西藏玉龙铜矿床成矿斑岩的厘定及地质意义     

孙茂妤  曲焕春  李秋耘  周利敏  杨志明  刘申态  刘永刚 《岩石矿物学杂志》2015,34(4):493-504

位于青藏高原东缘的玉龙铜矿是我国最大的斑岩铜矿之一,其形成一致认为与矿区中心产出的二长花岗质复式斑岩体有关,但成矿与复式岩体的确切关系并不清楚。本文通过详细的野外地质填图,特别是矿床8号勘探线12个钻孔的重新编录,在复式岩体中识别出一套花岗斑岩岩枝,岩枝中不规则状石英-钾长石脉广泛发育,同时还见有单向固结结构、粗晶及细晶结构,这些特征表明该岩浆中的流体曾经发生过饱和。同时结合矿床高品位(0.6%,质量分数)铜矿化紧密围绕花岗斑岩分布、含矿脉体自花岗斑岩向外围逐渐由高温石英-钾长石A脉过渡为中低温石英-硫化物脉、热液蚀变自花岗斑岩向外由高温钾硅酸盐化过渡为中低温石英-绢云母化的规律,最终确定这套花岗斑岩为玉龙矿床的成矿斑岩。玉龙铜矿成矿斑岩的厘定,较好地解释了矿床矿化类型及金属的分布规律,为进一步深入理解矿床形成过程提供了帮助。  相似文献   

硫代硫酸钠沉淀法富集铜冶炼废酸中铼的实验研究   总被引：2，自引：0，他引：2  

王永斌  黄建芬  栗威  梁富明 《岩石矿物学杂志》2015,34(1):110-116

白银有色集团铜业公司冶炼废酸量每年约为1×105m3,其中铼含量为5~70 mg/L,为综合利用废酸中的铼,采用硫代硫酸钠作为特效沉淀剂,对该沉淀剂加入量、反应时间、反应温度以及废酸中铼含量对铼沉淀率的影响做了较系统的实验研究,得到较优化的沉淀条件。进一步的中试放大实验取得了良好的技术指标:富铼渣泥中含铼达1.66%,铼的回收率达到99.8%。在此基础上,对沉淀剂的氧化还原反应机理进行了探讨。本方法工艺简单,铼沉淀率高,环境友好,较适用于废酸中铼的高效提取。  相似文献   

Zircon U-Pb Geochronology and Geochemical Characteristics of the Volcanic Host Rocks from the Tongyu VHMS Copper Deposit in the Western North Qinling Orogen and Their Geological Significance     

XIONG Xiao  ZHU Laimin  LI Ben  ZHANG Guowei  GONG Hujun  ZHENG Jun  JIANG Hang 《《地质学报》英文版》2015,89(6):1926-1946

Precise in situ zircon U-Pb dating and Lu–Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr–Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE(e.g. Th, U, Pb and La) and depletion of HFSE(e.g. Nb, Ta, Ti, Zr and Hf). Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr(0.703457 to 0.708218) and εNd(t)(-2 to 5.8) indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd(t) diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf(t) values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores(2616±39 Ma and 1297±22 Ma). The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.  相似文献   

基于Micromine的赞比亚西北省希富玛铜矿床资源量估算          下载免费PDF全文

张士红  李传班  杨国防 《地质找矿论丛》2015,30(2):256-260

赞比亚西北省希富玛铜矿床是中矿资源勘探股份有限公司在"走出去"战略背景下取得的一个勘探找矿成果。文章基于Micromine三维矿业软件平台,建立了希富玛铜矿床地质数据库,并对矿体进行了地质解译及圈定,同时结合矿区的一个矿体,介绍了采用距离反比加权法进行资源量估算的原理和流程。  相似文献   

Re–Os and U–Pb Geochronology of Porphyry and Skarn Types Copper Deposits in Jilin Province,NE China          下载免费PDF全文

Yong Zhang  Shu–Wen Xing  Quan–Heng Song  Yan Wang  Zheng–Tao Yu  Xiao–Hui Du  Yu–Bo Ma  Zeng–Jie Zhang 《Resource Geology》2015,65(4):394-404

Jilin Province in NE China lies on the eastern edge of the Xing–Meng Orogenic Belt. Mineral exploration in this area has resulted in the discovery of numerous large, medium, and small sized Cu, Mo, Au, and Co deposits. To better understand the formation and distribution of both the porphyry and skarn types Cu deposits of the region, we examined the geological characteristics of the deposits and applied zircon U–Pb and molybdenite Re–Os isotope dating to constrain the age of the mineralization. The Binghugou Cu deposit yields a zircon U–Pb age for quartz diorite of 128.1 ± 1.6 Ma; the Chang'anpu Cu deposit yields a zircon U–Pb age for granite porphyry of 117.0 ± 1.4 Ma; the Ermi Cu deposit yields a zircon U–Pb age for granite porphyry of 96.8 ± 1.1 Ma; the Tongshan Cu deposit yields molybdenite Re–Os model ages of 128.7 to 130.2 Ma, an isochron age of 129.0 ± 1.6 Ma, and a weighted mean model age of 129.2 ± 0.7 Ma; and the Tianhexing Cu deposit yields molybdenite Re–Os model ages of 113.9 to 115.2 Ma, an isochron age of 114.7 ± 1.2 Ma, and a weighted mean model age of 114.7 ± 0.7 Ma. The new ages, combined with existing geochronology data, show that intense porphyry and skarn types Cu mineralization was coeval with Cretaceous magmatism. The geotectonic processes responsible for the genesis of the Cu mineralization were probably related to lithospheric thinning. By analyzing the accumulated molybdenite Re–Os, zircon U–Pb, and Ar–Ar ages for NE China, it is concluded that the Cu deposits formed during multiple events coinciding with periods of magmatic activity. We have identified five phases of mineralization: early Paleozoic (~476 Ma), late Paleozoic (286.5–273.6 Ma), early Mesozoic (~228.7 Ma), Jurassic (194.8–137.1 Ma), and Cretaceous (131.2–96.8 Ma). Although Cu deposits formed during each phase, most of the Cu mineralization occurred during the Cretaceous.  相似文献   

基于ETM~+数据和GIS技术的缅甸铜金矿成矿预测     

独文惠  王功文  陈永清  郭娜娜  郝应龙  冯源 《地质通报》2015,34(4):786-791

在利用遥感数据和地理信息系统(GIS)技术的矿产资源勘查与评价中,矿化蚀变信息提取和构造信息提取起着至关重要的作用。以缅甸铜金矿为例,利用ETM+遥感图像,采用比值法、阈值分割和主成分分析(PCA)提取羟基蚀变信息;利用数字高程模型和遥感数据提取与铜金矿化有关的线环构造,结合地质资料和上述信息,利用证据权和分形方法进行整合,确定该研究区的成矿远景区。结果发现,已知铜金矿均分布于成矿靶区中,综合信息可为下一步的矿产资源勘探工作提供决策依据。  相似文献   

西藏朱诺斑岩铜 钼 金矿区侵入岩锆石U Pb年龄、Hf同位素组成及其成矿意义   总被引：2，自引：0，他引：2  

黄勇  丁俊  李光明  戴婕  闫国强  王刚  刘晓峰 《地质学报》2015,89(1):99-108

朱诺斑岩铜钼金矿位于冈底斯成矿带南缘,是近年来在冈底斯斑岩铜矿带最西端新发现的另一大型斑岩型铜-钼-金矿床,但一直以来对该矿区花岗岩年代学及成因分析缺乏系统的研究。本文选择矿区内主要岩浆岩体开展LA-ICP-MS锆石U-Pb定年,Hf同位素研究。获得黑云母花岗闪长岩锆石U-Pb年龄为14.14±0.32Ma,76 Hf/177 Hf介于0.282484~0.282750,εHf(t)介于-9.87~-0.49,二阶段模式年龄TDMC介于1.13~1.73Ga、似斑状二长花岗岩锆石U-Pb年龄为14.05±0.31Ma,176 Hf/177 Hf介于0.282633~0.282769,εHf(t)介于-4.61~0.21,二阶段模式年龄TDMC介于1.08~1.39Ga之间;角闪闪长玢岩锆石U-Pb年龄为14.10±0.29Ma,除4.1号为继承锆石外,其余测点176 Hf/177 Hf介于0.282607~0.282761,εHf(t)介于-5.53~-0.07,二阶段模式年龄TDMC介于1.10~1.45Ga之间。年代学与Hf同位素结果表明,朱诺斑岩铜矿与斑岩铜矿带中段和东段成岩成矿时代一致,集中在15~13Ma之间,指示了冈底斯在中新世的构造岩浆活动事件。花岗岩Hf同位素组成明显与中-东段斑岩矿床不同,具有富集Hf同位素特征以及古老二阶段模式年龄(1.08~1.73Ga)等特点,反映出朱诺矿区中新世岩浆岩源区与中-东段中新世斑岩矿床明显不同,可能指示古老拉萨地体的印迹。  相似文献   

青海省都兰县郭勒纸铜矿区地质特征及找矿前景浅析     

王彦明  李军  张国权 《山东国土资源》2015,31(8)

工作区位于东昆仑山脉中段,布尔汗布达山南坡。区域上断裂构造较为发育,岩浆活动频繁,岩浆热液以及岩浆期后热液活动强烈,为成矿元素的进一步活化、运移、富集创造了条件。该文对区内的成矿地质背景、矿床地质特征,矿石特征、矿床成因及控矿因素进行研究分析,认为该矿床有着较好的找矿前景。同时也确定地层标志、构造标志、蚀变标志为其找矿标志,以指导后续普查工作的有效进行。  相似文献   

Effects of waterborne Cu and Cd on anti-oxidative response,lipid peroxidation and heavy metals accumulation in abalone Haliotis discus hannai ino     

Lei  Yanju  Zhang  Wenbing  Xu  Wei  Zhang  Yanjiao  Zhou  Huihui  Mai  Kangsen 《中国海洋大学学报(英文版)》2015,14(3):511-521

The aim of this study was to compare the effects of waterborne copper(Cu) and cadmium(Cd) on survival, anti-oxidative response, lipid peroxidation and metal accumulation in abalone Haliotis discus hannai. Experimental animals(initial weight: 7.49 g ± 0.01 g) were exposed to graded concentrations of waterborne Cu(0.02, 0.04, 0.06, 0.08 mg L-1) or Cd(0.025, 0.05, 0.25, 0.5mg L-1) for 28 days, respectively. Activities of the anti-oxidative enzymes(catalase, CAT; superoxide dismutase, SOD; glutathione peroxidases, GPx; glutathione S-transferase, GST), contents of the reduced glutathione(GSH) and malondiadehyde(MDA) in the hepatopancreas, and metal accumulation in hepatopancreas and muscles were analyzed after 0, 1, 3, 6, 10, 15, 21, 28 days of metal exposure, respectively. Results showed that 0.04 mg L-1, 0.06 mg L-1 and 0.08 mg L-1 Cu caused 100% death of abalone on the 21 st, 10 th and 6th day, respectively. However, no dead abalone was found during the 28-day waterborne Cd exposure at all experimental concentrations. Generally, activities of SOD and GST in hepatopancreas under all Cu concentrations followed a decrease trend as the exposure time prolonged. However, these activities were firstly increased and then decreased to the control level and increased again during Cd exposure. Activities of CAT in all Cu exposure treatments were higher than those in the control. These activities were firstly increased and then decreased to the control level and increased again during Cd exposure. Contents of MDA in hepatopancreas in all Cu treatments significantly increased first and then decreased to the control level. However, the MDA contents in hepatopancreas were not significantly changed during the 28-day Cd exposure. The metals accumulation in both hepatopancreas and muscles of abalone significantly increased with the increase of waterborne metals concentration and exposure time. These results indicated that H. discus hannai has a positive anti-oxidative defense against Cu or Cd. In conclusion, anti-oxidative mechanism in abalone to resist waterborne Cu did not follow the same pattern as that for waterborne Cd.  相似文献   

吡啶硫酮类防污剂对华美盘管虫早期不同发育阶段的毒性效应研究     

商群  陈新  王超超  葛天宇  曹瑞  朱秀琴  徐利婷  唐敏 《海洋科学》2015,39(9):33-38

以中国南海常见的多毛类——华美盘管虫(Hydroides elegans)作为受试生物,分别研究了吡啶硫酮铜和吡啶硫酮锌对早期不同发育阶段的华美盘管虫的急性毒理效应。发现暴露于吡啶硫酮铜的华美盘管虫精子和卵子的受精半数抑制浓度(IC50)分别为19.49μg/L和88.44μg/L,担轮幼虫24 h半数致死浓度(24h-LC50)和48 h半数致死浓度(48h-LC50)分别为7.35μg/L和5.00μg/L,后担轮幼虫24h-LC50和48h-LC50分别为8.57μg/L和5.87μg/L;暴露于吡啶硫酮锌的华美盘管虫精子和卵子的受精IC50分别为36.74μg/L和159.59μg/L,担轮幼虫24 h-LC50和48 h-LC50分别为8.57μg/L和6.67μg/L,后担轮幼虫24 h-LC50和48 h-LC50分别为12.03μg/L和8.07μg/L。表明华美盘管虫早期发育的不同阶段对吡啶硫酮铜和吡啶硫酮锌的敏感性表现出一定差异,与配子受精率和后担轮幼虫的毒性反应相比,担轮幼虫对吡啶硫酮铜和吡啶硫酮锌的毒性表现出较高的敏感性;而且,对吡啶硫酮铜的敏感性普遍高于吡啶硫酮锌。  相似文献