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41.
The entropy budget is calculated of the coupled atmosphere–ocean general circulation model HadCM3. Estimates of the different entropy sources and sinks of the climate system are obtained directly from the diabatic heating terms, and an approximate estimate of the planetary entropy production is also provided. The rate of material entropy production of the climate system is found to be ~50 mW m?2 K?1, a value intermediate in the range 30–70 mW m?2 K?1 previously reported from different models. The largest part of this is due to sensible and latent heat transport (~38 mW m?2 K?1). Another 13 mW m?2 K?1 is due to dissipation of kinetic energy in the atmosphere by friction and Reynolds stresses. Numerical entropy production in the atmosphere dynamical core is found to be about 0.7 mW m?2 K?1. The material entropy production within the ocean due to turbulent mixing is ~1 mW m?2 K?1, a very small contribution to the material entropy production of the climate system. The rate of change of entropy of the model climate system is about 1 mW m?2 K?1 or less, which is comparable with the typical size of the fluctuations of the entropy sources due to interannual variability, and a more accurate closure of the budget than achieved by previous analyses. Results are similar for FAMOUS, which has a lower spatial resolution but similar formulation to HadCM3, while more substantial differences are found with respect to other models, suggesting that the formulation of the model has an important influence on the climate entropy budget. Since this is the first diagnosis of the entropy budget in a climate model of the type and complexity used for projection of twenty-first century climate change, it would be valuable if similar analyses were carried out for other such models.  相似文献   
42.
This paper presents the results of a multiproxy investigation including volume magnetic susceptibility (κ), mineral and pollen analyses of Late Glacial sediments from Lake Lautrey (Jura, France). Small‐scale lithological variations have been identified with high stratigraphic resolution in order to establish lithostratigraphic correlations between cores. κ measurements, combined with mineralogical analyses, provide information on past sedimentary processes. This combined approach reflects major changes in terrestrial habitats and soil processes which may relate to the climatic events characterising the Late Glacial climatic warming and cooling phases. During warm intervals, the record indicates increased lake productivity via carbonate precipitation and decreased input of detrital material. In contrast, cooler intervals show reduced lake productivity, catchment area instability and increased detrital inputs. Several short interruptions in reforestation and in soil stabilisation can be identified and linked with abrupt colder events occurring through the Bølling. A general trend of warming is recorded from the coldest part of the Younger Dryas. Three tephra layers were also detected. The mineral composition analyses show that the upper tephra layer corresponds to the Laacher See eruption (Eifel, Germany) while the lower ones may relate to the volcanic activity of the Chaîne des Puys (Massif Central, France) around 13 000 cal. yr BP. These two events, recognised for the first time outside the Massif Central region, may provide additional chronostratigraphic markers for the Late Glacial sedimentary records of the Jura mountains and northern Alps. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
43.
Abstract— We have investigated the native amino acid composition of two analogs of Martian soil, JSC Mars‐1 and Salten Skov. A Mars simulation chamber has been built and used to expose samples of these analogs to temperature and lighting conditions similar to those found at low latitudes on the Martian surface. The effects of the simulated conditions have been examined using high‐performance liquid chromatography (HPLC). Exposure to energetic ultraviolet (UV) light in vacuum appears to cause a modest increase in the concentration of certain amino acids within the materials, which is interpreted as resulting from the degradation of microorganisms. The influence of low temperatures shows that the accretion of condensed water on the soils leads to the destruction of amino acids, supporting the idea that reactive chemical processes involving H2O are at work within the Martian soil. We discuss the influence of UV radiation, low temperatures, and gaseous CO2 on the intrinsic amino acid composition of Martian soil analogs and describe, with the help of a simple model, how these studies fit within the framework of life detection on Mars and the practical tasks of choosing and using Martian regolith analogs in planetary research.  相似文献   
44.
Gem-quality alexandrite, hiddenite and kunzite, elbaite and topaz minerals were characterized through a multi-methodological investigation based on EMPA-WDS, LA-ICP-MS, and laser-induced breakdown spectroscopy (LIBS). With respect to the others, the latter technique enables a simultaneous multi-elemental composition without any sample preparation and the detection of light elements, such as Li, Be and B. The criteria for the choice of minerals were: (a) the presence of chromophore elements in minor contents and/or as traces; (b) the presence of light lithophile elements (Li, Be and B); (c) different crystal chemistry complexity. The results show that LIBS can be employed in mineralogical studies for the identification and characterization of minerals, and as a fast screening method to determine the chemical composition, including the chromophore and light lithophile elements.  相似文献   
45.
Most current coral reef management is supported by mapping and monitoring limited in record length and spatial extent. These deficiencies were addressed in a multidisciplinary study of cyclone impacts on Aboré Reef, New-Caledonia. Local knowledge, high thematic-resolution maps, and time-series satellite imagery complemented classical in situ monitoring methods. Field survey stations were selected from examination of pre- and post-cyclone images and their post-cyclone coral communities documented in terms of substrata, coral morphologies, live coral cover, and taxonomy. Time-series maps of hierarchically defined coral communities created at spatial scales documenting the variability among communities (29-45 classes) and suggesting the processes that affected them. The increased spatial coverage and repeatability of this approach significantly improved the recognition and interpretation of coral communities’ spatio-temporal variability. It identified precise locations of impacted areas and those exhibiting coral recovery and resilience. The approach provides a comprehensive suite of information on which to base reef-scale conservation actions.  相似文献   
46.
The process of organomineralization is increasingly well understood with respect to modern carbonate sediments accumulating adjacent to tropical reef atolls and reef caves. Mineralization related to non-living organic substrates results in autochthonous micrite production (‘automicrites’). ‘Automicrites’ are the main constructive element of Lower Cretaceous (Albian) carbonate mud mounds in northern Spain. These slope mud mounds occur within transgressive and early highstand system tracts encompassing several macrobenthic ecological zones. They are clearly separated from the biocalcifying carbonate factory (Urgonian carbonate platforms), in both space and time. Within these build-ups, most ‘automicrites’ were initially indurated and accreted to form a medium-relief growth framework. ‘Automicrites’ have a uniform, presumably high-Mg-calcite precursor mineralogy. They show an inorganic stable-isotope signature (?13C around +3·3‰) within the range of early marine cements, and skeletal compounds lacking major vital effects. Epifluorescence microscopy shows that they have facies-specific fluorescence, which is similar to skeletal compounds of Acanthochaetetes, but clearly different from allomicritic sediment and cements, which are mostly non-fluorescent. The EDTA-soluble intracrystalline organic fraction (SIOF) of Albian automicrites shows an amino acid spectrum that is similar to shallow subsurface samples from their modern counterparts. Gel electrophoresis of the SIOF demonstrates an exclusively acidic character, and a mean molecular size range between 20 and 30 kDa. Experiments in vitro (inhibition tests) indicate that the SIOF has a significant Ca2+-binding capacity. Fluorescence and chemical characteristics of SIOF point to a main substance class, such as humic and fulvic acids, compounds that form from pristine organic matter during early diagenesis. Biomarker analyses provide evidence for the crucial role of biodegradation by heterotrophic microorganisms, but no biomarker for cyanobacteria has been found. Primary sources of organic material should have been manifold, including major contributions by metazoans such as sponges. It is concluded that many carbonate mud mounds are essentially organomineralic in origin and that the resulting fabric of polygenetic muds (‘polymuds’) may represent ancestral metazoan reef ecosystems, which possibly originated during the Neoproterozoic.  相似文献   
47.
River confluences are characterized by a complex mixing zone with three-dimensional (3D) turbulent structures which have been described as both streamwise-oriented structures and Kelvin–Helmholtz (KH) vertical-oriented structures. The latter are visible where there is a turbidity difference between the two tributaries, whereas the former are usually derived from mean velocity measurements or numerical simulations. Few field studies recorded turbulent velocity fluctuations at high frequency to investigate these structures, particularly at medium-sized confluences where logistical constraints make it difficult to use devices such as acoustic doppler velocimeter (ADV). This study uses the ice cover present at the confluence of the Mitis and Neigette Rivers in Quebec (Canada) to obtain long-duration, fixed measurements along the mixing zone. The confluence is also characterized by a marked turbidity difference which allows to investigate the mixing zone dynamics from drone imagery during ice-free conditions. The aim of the study is to characterize and compare the flow structure in the mixing zone at a medium-sized (~40 m) river confluence with and without an ice cover. Detailed 3D turbulent velocity measurements were taken under the ice along the mixing plane with an ADV through eight holes at around 20 positions on the vertical. For ice-free conditions, drone imagery results indicate that large (KH) coherent structures are present, occupying up to 50% of the width of the parent channel. During winter, the ice cover affects velocity profiles by moving the highest velocities towards the centre of the profiles. Large turbulent structures are visible in both the streamwise and lateral velocity components. The strong correlation between these velocity components indicates that KH vortices are the dominating coherent structures in the mixing zone. A spatio-temporal conceptual model is presented to illustrate the main differences on the 3D flow structure at the river confluence with and without the ice cover. © 2019 John Wiley & Sons, Ltd.  相似文献   
48.
We have conducted four numerical experiments with an atmospheric general circulation model (AGCM) to investigate the sensitivity of Asian and African monsoons to small changes (–5 to +12%), with respect to present-day, in incoming solar radiation at the top of the atmosphere. We show that, during the mid-Holocene (6 kBP where kBP means thousands of years before present-day) and the last interglacial (126 kBP), the Northern Hemisphere seasonal contrast was increased, with warmer summers and colder winters. At the time of glacial inception (115 kBP) however, summers were cooler and winters milder. As a consequence, Asia and tropical North Africa experienced stronger (weaker) summer monsoons 6 and 126 kBP (115 kBP), in agreement with previous numerical studies. This present study shows that summer warming/cooling of Eurasia and North Africa induced a shift of the main low-level convergence cell along a northwest/southeast transect. When land was warmer (during the summer months 6 and 126 kBP), the monsoon winds converged further inland bringing more moisture into northern India, western China and the southern Sahara. The southern tips of India, Indochina and southeastern China, as well as equatorial North Africa became drier. When land was cooler (during the summer 115 kBP), the main convergence zone was located over the west Pacific and the wet (dry) areas were those that were dry (wet) 6 and 126 kBP. The location and intensity of the simulated precipitation maxima were therefore very sensitive to changes in insolation. However the total amount of monsoon rain in Asia as well as in Africa remained remarkably stable through the time periods studied. These simulated migrations of convective activities were accompanied by changes in the nature of precipitation events: increased monsoon rains in these experiments were always associated with more high precipitation events (> 5 mm day –1), and fewer light showers (1 mm day). Rainy days with rates between 1 and 5 mm day–1 were almost unchanged.  相似文献   
49.
50.
The aim of this study was to distinguish between sources of the complex variety of Marennes-Oléron Bay suspended particulate organic matter (SPOM) contributing to the tropho-dynamics of the Marennes-Oléron oyster farming bay. Basic biomarkers (Chl a, C/N and POC/Chl a ratios), carbon and nitrogen stable isotopes from SPOM were analyzed and the microalgae community was characterized. The sampling strategy was bimonthly from March 2002 to December 2003; samples were taken from an intertidal mudflat. Four main sources contributed to the SPOM pool: terrigenous input from rivers, neritic phytoplankton, resuspended microphytobenthos and periodic inputs from intertidal Zostera noltii meadows. Seasonal fluctuations were observed in both years of the study period: (1) SPOM collected in the spring of 2002 (δ13C = −25‰ to −23‰) was mainly composed of fresh estuarine inputs; (2) SPOM from the summer and fall of 2002 and 2003 was predominantly neritic phytoplankton (δ13C = − 22‰ to −19‰); (3) SPOM from the winter of 2002, spring of 2003 and winter of 2003 (δ13C = −21 to −23‰) was composed of a mixture of decayed terrigenous river inputs and pelagic phytoplankton, which was predominantly resuspended microphytobenthos. In the summer of 2003—the warmest summer on record in southern France and Europe—SPOM was particularly enriched for 13C, with δ13C values ranging from −14‰ to −12‰. Pulses in δ13C values, indicative of 13C-enriched decaying materials, extended into the fall. These were attributed to benthic intertidal inputs, including both resuspended microphytobenthos and Z. noltii detritus. Changes in SPOM sources in Marennes-Oléron Bay may lead to differences in the quality of the trophic environment available for reared oysters.  相似文献   
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