correlation to be established with the upper part of a sequence derived from the nearby Praclaux crater, the lower part of this sequence being of Holsteinian age (OIS 11c). The cross-dating of the pollen sequences from Lac du Bouchet (cores H, I and D) and from Praclaux provides a complete record from the Massif Central, southern France, of successive glacial and interglacial episodes that span the last ca. 400 ka, that is the interval from the Holsteinian to the Holocene. 相似文献
44.
《Comptes Rendus Geoscience》2014,346(11-12):317-325
Major features of the Earth's structure and dynamics originate in the contrast between the rigidity of SiO bonds and the softness of SiOSi linkages. Because this contrast results from orbital hybridization, a real understanding of bonding relies on ab initio quantum-mechanical principles. As investigated with first-principles interatomic potentials, the α–β transitions of SiO2 polymorphs illustrate how soft SiOSi linkages give rise to dynamical structures at rather low temperatures and yield the low melting temperatures of SiO2-rich minerals that are at the roots of SiO2 enrichment in magmatic differentiation. The increasing concentration of alkalis throughout this process is another aspect that must also be studied in terms of molecular orbitals in relation with the presence of aluminum in tetrahedral coordination. Finally, calculations of noble gas solubility show that some important features can be treated with “hybrid” calculations when, in addition to quantum-mechanical effects, the energy needed to create a cavity in the silicate melt is dealt with in a classical manner. 相似文献
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Aluminum oxide, which could be an alternative filter media for phosphorus uptake from aqueous solution, was selected as an adsorbent for the isotherm study of phosphorus uptake from aqueous solution. Batch method was adopted to investigate the adsorption behavior of phosphorus onto aluminum oxide. The Langmuir, Freundlich, and Redlich–Peterson isotherms were used to analyze the experimental data by both the linear and nonlinear regression methods. The adsorption experiment was conducted at various temperatures, to choose the appropriate method and obtain the creditable adsorption parameters for phosphorus uptake studies. The results indicated that the nonlinear regression method might be a better way to compare the best‐fitting isotherm and obtain the parameters for the adsorption of phosphorus onto aluminum oxide. Both the Redlich–Peterson and the Freundlich isotherms have high coefficients of determination for the adsorption of phosphorus onto aluminum oxide at various temperatures. In addition, a new relationship between the Redlich–Peterson and the Freundlich isotherm parameters was presented. 相似文献