An In‐Depth Characterization of Urban Aerosols Using Electron Microscopy and Energy Dispersive X‐Ray Analysis     

Haider A. Khwaja  Pravin P. Parekh  Adil R. Khan  Daniel L. Hershey  Ronaq R. Naqvi  Abdul Malik  Khalid Khan 《洁净——土壤、空气、水》2009,37(7):544-554

The physical and chemical characterization of aerosols from three large cities, Karachi and Islamabad, Pakistan, and New York City (NYC), USA, was investigated. A scanning electron microscope equipped with an energy dispersive spectrometer (EDS) was used to determine particle morphology and elemental composition of the samples. A Bruker Spirit system in combination with a Sahara detector provided both computer controlled Automated Chemical Classification (ACC) and digital mapping features for analysis purposes. The use of these two features to characterize the elemental composition, particle size, and to determine specific classes or source types is described in this paper. Filters were analyzed for the following elements; Na, Mg, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Se, Br, Sr, Y, Zr, Mo, Pd, Ag, Cd, In, Sn, Sb, Ba, La, Au, Hg, Tl, Pb, and U. The EDS work was qualitative not quantitative. Seven source types (mobile, cement, soil, steel mill, fossil fuel, sea salt and biological) contributed to particulate matter in the ambient air of both cities in Pakistan, whereas there were eight source types (diesel, road dust, automobile, iron, residual fuel oil, sea salt, ammonium sulfate and ammonium nitrate) for NYC. For all three urban centers, vehicular traffic emissions were the main contributor to particle number. Diesel emissions from trucks and buses were relatively more prominent in NYC aerosols, while gasoline emission from automotive exhaust was dominant in the two cities of Pakistan. The cement/limestone component from local cement industries was very evident in both particle surface characteristics and number for both Karachi and Islamabad, but not in NYC air. Sea salt aerosols were seen in the two coastal cities, Karachi and NYC. It was also witnessed in Islamabad aerosols and was attributable to the mining of rock salt at the world's richest salt mine, Khewra, situated upwind from the city.  相似文献   

Geochemical assessment of groundwater contamination with special emphasizes on fluoride,a case study from Midyan Basin,northwestern Saudi Arabia   总被引：1，自引：0，他引：1  

Habes Ghrefat  Yousef Nazzal  Awni Batayneh  Taisser Zumlot  Haider Zaman  Eslam Elawadi  Abdulaziz Laboun  Saad Mogren  Saleh Qaisy 《Environmental Earth Sciences》2014,71(4):1495-1505

Water samples for chemical analyses were collected in January 2012. A total of 72 samples of groundwater were collected from 72 boreholes in the Midyan Basin, northwestern Saudi Arabia. Samples were collected in polyethylene bottles and preserved and the used analytical techniques were in accordance with the standard methods from American public health association. Geochemical analyses of the groundwater samples from Midyan Basin reveal the concentration of fluoride (F) between 0.98 and 2.1 mg/l. Other parameters, e.g, pH, EC, TDS, HCO₃, SO₄, NO₃, Cl, K, Na, Mg, and Ca have been found in a variable proportion. Among them, the concentration of EC, HCO₃, K, Na and Mg is higher than the permissible limits. According to thermodynamical considerations, most of the analysed samples are graded under-saturated with respect to calcite and fluoride, while saturation has been observed in some samples. The under-saturation could probably be attributed to low concentration of calcite and fluoride in the studied wells. Fluoride concentration shows weak positive correlation with EC, TDS, Na, Cl, and SO₄. Factors controlling the concentration of fluoride (F) in the studied samples are the area climate, water chemistry and the presence of accessory minerals in the rocks through which groundwater is circulating, besides the anthropogenic activities in the area.  相似文献   

Lithological mapping with multispectral data–setup and application of a spectral database for rocks in the Balakot area,Northern Pakistan     

Michael Fuchs  Adnan A. Awan  Sardar S. Akhtar  Ijaz Ahmad  Simon Sadiq  Asif Razzak  Naghmah Haider 《山地科学学报》2017,14(5):948-963

In the frame of landslide susceptibility assessment, a spectral library was created to support the identification of materials confined to a particular region using remote sensing images. This library, called Pakistan spectral library (pklib) version 0.1, contains the analysis data of sixty rock samples taken in the Balakot region in Northern Pakistan. The spectral library is implemented as SQLite database. Structure and naming are inspired by the convention system of the ASTER Spectral Library. Usability, application and benefit of the pklib were evaluated and depicted taking two approaches, the multivariate and the spectral based. The spectral information were used to create indices. The indices were applied to Landsat and ASTER data to support the spatial delineation of outcropping rock sequences in stratigraphic formations. The application of the indices introduced in this paper helps to identify spots where specific lithological characteristics occur. Especially in areas with sparse or missing detailed geological mapping, the spectral discrimination via remote sensing data can speed up the survey. The library can be used not only to support the improvement of factor maps for landslide susceptibility analysis, but also to provide a geoscientific basis to further analyze the lithological spot in numerous regions in the Hindu Kush.  相似文献   

西南印度洋中脊49.5°E离轴地壳结构          下载免费PDF全文

王伟  牛雄伟  阮爱国  Syed Waseem Haider  胡昊  王奥星  卫小冬  张洁 《地球物理学报》2018,61(11):4406-4417

超慢速扩张西南印度洋中脊岩浆的集中供给在空间维度上表现为岩浆扩张段（NVR）与相邻的非转换断层不连续带（NTD）地壳结构的差异,而在时间维度上表现为离轴与沿轴地壳结构的差异.为了进一步揭示岩浆集中供给的时空分布特征,本文选取西南印度洋中脊热液区2010年海底地震仪深部探测中平行于洋中脊距轴部偏北约10 km的离轴测线d0d10,使用射线追踪正演和反演的方法,得到了NVR和NTD北侧离轴区域的地壳及上地幔P波速度结构,并与轴部速度结构进行了对比分析.研究结果表明：（1）NTD北侧离轴区域的地壳厚度约5.2 km,其厚度明显大于轴部NTD下方地壳厚度（~3.2 km）,由此推测洋脊轴部NTD区域形成的地壳在不断减薄;（2）NVR北侧离轴区域的地壳厚度约7.0 km,其厚度亦大于轴部NVR地壳厚度（~5.8 km）,表明在洋中脊演化过程中洋脊轴区域的岩浆供给在不断减少,其活动性在不断减弱.  相似文献   

洋中脊扩张速率对洋壳速度结构的约束          下载免费PDF全文

李龑  牛雄伟  阮爱国  刘绍文  Syed Waseem Haider  卫小冬 《地球物理学报》2020,63(5):1913-1926

洋中脊速度结构是揭示大洋岩石圈演化过程的重要约束.为探讨不同扩张速率下洋中脊的洋壳速度结构特征,挑选了全球152处快速(全扩张速率 90mm·a-1)、慢速(全扩张速率20～50mm·a-1)和超慢速(全扩张速率20mm·a-1)扩张洋中脊和非洋中脊的洋壳1-D地震波速度结构剖面,通过筛选统计、求取平均值等方法对分类的洋壳1-D速度结构进行对比研究,获得了不同扩张速率下洋中脊洋壳速度结构差异以及洋中脊与非洋中脊洋壳速度结构差异的新认识:(1)快速、慢速和超慢速扩张洋中脊的平均正常洋壳厚度分别为6.4km、7.2km和5.3km,其中洋壳层2的厚度基本相似,洋壳厚度差异主要源自洋壳层3;其洋壳厚度变化范围分别为4.9～8.1km、4.6～8.7km和4.2～10.2km,随着洋中脊扩张速率减小,洋壳厚度的变化范围逐渐增大;(2)快速扩张洋中脊的洋壳速度大于慢速和超慢速,可能与快速扩张脊洋壳生成过程中深部高密度岩浆上涌比较充足有关;(3)非洋中脊(10Ma)的洋壳比洋中脊(10Ma)的洋壳厚～0.3km,表明洋壳厚度与洋壳年龄有一定的正相关性.  相似文献