Improved reliability in the interpretation of geochemical measurements by the quantification of uncertainty from sampling     

Michael H. Ramsey Paul D. Taylor Katy A. Boon 《中国地球化学学报》2006,25(B08):209-210

All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants （organic and metals）, previous land uses （e.g. tin mining, railway sidings and gas works）, intended future use （housing to nature reserves） and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty （〉70% of measurement uncertainty） in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation （OCLI） method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 （predicted by sampling theory）. It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment.  相似文献   

Modification of streaming potential by precipitation of calcite in a sand–water system: laboratory measurements in the pH range from 4 to 12     

Xavier Guichet  Laurence Jouniaux  Nicole Catel 《Geophysical Journal International》2006,166(1):445-460

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Comparison of magnetic parameters with vehicular Br levels in urban roadside soils     

Xue-Song Wang  Yong Qin 《Environmental Geology》2006,50(6):787-791

Chemical methods are generally chosen to monitor soil pollution but magnetic measurements proved to yield additional information at low cost and less time consumption. In this investigation, the novel use of rapid and non-destructive magnetic measurements to characterize Br levels in Xuzhou (China) urban roadside soils was reported. X-ray fluorescence spectrometry (XRF) was used to quantify Br in the soil samples. Data from 21 roadside soil samples confirm Br contamination, with a mean level of 4.36 mg kg⁻¹ and a range of 2.4–8.7 mg kg⁻¹. These values are higher than that of unpolluted soils in Xuzhou that averages 1.1 mg kg⁻¹. Hierarchical clustering analysis shows Br in Xuzhou roadside soils is mainly from road traffic. Clear correlations between Br levels and simple magnetic parameters [mass specific susceptibility (χ _LF), susceptibility of anhysteretic remanent magnetization (χ _ARM), saturation isothermal remanence (SIRM)] are observed. The present study shows that these three magnetic parameters can be used as a proxy for Br levels in Xuzhou urban roadside soils.  相似文献   

圆形标志中心子像素定位方法的研究与实现   总被引：18，自引：1，他引：18  

黄桂平 《武汉大学学报(信息科学版)》2005,30(5):388-391

采用回光反射材料制作圆形回光反射标志，经摄影后得到标志的“准二值影像”；对标志的椭圆影像进行亚像素边缘提取，经最小二乘椭圆拟合后得到标志中心的子像素级位置。试验表明，可以达到0．02像素的定位精度。  相似文献   

中国大陆科学钻探主孔声发射法现今地应力状态的确定   总被引：9，自引：0，他引：9       下载免费PDF全文

王连捷李朋武  崔军文丁原辰 《中国地质》2005,32(2):259-264

对中国大陆科学钻探主孔的岩心进行了声发射测量,确定了301～1531m深度的最大主应力。并与钻孔崩落法(深度1269～1655m)测量结果进行了对比,结果表明,声发射测量所得测值基本上落在钻孔崩落法测值的趋势线上,两种方法所得结果一致,说明测量结果可信。测量结果表明科学钻探主孔地应力大小随深度增加,在浅部301m最大主应力为13.4MPa,在深部1655m为55.2MPa。随深度的增加率为0.0279MPa/m。最大主应力方向为N54°±3.3°E,且方向不随深度变化。  相似文献   

贵州大方县公鸡山地裂缝特征成因及防治     

安正泽 《中国地质灾害与防治学报》2005,16(1):69-71

文章通过对贵州省大方县以公鸡山地裂隙实地调查，认为地裂隙的形成主要与公鸡山一带地下采煤有关。即采煤虚脱，沿先存构造断裂拉张而成。同时叙述了地裂缝特征及危害，并提出防灾减灾措施。  相似文献   

城市热岛效应监测方法研究进展   总被引：16，自引：0，他引：16  

肖荣波  欧阳志云  张兆明  王效科  李伟峰  郑华 《气象》2005,31(11):3-6

城市热岛效应是一种由于城市建筑及人们活动导致的热量在城区空间范围内聚集的现象,是城市气候最明显的特征之一.由于城市热岛影响因素以及相互关系的复杂性,为了精确细致地描述其时空分布,人们采用了多种方法来研究城市热岛现象,主要归纳为：气象站法、定点观测法、运动样带法、遥感测定法以及模拟预测等.最后,认为各种测定方法都存在一定的缺陷,建议多种测定方法综合运用.  相似文献   

等距等高电磁波测距三角高程测量及精度分析   总被引：7，自引：0，他引：7  

张正禄  黎明  邓勇  罗长林  张松林 《现代测绘》2005,28(1):3-4,19

介绍了等距等高电磁波测距三角高程测量的原理，详细深入地分析了这种高程测量方法的精度，通过计算和作图表示，可直观地反映在不同条件下的精度变化情况，讨论了代替国家等级水准测量的范围和条件，可供生产实际和进一步研究参考。  相似文献   

Hyper Redundancy for Accuracy Enhancement in Automated Close Range Photogrammetry   总被引：1，自引：0，他引：1  

Clive S.  Fraser  Alex  Woods  Danny  Brizzi 《The Photogrammetric Record》2005,20(111):205-217

A generic network design in close range photogrammetry is one where optimal multi-ray intersection geometry is obtained with as few camera stations as practicable. Hyper redundancy is a concept whereby, once the generic network is in place, many additional images are recorded, with the beneficial impact upon object point precision being equivalent to the presence of multiple exposures at each camera position within the generic network. The effective number of images per station within a hyper redundant network might well be in the range of 10 to 20 or more. As is apparent when it is considered that a hyper redundant network may comprise hundreds of images, the concept is only applicable in practice to fully automatic vision metrology systems, where it proves to be a very effective means of enhancing measurement accuracy at the cost of minimal additional work in the image recording phase. This paper briefly reviews the network design and accuracy aspects of hyper redundancy and illustrates the technique by way of the photogrammetric measurement of surface deformation of a radio telescope of 26 m diameter. This project required an object point measurement accuracy of σ  = 0·065 mm, or 1/400 000 of the diameter of the reflector.  相似文献   

Electrical aerosol spectrometer of Tartu University     

H. Tammet  A. Mirme  E. Tamm   《Atmospheric Research》2002,62(3-4)

The electrical aerosol spectrometer (EAS) of the parallel measuring principle at Tartu University is an efficient instrument for rapid measurement of the unstable size spectrum of aerosol particles. The measuring range from 10 nm to 10 μm is achieved by simultaneously using a pair of differential mobility analyzers with two different particle chargers. The particle spectrum is calculated and measurement errors are estimated in real time by using a least-squares method. Experimental calibration ensures reliability of measurement. The instrument is well suited for continuous monitoring of atmospheric aerosol.  相似文献