Assessing redox properties of standard humic substances     

S. Rakshit  D. Sarkar 《International Journal of Environmental Science and Technology》2017,14(7):1497-1504

Redox properties of humic substances (HS) control important biogeochemical processes. Thus, accurate estimation of redox properties of HS is essential. However, there is no general consensus regarding the best available measurement method of HS redox properties. In this study, we compared several common HS redox property measurement methods using anthraquinone-2,6-disulfonate (AQDS) as model compound, and standard Elliot soil humic acid (1S102H, ESHA), reference Pahokee peat (1R103H, PPHA), and Suwannee River natural organic matter (1R101N, SRNOM) as representative HS. We found that the H₂/Pd reduction method followed by incubation with ferric citrate (FeCit) reagent was incomplete, and the H₂/Pd reduction method followed by incubation with potassium ferricyanide (K₃Fe(CN)₆) was insensitive. Stannous chloride (SnCl₂) reduction followed by titration of excess stannous (Sn²⁺) by potassium dichromate (K₂Cr₂O₇) was found to be most accurate. These findings will help in future investigations on detailed characterizations of functional groups of HS responsible for oxidation/reduction reactions.  相似文献   

Mercury enrichments in core sediments in Hugli–Matla–Bidyadhari estuarine complex,north-eastern part of the Bay of Bengal and their ecotoxicological significance     

M. Chatterjee  J. Canário  S. K. Sarkar  V. Branco  A. K. Bhattacharya  K. K. Satpathy 《Environmental Geology》2009,57(5):1125-1134

Mercury concentrations (Hg_T) in fine-grained fraction (<63 μm) of core sediments of the Hugli–Matla–Bidyadhari estuarine complex, India were analyzed. Results revealed a wide range of spatial variations (<4–93 ng g⁻¹ dry weight) with a definite enhancement level at the lower stretch of the estuarine complex infested with mangrove plants, which might act as a sink to Hg_T. An elevated concentration of Hg was encountered in surface/subsurface layer of the core in majority of the cases resulting from physical, biogenic and postdepositional diagenetic processes that remobilized and resuspended the metal from deeper sediments. A strong positive correlation was observed between the Hg and clay fraction content of the sediments, while the correlations of Hg with Al, Fe and Mn were poor. Based on the index of geoaccumulation (I _geo) and effects range-low (ER-L) value, it is considered that the sediments are less polluted and thus there is less chance of ecotoxicological risk to organisms living in sediments.  相似文献   

Determination of Ocean Wave Period from Altimeter Data Using Wave-Age Concept     

Jignesh Kshatriya  Abhijit Sarkar  Raj Kumar 《Marine Geodesy》2013,36(1):71-79

This study makes use of the concept of wave age in estimating ocean wave period from space borne altimeter measurements of backscattering coefficient and significant wave height. Introduction of wave age allowed better accounting of the difference between swells and wind waves. Using two years (1998 and 1999) data of TOPEX/Poseidon altimeter and ocean data buoy observations in the Indian Ocean, coefficients were generated for wave period, which were subsequently tested against data for the years 2000 and 2001. The results showed the wave period accuracy to be of the order of 0.6 sec (against 1.3 sec obtained with the semiempirical approach, reported earlier).  相似文献   

Inter-Comparison of Numerical Model Generated Surface Winds with QuikSCAT Winds over the Indian Ocean     

Sanjib K. Deb  Suchandra A. Bhowmick  Raj Kumar  Abhijit Sarkar 《Marine Geodesy》2013,36(4):391-408

The accurate surface wind in the equatorial Indian Ocean is crucial for modeling ocean circulation over this region. In this study, the surface wind analysis generated at the European Center for Medium Range Weather Forecasts (ECMWF) and the National Centers for Environmental Prediction (NCEP) are compared with NASA QuikSCAT satellite derived Level2B (swath level) and Level3 (gridded) surface winds for the year 2005. It is observed that the ECMWF winds exhibit speed bias of 1.5 m/s with respect to QuikSCAT Level3 in the southern equatorial Indian Ocean. The NCEP winds are found to exhibit speed bias (1.0–1.5 m/s) in the southern equatorial Indian Ocean specifically during January–February 2005. The biases are also observed in the analysis when compared with Level2B product as well; however, it is less in comparison to Level3 products. The amplitude of daily variations of both ECMWF and NCEP wind speed in Bay of Bengal and parts of the Arabian Sea is about 80% of that in QuikSCAT, while in the equatorial Indian Ocean it is about 60% of that of QuikSCAT.  相似文献   

Substrate control on formation and maturation of glauconites in the Middle Eocene Harudi Formation, western Kutch, India     

Santanu Banerjee  Shovan Lal ChattorajP.K. Saraswati  Somnath DasguptaUrbashi Sarkar 《Marine and Petroleum Geology》2012,30(1):144-160

Formation and maturation of glauconites within the early Middle Eocene Harudi Formation, built up in a lagoon to shelf transition in western Kutch, India is addressed taking recourse to a combined sedimentological, micropalaeontological and mineralogical investigation. The glauconite is authigenic and its occurrence coincides with maximum flooding. The glauconite is more matured within the fecal pellets and is less matured within the intra-particle pores of bioclasts namely, foraminifera, ostracoda, gastropoda and bryozoa. SEM-EDS, XRD and geochemical studies clearly document that the infilling within the intra-particle pores of bioclasts belong to nascent to slightly evolved glauconite (<5 wt% K₂O), while the pellet belongs to slightly evolved to evolved glauconite (5-7 wt% K₂O). Based on chemical characteristics and SEM investigations the glauconitization process can be best explained by the ‘verdissement theory’. The glauconite possibly formed as initial authigenic glauconitic smectite precipitates; while the pellet matured subsequently by addition of K, the process was hindered in case of infillings. The maturation process also involved addition of Si and release of Al, with or without release of Mg. The glauconite maturation was facilitated in case of fecal pellets because of higher porosity, inter-granular nature of pores and availability of necessary elements in semi-confined micro-environments. In contrast, the maturation was aborted at an early stage in case of infillings because of the minute, closed nature of the pores and prevalent alkaline conditions not allowing dissolution of calcitic tests. A low negative cerium anomaly suggests glauconite formation in sub-oxic micro-environments, created by decay of organic matters within the fecal pellets and bioclasts. A clear case of substratum control on glauconitization becomes apparent.  相似文献   

Geochemical Fractionation of Trace Elements in Stream Sediments Contaminated by Mining Activity          下载免费PDF全文

Paulo J. C. Favas  Santosh Kumar Sarkar  Dibyendu Rakshit 《洁净——土壤、空气、水》2015,43(3):446-455

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Hydrogeological characterization of aquifer in palla flood plain of Delhi using integrated approach     

Suman Kumar  Aditya Sarkar  Sachin Kumar Thakur  Shashank Shekhar 《Journal of the Geological Society of India》2017,90(4):459-466

The Yamuna flood plains spread across the northern part of Indian subcontinent is home to millions of people. The ever-growing population in these plains make it difficult to sustain the demand of freshwater resources. However, the productive aquifers of flood plains could provide solution for these issues. In this context, it is necessary to understand the aquifer characteristics. Thus, the paper attempts to characterize the aquifer in Palla area of the flood plain using integrated approach. Besides, grain size analysis and site-litholog study, the nature of aquifer material was also ascertained from bulk mineralogy of the sediments using X-Ray Diffraction. The aquifer parameters were estimated with help of long duration pumping test data. Moreover, the effect of pumping on salinity variation and hydrochemical facies evolution was also examined. The sand dominant, unconfined aquifer was estimated to have horizontal hydraulic conductivity in the range of 25 m/day and vertical hydraulic conductivity of 6–7 m /day. While the specific yield of the aquifer was estimated in the range of 0.07–0.08. It is observed that under conducive active flood plain environment, the given sand mineralogy at the site does not allow salinity increase in groundwater even after more than a decade of groundwater pumping. In fact, over years, hydrochemical facies have evolved towards Bicarbonate type. These things put together make the active flood plain aquifer a sustainable groundwater resource.  相似文献   

Seismic profile analysis of the Kangra and Dehradun re-entrant of NW Himalayan Foreland thrust belt,India: A new approach to delineate subsurface geometry     

Joyjit Dey  R Jayangonda Perumal  Subham Sarkar  Anamitra Bhowmik 《Journal of Earth System Science》2017,126(6):83

In the NW Sub-Himalayan frontal thrust belt in India, seismic interpretation of subsurface geometry of the Kangra and Dehradun re-entrant mismatch with the previously proposed models. These procedures lack direct quantitative measurement on the seismic profile required for subsurface structural architecture. Here we use a predictive angular function for establishing quantitative geometric relationships between fault and fold shapes with ‘Distance–displacement method’ (D–d method). It is a prognostic straightforward mechanism to probe the possible structural network from a seismic profile. Two seismic profiles Kangra-2 and Kangra-4 of Kangra re-entrant, Himachal Pradesh (India), are investigated for the fault-related folds associated with the Balh and Paror anticlines. For Paror anticline, the final cut-off angle \(\beta =35{^{\circ }}\) was obtained by transforming the seismic time profile into depth profile to corroborate the interpreted structures. Also, the estimated shortening along the Jawalamukhi Thrust and Jhor Fault, lying between the Himalayan Frontal Thrust (HFT) and the Main Boundary Thrust (MBT) in the frontal fold-thrust belt, were found to be 6.06 and 0.25 km, respectively. Lastly, the geometric method of fold-fault relationship has been exercised to document the existence of a fault-bend fold above the Himalayan Frontal Thrust (HFT). Measurement of shortening along the fault plane is employed as an ancillary tool to prove the multi-bending geometry of the blind thrust of the Dehradun re-entrant.  相似文献   

Chelant‐assisted Phytostabilization of Paint‐contaminated Residential Sites     

Syam S. Andra  Dibyendu Sarkar  Sumathi K. M. Saminathan  Rupali Datta 《洁净——土壤、空气、水》2010,38(9):803-811

Following the basic incubation study, a greenhouse experiment was conducted to elucidate the efficiency of vetiver grass (Vetiveria zizanioides L.), with or without chelating agents, in remediating lead (Pb)‐contaminated soils from actual residential sites where Pb‐based paints were used. Because the primary factor affecting Pb phytoavailability in soils is soil pH, we used two soil types widely varying in pH that have total Pb concentrations above 1500 mg kg^?1 soil. Lead‐contaminated, low pH, acidic soils were collected from residential sites in Baltimore, MD and high pH, alkaline soils were collected from residential sites in San Antonio, TX. Based on the soil characterization results, two most appropriate soils (one from each city, having similar Pb levels but variable soil physico‐chemical properties) were selected for this study. Ethylenediaminetetraacetic acid (EDTA) and [S,S′]ethylenediaminedisuccinate (EDDS) were applied at 5, 10, and 15 mmol kg^?1 soil. Lead uptake and translocation in vetiver was determined on day 10 after chelants addition. Plant and soil analysis show that EDTA treated soils have maximum Pb uptake and lower total soil Pb levels. Prediction models developed for exchangeable Pb show a strong correlation for total Pb accumulated in vetiver grass. Results of the sequential chemical extraction of the soils at both initial and final time‐points, indicates a significant mobilization of Pb by the two chelants from carbonate‐bound fraction to exchangeable pool. Information on physico‐chemical properties of contaminated residential soils help in predicting Pb phytoextraction and thus further help in calibrating a successful chelant‐assisted phytoremediation model.  相似文献   

Application of an Alkali Functionalized Material for Treating Pharmaceutical Wastewater Containing Chlorhexidine Gluconate and Cetrimide          下载免费PDF全文

Debasree Banerjee  Shyamal Jana  Ujjaini Sarkar  Debasri Roy 《洁净——土壤、空气、水》2016,44(2):169-179

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