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41.
The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.  相似文献   
42.
The development of groundwater favourability map is an effective tool for the sustainability management of groundwater resources in typical agricultural regions, such as southern Perak Province, Malaysia. Assessing the potentiality and pollution vulnerability of groundwater is a fundamental phase of favourability mapping. A geographic information system (GIS)-based Boolean operator of a spatial analyst module was applied to combine a groundwater potentiality map (GPM) model and a groundwater vulnerability to pollution index (GVPI) map, thereby establishing the favourable zones for drinking water exploration in the investigated area. The area GPM model was evaluated by applying a GIS-based Dempster–Shafer–evidential belief function model. In the evaluation, six geoelectrically determined groundwater potential conditioning factors (i.e. overburden resistivity, overburden thickness, aquifer resistivity, aquifer thickness, aquifer transmissivity and hydraulic conductivity) were synthesized by employing the probability-based algorithms of the model. The generated thematic maps of the seven hydrogeological parameters of the DRASTIC model were considered as pollution potential conditioning factors and were analysed with the developed ordered weighted average–DRASTIC index model algorithms to construct the GVPI map. Approximately 88.8 and 85.71% prediction accuracies for the Groundwater Potentiality and GVPI maps were established using the reacting operating characteristic curve method and water quality status–vulnerability zone relationship scheme, respectively. Finally, the area groundwater favourability map (GFM) model was produced by applying a GIS-based Boolean operator on the Groundwater Potentiality and GVPI maps. The GFM model reveals three distinct zones: ‘not suitable’, ‘less suitable’ and ‘very suitable’ zones. The area analysis of the GFM model indicates that more than 50% of the study area is covered by the ‘very suitable’ zones. Results produce a suitability map that can be used by local authorities for the exploitation and management of drinking water in the area. The study findings can also be applied as a tool to help increase public awareness of groundwater issues in developing countries.  相似文献   
43.
Although antimony (Sb) and arsenic (As) exhibit similar geochemical behavior and toxicity in the environment, growing evidence suggests that their water–rock interaction behavior in contaminated rivers is quite different. Twenty-nine river water samples were collected between September and November 2018 from contaminated rivers around an antimony mine in Hunan Province, China. The concentrations of As and Sb were inversely proportional to the water flow distance. The rates and magnitudes of Sb decrease were more prominent than those of As. Silicate mineral dissolution from rocks such as silicified limestone increased the As and Sb concentration of in-mine-district (IMD) water. Dissolution of carbonate minerals, ion exchange, and competitive adsorption were the major water–rock interactions, resulting in rapidly decreasing As and Sb concentration in IMD direct impacted water and IMD indirect impacted water. The behaviors of As and Sb during water–rock interaction were dissimilar for areas dominated by carbonate and silicate minerals.  相似文献   
44.
Here we reconstruct the last advance to maximum limits and retreat of the Irish Sea Glacier (ISG), the only land-terminating ice lobe of the western British Irish Ice Sheet. A series of reverse bedrock slopes rendered proglacial lakes endemic, forming time-transgressive moraine- and bedrock-dammed basins that evolved with ice marginal retreat. Combining, for the first time on glacial sediments, optically stimulated luminescence (OSL) bleaching profiles for cobbles with single grain and small aliquot OSL measurements on sands, has produced a coherent chronology from these heterogeneously bleached samples. This chronology constrains what is globally an early build-up of ice during late Marine Isotope Stage 3 and Greenland Stadial (GS) 5, with ice margins reaching south Lancashire by 30 ± 1.2 ka, followed by a 120-km advance at 28.3 ± 1.4 ka reaching its 26.5 ± 1.1 ka maximum extent during GS-3. Early retreat during GS-3 reflects piracy of ice sources shared with the Irish-Sea Ice Stream (ISIS), starving the ISG. With ISG retreat, an opportunistic readvance of Welsh ice during GS-2 rode over the ISG moraines occupying the space vacated, with ice margins oscillating within a substantial glacial over-deepening. Our geomorphological chronosequence shows a glacial system forced by climate but mediated by piracy of ice sources shared with the ISIS, changing flow regimes and fronting environments.  相似文献   
45.
安徽桂林郑钼钨矿床位于江南钨矿带北部,是目前区内唯一钼储量达到大型的钼钨矿床。本文在对该矿床地质特征和已有成果总结基础上,详细观察了各代表性矿化蚀变样品的岩相学特征,提出该矿床具镁质矽卡岩矿床特征,是桂林郑花岗斑岩熔体与奥陶系白云质灰岩地层交代的产物。矿石类型可分为靠近岩体(100m)浸染状矿石和远离岩体( 100m)的条带状矿石,分别赋存在接触交代矽卡岩和层控矽卡岩中。桂林郑矿床的矿石矿物为富钼白钨矿(钼钙矿-白钨矿系列),可分为三个世代,分别形成于无水矽卡岩阶段(Sch-Ⅰ)和含水矽卡岩-氧化物阶段(Sch-Ⅱ和Sch-Ⅲ),辉钼矿仅在浸染状矿石富钼白钨矿(Sch-Ⅲ)边部少量发育。不同矿石类型、不同世代富钼白钨矿的电子探针成分分析显示,富钼白钨矿的钼含量(MoO_3%)在5.75%~71.02%之间,均值为46.00%(n=224),总体具有超常富钼的特点;从无水矽卡岩阶段到含水矽卡岩-氧化物阶段(早→晚)、从浅部的条带状矿石到深部的浸染状矿石(浅→深),富钼白钨矿MoO_3含量有降低趋势。桂林郑钼钨矿床是首个以富钼白钨矿为主要矿石矿物的钼-多金属矿床,这一特殊钼钨矿床的发现深化了矽卡岩钼钨矿床的成因认识,同时对江南钨矿带内区域成矿规律与找矿勘探工作的推进提供了依据。  相似文献   
46.
Radiogenic isotopic dating and Lu–Hf isotopic composition using laser ablation-inductively coupled plasma-mass spectrometry(LA-ICP-MS)of the Wude basalt in Yunnan province from the Emeishan large igneous province(ELIP)yielded timing of formation and post-eruption tectonothermal event.Holistic lithogeochemistry and elements mapping of basaltic rocks were further reevaluated to provide insights into crustal contamination and formation of the ELIP.A zircon U–Pb age of 251.3±2.0 Ma of the Wude basalt recorded the youngest volcanic eruption event and was consistent with the age span of 251-263 Ma for the emplacement of the ELIP.Such zircons hadεHf(t)values ranging from7.3 to+2.2,identical to those of magmatic zircons from the intrusive rocks of the ELIP,suggesting that crust-mantle interaction occurred during magmatic emplacement,or crust-mantle mixing existed in the deep source region prior to deep melting.The apatite U–Pb age at 53.6±3.4 Ma recorded an early Eocene magmatic superimposition of a regional tectonothermal event,corresponding to the Indian–Eurasian plate collision.Negative Nb,Ta,Ti and P anomalies of the Emeishan basalt may reflect crustal contamination.The uneven Nb/La and Th/Ta values distribution throughout the ELIP supported a mantle plume model origin.Therefore,the ELIP was formed as a result of a mantle plume which was later superimposed by a regional tectonothermal event attributed to the Indian–Eurasian plate collision during early Eocene.  相似文献   
47.
The early Paleozoic tectonic evolution of the Xing'an-Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing'an Block,i.e.,the Xinlin-Xiguitu Ocean and the Nenjiang Ocean.However,the early development of the Nenjiang Ocean remains unclear.Here,we present zircon U-Pb geochronology and whole-rock elemental and Sr-Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area.LA-ICP-MS zircon U-Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443-436 Ma and 452-451 Ma,respectively.The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs,and depleted in HFSEs,with relatively low U/Th ratios of 0.18-0.36 andεNd(t)values of-1.6 to+0.5.These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts,consistent with a back-arc basin setting.By contrast,the andesitic tuffs are characterized by high MgO(>5 wt.%),Cr(138-200 ppm),and Ni(65-110 ppm)contents,and can be termed as high-Mg andesites.Their low Sr/Y ratios of 15.98-17.15 and U/Th values of 0.24-0.25 and moderate(La/Sm)_n values of 3.07-3.26 are similar to those from the Setouchi Volcanic Belt(SW Japan),and are thought to be derived from partial melting of subducted sediments,and subsequent melt-mantle interaction.The Duobaoshan basalts have high Nb(8.44-10.30 ppm)and TiO2 contents(1.17-1.60 wt.%),typical of Nb-enriched basalts.They are slightly younger than regional adakitic rocks and have positiveεNd(t)values of+5.2 to+5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts.Synthesized with coeval arc-related igneous rocks from the southeastern Xing'an Block,we propose that the Duobaoshan high-Mg andesitic tuffs and Nbenriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi-Duobaoshan arc belt,and they were formed by the northwestern subduction of the Nenjiang Ocean.Such a subduction beneath the integrated Xing'an-Erguna Block also gave rise to the East Ujimqin-Xinglong igneous belt in a continental back-arc basin setting.Our new data support an early Paleozoic arc-back-arc model in the northern Great Xing'an Range.  相似文献   
48.
The granite‐greenstone terranes of the Eastern Goldfields Province, Yilgarn Craton, Western Australia, are a major Australian and world gold and nickel source. The Kalgoorlie region, in particular, hosts several world‐class gold deposits. To attempt to understand why these deposits occur where they do, it is important to understand the crustal architecture in the region and how the major mineral systems operate in this architecture. One way to understand these relationships is to develop a detailed 3–D geological model for the region. The best method to map the 3–D geometry of major geological structures is by acquisition and interpretation of seismic‐reflection profiles. To contribute to this aim, a grid of deep seismic‐reflection traverses was acquired in 1999 to examine the 3–D geometry of the region in an area including the Kalgoorlie mineral region and mineral fields to the north and west. This grid was tied to the 1991 regional deep seismic traverse and 1997 high‐resolution seismic profiles in the same region. The grid covers an area measuring approximately 50 km wide by 50 km long and extended to a depth of approximately 50 km (below the base of the crust in this region). The resulting 3–D geological model was further constrained by both surface geological data and geophysical interpretations, with the seismic interpretations themselves also constrained by gravity and magnetic modelling. The 3–D model was used to investigate the geometric relationships between the major faults and shear zones in the area, the relationship between the granite‐greenstone succession and the basement, and the spatial relationships between the greenstones and the granites. Interpretation of the grid of seismic lines and construction of the 3–D geological model confirmed the existence of the detachment surface and led to the recognition that the granite‐greenstone contact usually occurs at a much shallower level than the detachment. Also, west‐dipping faults in the vicinity of the Golden Mile, including the Abattoir Shear through to Boulder‐Lefroy Fault, appear to be more important than previously thought in controlling the structure of that area. An antiformal thrust stack occurs beneath a triangle zone centred on the Golden Mile. The Black Flag Group was deposited in a probable extensional setting, and late extension was also probably more important than previously thought. The granite‐gneiss domes were uplifted by the formation of antiformal thrust stacks at depth beneath them.  相似文献   
49.
Abstract

The potential influence of a developing La Niña on Arctic sea-ice annual variability is investigated using both observational data and an atmospheric general circulation model. It is found that during the developing phase of an eastern Pacific (EP) La Niña event in June, July, and August (JJA) and September, October, and November (SON), the sea-ice concentration (SIC) over the Barents–Kara Seas declines more than 15%. The local atmospheric circulation pattern associated with the EP La Niña is characterized as a weak decrease in geopotential height over the Barents–Kara Seas, combined with an anticyclone in the North Atlantic. The corresponding southerly winds push warm waters northward into the key sea-ice reduction region and directly accelerate sea-ice melt. Meanwhile, the abundant moisture contained in the lower troposphere is transported into the Arctic region by winds resulting from the local barotropic structure. The humid atmosphere contributes to both net shortwave and longwave radiation and thus indirectly accelerates the decline in sea ice. Simulations by the European Centre Hamburg Model, version 5.4, are forced by observed sea surface temperature anomalies associated with EP La Niña events. The results of the simulations capture the North Atlantic anticyclone and reproduce the moisture transport, which supports the premise that an EP La Niña plays a crucial role in sea-ice reduction over the Barents–Kara sector from the perspective of atmospheric circulation and net surface heat flux.  相似文献   
50.
Fifty‐five new SHRIMP U–Pb zircon ages from samples of northern Australian ‘basement’ and its overlying Proterozoic successions are used to refine and, in places, significantly change previous lithostratigraphic correlations. In conjunction with sequence‐stratigraphic studies, the 1800–1580 Ma rock record between Mt Isa and the Roper River is now classified into three superbasin phases—the Leichhardt, Calvert and Isa. These three major depositional episodes are separated by ~20 million years gaps. The Isa Superbasin can be further subdivided into seven supersequences each 10–15 million years in duration. Gaps in the geological record between these supersequences are variable; they approach several million years in basin‐margin positions, but are much smaller in the depocentres. Arguments based on field setting, petrography, zircon morphology, and U–Pb systematics are used to interpret these U–Pb zircon ages and in most cases to demonstrate that the ages obtained are depositional. In some instances, zircon crystals are reworked and give maximum depositional ages. These give useful provenance information as they fingerprint the source(s) of basin fill. Six new ‘Barramundi’ basement ages (around 1850 Ma) were obtained from crystalline units in the Murphy Inlier (Nicholson Granite and Cliffdale Volcanics), the Urapunga Tectonic Ridge (‘Mt Reid Volcanics’ and ‘Urapunga Granite’), and the central McArthur Basin (Scrutton Volcanics). New ages were also obtained from units assigned to the Calvert Superbasin (ca 1740–1690 Ma). SHRIMP results show that the Wollogorang Formation is not one continuous unit, but two different sequences, one deposited around 1730 Ma and a younger unit deposited around 1722 Ma. Further documentation is given of a regional 1725 Ma felsic event adjacent to the Murphy Inlier (Peters Creek Volcanics and Packsaddle Microgranite) and in the Carrara Range. A younger ca 1710 Ma felsic event is indicated in the southwestern McArthur Basin (Tanumbirini Rhyolite and overlying Nyanantu Formation). Four of the seven supersequences in the Isa Superbasin (ca 1670–1580 Ma) are reasonably well‐constrained by the new SHRIMP results: the Gun Supersequence (ca 1670–1655 Ma) by Paradise Creek Formation, Moondarra Siltstone, Breakaway Shale and Urquhart Shale ages grouped between 1668 and 1652 Ma; the Loretta Supersequence (ca 1655–1645 Ma) by results from the Lady Loretta Formation, Walford Dolomite, the upper part of the Mallapunyah Formation and the Tatoola Sandstone between ca 1653 and 1647 Ma; the River Supersequence (ca 1645–1630 Ma) by ages from the Teena Dolomite, Mt Les and Riversleigh Siltstones, and Barney Creek, Lynott, St Vidgeon and Nagi Formations clustering around 1640 Ma; and the Term Supersequence (ca 1630–1615 Ma) by ages from the Stretton Sandstone, lower Doomadgee Formation and lower part of the Lawn Hill Formation, mostly around 1630–1620 Ma. The next two younger supersequences are less well‐constrained geochronologically, but comprise the Lawn Supersequence (ca 1615–1600 Ma) with ages from the lower Balbirini Dolomite, and lower Doomadgee, Amos and middle Lawn Hill Formations, clustered around 1615–1610 Ma; and the Wide Supersequence (ca 1600–1585 Ma) with only two ages around 1590 Ma, one from the upper Balbirini Dolomite and the other from the upper Lawn Hill Formation. The Doom Supersequence (<1585 Ma) at the top of the Isa Superbasin is essentially unconstrained. The integration of high‐precision SHRIMP dating from continuously analysed stratigraphic sections, within a sequence stratigraphic context, provides an enhanced chronostratigraphic framework leading to more reliable interpretations of basin architecture and evolution.  相似文献   
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