(40)~Ar/(39)~Ar chronology and geochemistry of high-K volcanic rocks in the Mangkang basin, Tibet   总被引：9，自引：0，他引：9  

ZHANG Huihua  HE Huaiyu  WANG Jianghai & XIE Guanghong Guangzhou Institute of Geochemistry  Chinese Academy of Sciences  Guangzhou  China  Institute of Geology  Geophysics  Chinese Academy of Sciences  Beijing  China  College of Life Sciences  Sun Yat-Sen University  Guangzhou  China 《中国科学D辑(英文版)》2005,48(1)

Our two newly obtained high-quality 40Ar/39Ar ages suggest that the high-K volcanic rocks of the Lawuxiang Formation in the Mangkang basin, Tibet were formed at 33.5±0.2 Ma. The tracing of elemental and Pb-Sr-Nd isotopic geochemistry indicates that they were derived from an EM2 enriched mantle in continental subduction caused by transpression. Their evidently negative anomalies in HFSEs such as Nb and Ta make clear that there is an input of continental material into the mantle source. The high-K rocks at 33.5±0.2 Ma in the Mangkang basin may temporally, spatially and compositionally compare with the early one of two-pulse high-K rocks in eastern Tibet distinguished by Wang J. H. et al., implying that they were formed in the same tectonic setting.  相似文献   

Microorganisms in Lianxian lateritic gold deposit in Guangdong and their effects on leaching of heavy metals     

陈炳辉刘琥琥  毋福海徐文烈 《中国地球化学学报》2005,24(2):144-148

Microorganisms in the lateritic profiles of the Lianxian gold deposit in Guangdong were cultured, isolated and identified. The microorganisms include bacteria such as Bacillus, Enterobacter, Pseudomonas, Lactobacillus, Actinetobacter, Aeromona, Listeria, Agrobacteriura, Cotyttebacteriurn, and Moraxella, fungi such as Penicillium, Alter naria, Cladosporium, Saccharcornyces, Mucor, and the chemoautotrophic Thiobacillu.~. It is shown in a leaching experiment that the microorganisms can accelerate the leaching of Cu, Cd, Zn, and that the G- bacteria are most efficient for leaching Cu, Zn and the G^ bacteria are better for leaching Cd.  相似文献   

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China   总被引：2，自引：0，他引：2  

WANG Min 《中国地球化学学报》2005,24(4):297-305

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.  相似文献   

Net alkalinity and net acidity 2: Practical considerations     

《Applied Geochemistry》2005,20(10):1941-1964

The pH, alkalinity, and acidity of mine drainage and associated waters can be misinterpreted because of the chemical instability of samples and possible misunderstandings of standard analytical method results. Synthetic and field samples of mine drainage having various initial pH values and concentrations of dissolved metals and alkalinity were titrated by several methods, and the results were compared to alkalinity and acidity calculated based on dissolved solutes. The pH, alkalinity, and acidity were compared between fresh, unoxidized and aged, oxidized samples.Data for Pennsylvania coal mine drainage indicates that the pH of fresh samples was predominantly acidic (pH 2.5–4) or near neutral (pH 6–7); ≈ 25% of the samples had pH values between 5 and 6. Following oxidation, no samples had pH values between 5 and 6.The Standard Method Alkalinity titration is constrained to yield values >0. Most calculated and measured alkalinities for samples with positive alkalinities were in close agreement. However, for low-pH samples, the calculated alkalinity can be negative due to negative contributions by dissolved metals that may oxidize and hydrolyze.The Standard Method hot peroxide treatment titration for acidity determination (Hot Acidity) accurately indicates the potential for pH to decrease to acidic values after complete degassing of CO₂ and oxidation of Fe and Mn, and it indicates either the excess alkalinity or that required for neutralization of the sample. The Hot Acidity directly measures net acidity (= −net alkalinity). Samples that had near-neutral pH after oxidation had negative Hot Acidity; samples that had pH < 6.3 after oxidation had positive Hot Acidity. Samples with similar pH values before oxidation had dissimilar Hot Acidities due to variations in their alkalinities and dissolved Fe, Mn, and Al concentrations. Hot Acidity was approximately equal to net acidity calculated based on initial pH and dissolved concentrations of Fe, Mn, and Al minus the initial alkalinity. Acidity calculated from the pH and dissolved metals concentrations, assuming equivalents of 2 per mole of Fe and Mn and 3 per mole of Al, was equivalent to that calculated based on complete aqueous speciation of Fe^II/Fe^III. Despite changes in the pH, alkalinity, and metals concentrations, the Hot Acidities were comparable for fresh and most aged samples.A meaningful “net” acidity can be determined from a measured Hot Acidity or by calculation from the pH, alkalinity, and dissolved metals concentrations. The use of net alkalinity = (Alkalinity_measured − Hot Acidity_measured) to design mine drainage treatment can lead to systems with insufficient Alkalinity to neutralize metal and H⁺ acidity and is not recommended. The use of net alkalinity = −Hot Acidity titration is recommended for the planning of mine drainage treatment. The use of net alkalinity = (Alkalinity_measured − Acidity_calculated) is recommended with some cautions.  相似文献   

基于可持续发展的广东省城市供水价格改革探讨     

刘祖发  江涛  陈晓宏  王高旭  杨杨  叶锦昭 《热带地理》2005,25(4):336-340

针对目前城市供水价格计算与计量方式不合理和突出的水资源供需矛盾,提出了按全成本水价模式测算广东省城市供水价格,并采用阶梯水价、两部制水价和季节水价计量方式逐步达到全成本水价的措施与实施步骤,确保水资源的持续利用支撑广东省经济社会的可持续发展.  相似文献   

1978年以来广州市居民职住地选择行为时空特征与影响因素的代际差异   总被引：3，自引：0，他引：3  

林荣平  周素红  闫小培 《地理学报》2019,74(4):753-769

1978年以来,中国体制改革重塑了个体日常时空行为及其在生命过程中的活动轨迹,但鲜有文献解析长时间序列下不同代际群体对职住政策调整做出的响应及其代际差异。基于时间地理学视角与代际差异理论,将广州市微观个体职住地变动历程与代际问题相结合,利用问卷调查分析1988年和1998年居民职住制度改革前后,不同代际居民职住地变迁行为时空特征及其影响因素的结构性差异。结果发现：① 在居住地和就业地变迁方向方面,各代际居民住房迁出地主要集中于老城区,就业地变迁围绕两个城市中心,形成由老城核心地域向内城、近郊扩散的变迁过程。② 职住地距离变化方面,居民平均职住距离由1988年之前的4.91 km增至1998年之后的6.46 km,20世纪90年代出生居民（简称90后,下同）的职住分离度大于其他群体。③ 在职住地变迁率方面,住房商品化和就业社会化极大地增加了居民职住地选择自由度,60后和70后在1998年之后的迁居率分别为113.16%与112.33%,就业地变迁率分别为148.68%与197.26%,二者都远高于住房改革前的比例。④ 驻留时长方面,职住自由化使得驻留时长明显缩短。60后变化最为明显,该群体在一个居住地的居住时长由1988年以前的14.43年缩至1998年以后的5.43年,就业地驻留时长由12.43年降至3.95年;80后与90后在1998年以后的职住地驻留时长明显较短,70后相对较长。⑤ 能力、组合及权威制约中的房价、婚姻状况、学历、福利分房及下岗等因素对职住地变迁表现出明显代际差异,因子女上学及同事关系等组合制约对就业地变迁无显著群体差别。  相似文献   

长江感潮河段潮波传播变化特征及影响因素分析     

黄竞争  张先毅  吴峥  刘锋  蔡华阳  杨清书 《海洋学报》2020,42(3):25-35

径潮相互作用是感潮河段水动力变化的典型特征，受其影响潮波传播具有明显的洪枯季及沿程变化。本文基于长江感潮河段天生港、江阴、镇江、南京、马鞍山及芜湖6个潮位站2002?2014年连续高低潮位资料及大通站月均流量数据，统计分析长江感潮河段潮波振幅衰减率、潮波传播速度及余水位坡度等传播特征值的洪枯季及沿程变化特征，并探讨这些潮波传播特征的变化规律及其主要影响因素。结果表明，潮波传播特征的洪枯季差异自上游至下游逐渐减小，其分界点位于天生港与江阴之间（其中，天生港和江阴站的多年平均洪枯季潮差差值约为0.01 m和?0.04 m）；径流动力对潮波衰减的影响主要位于江阴以上河段，江阴以下河段主要受潮汐动力控制；径流驱动下余水位坡度引起的余水位及水深增加，导致潮波传播的有效摩擦减小，当流量超过某个阈值时潮波振幅衰减反而减弱，特别是上游马鞍山-芜湖段最为明显，统计结果表明该河段流量阈值约为33 000 m3/s。本文分析结果作为前人研究的重要补充，可为长江河口感潮河段径潮相互作用机制研究及河口治理等提供基础参考。  相似文献   

中国避暑型与避寒型宜人气候的分布特征及差异     

邓粒子  保继刚 《地理研究》2020,39(1):41-52

宜人气候可以分为避暑型和避寒型两种类型,但现有研究鲜有关注国内两类气候的分布特征及差异。本文采用1981—2010年2132个国家气象观测站数据,基于温湿指数、风寒指数和着衣指数计算各个气象站点的气候综合舒适指数,结合协同克里金空间插值方法对全国避暑型和避寒型宜人气候的分布特征进行了研究,并对两类气候的地域差异进行了分析。结果表明：① 中国避暑型气候区包括40°N以北的西北边疆和东北地区、西北中部地区及西南地区三大集中分布区。中国避寒型气候区集中分布在北回归线以南的低纬地区。② 国内夏冬两季的气候不舒适地域广阔,包括环渤海、长三角等经济发达、人口稠密地区,避暑型与避寒型气候资源的开发潜力显著。③ 两类宜人气候呈现明显的地域分离特征,拥有避暑和避寒双重属性的地方极少。④ 国内避寒型气候是稀缺资源,具有垄断性特征;而避暑型气候相对分布广泛,是一种相对遍在性资源。本文不仅丰富了宜人气候分布特征研究的理论成果,而且可为地方气候资源的旅游开发提供科学依据。  相似文献   

基于SWAT模型的森林分布不连续流域水源涵养量多时间尺度分析   总被引：1，自引：0，他引：1  

林峰  陈兴伟  姚文艺  方艺辉  邓海军  吴杰峰  林炳青 《地理学报》2020,75(5):1065-1078

为解决森林分布不连续流域森林水源涵养功能及其多时间尺度特征的定量评价问题,根据分布式水文模型（SWAT）的特点,提出了反映森林斑块空间分布的水文响应单元划分方法,以及基于水量平衡法的森林不连续分布流域森林水源涵养量计算公式。以东南沿海的晋江流域为例,构建了2006年土地利用条件下的日时间步长SWAT模型,统计分析了2002—2010年降水条件下森林水源涵养量的时空变化规律。结果表明：① 构建的晋江流域SWAT模型精度较高,面积阈值为零生成的水文响应单元比较准确地反映流域森林斑块分布,提出的森林水源涵养量计算公式适用于森林空间分布不连续流域森林水源涵养量的多时间尺度分析,为流域森林水源涵养功能评价提供了一个新的方法。② 晋江流域森林水源年涵养量271.41~565.25 mm;月涵养量-29.15~154.59 mm;日尺度的极端降水期皆为正值,极端枯水期都为负值。表明年际之间不存在森林水源涵养的蓄丰补枯调节作用,但在年内的部分月份得到体现,而日尺度的森林蓄丰补枯功能充分发挥。从而揭示了不同时间尺度森林水源涵养量及其蓄丰补枯功能的差异。  相似文献   

Zircon provenances provide paleogeographic constraints on models reconstructing the Paleoproterozoic Columbia Supercontinent     

《Gondwana Research》2020

Paleoproterozoic orogens of the North Australian Craton are related to the assembly of the Columbia Supercontinent. The roles of the distinct orogens in the Paleoproterozoic craton amalgamation are poorly understood due to the lack of surface exposure. The age and isotopic systematics of detrital zircon grains hosted in Paleoproterozoic sedimentary sequences are used to unravel the geological history of the craton, in terms of paleogeography and tectonic setting. The oldest (Early Paleoproterozoic) metasedimentary units are characterised by detrital zircon ages peaking at ca. 2500 Ma. The zircon ε_Hf values show large variations in the different orogens and range from −18 to +6. The overlaying youngest turbiditic units show minor accumulation of Archean detritus. Units from apparently different metasedimentary sequences have a major detrital zircon age population at ca. 1865 Ma, and a relatively restricted range of zircon ε_Hf values between −7.3 and +2.6. The isotopic distinctiveness of the oldest units is attributed to local variations in the depositional environment, probably due to horst-graben architecture of the early Paleoproterozoic basin. The youngest turbiditic units blanketed this early horst-graben architecture and in part have a local provenance. Potential detritus sources include South Australian Craton, Dharwar Craton and Aravalli-Lesser Himalayan terrains in India, South China, and Madagascar (Africa). This finding indicates that these regions might have been connected before the Columbia Supercontinent was formed. The ubiquitous ca. 2500 Ma magmatic event records the assembly of these cratonic fragments in a previous supercontinent called Kernorland. In addition, the data do not support a proximity of the North Australian Craton with the North China Block, Western Laurentia (North America), and Kaapvaal Craton (Africa) during Columbia amalgamation.  相似文献