Origin of rutile needles in star garnet and implications for interpretation of inclusion textures in ultrahigh‐pressure metamorphic rocks          下载免费PDF全文

S.‐L. Hwang  P. Shen  H.‐T. Chu  T.‐F. Yui  Y. Iizuka 《Journal of Metamorphic Geology》2015,33(3):249-272

The asterism effect of star garnet has been attributed to the oriented distribution of needle‐like rutile inclusions. Rutile needles occur in garnet from a wide range of metamorphic settings and rock bulk compositions, and their origin has been ascribed to different mechanisms, such as exsolution, and used to interpret petrological and tectonic processes. Results from an optical and transmission electron microscopy of Idaho star garnet indicate a co‐precipitation origin. It was found that rutile needles are predominantly oriented along the <103>_rt//<111>_grt and <001>_rt//<001>_grt directions following multiple crystallographic orientation relationships (CORs); i.e. COR‐1, 2, 2′, 3, 4 and 5 in 6‐ray star garnet, and are oriented solely along the <103>_rt//<111>_grt directions following exclusively COR‐2 in 4‐ray star garnet. The sole presence of COR‐2 <111>_grt needles in the common 4‐ray star garnet, in contrast to the presence of both <111>_grt and <001>_grt needles with multiple CORs in the rare 6‐ray star garnet, suggests that the COR‐2 <111>_grt needle probably is the energetically most favoured variant, as is also supported by the coincidence site lattice considerations. The unique crystallography‐controlled microstructures of 4‐ray star garnet, including the cloudy domains behind the {111}_grt or {100}_grt fronts with abundant inclusions of rutile needle, rutile compound needle and multiple‐phase‐inclusion, as well as the clear domains behind the {110}_grt fronts with only a few above inclusions concentrated exclusively within the linear, <110>_grt‐oriented, continuous tube‐like domains, further suggest that the COR‐2 <111>_grt needles in 4‐ray star garnet most likely have a growth‐in origin, co‐precipitating with garnet at its growth fronts close to thermodynamic equilibrium conditions. The 6‐ray star garnet, on the other hand, most likely formed under far‐from equilibrium conditions, thereby yielding a maximum of 99 crystallographic variants of rutile needles with multiple CORs in a single crystal. In the light of these findings, along with the common occurrences of the sole COR in many inclusion‐host systems owing to the requirement to minimize the energy barrier in an exsolution process, the presence of both <103>_rt//<111>_grt and <001>_rt//<001>_grt needles with multiple CORs in garnet of Sulu eclogite and Erzegebirge quartzofeldspathic rock would therefore cast doubt on the assertion of an exsolution origin of rutile needles in garnet from these ultrahigh‐pressure rocks.  相似文献   

拉萨地块东南缘晚白垩世高温变质作用及其地质意义:来自石英出溶金红石的证据和锆石U-Pb定年          下载免费PDF全文

郭亮  张宏飞  潘发斌 《地学前缘》2012,19(3):228-239

文中对拉萨地块东南缘林芝杂岩中的含榴斜长角闪岩进行了详细的岩相学研究和锆石U-Pb定年。岩相学观察表明,含榴斜长角闪岩经历了峰期麻粒岩相变质和角闪岩相退变质作用。峰期麻粒岩相矿物组合为石榴子石+高Ti角闪石+紫苏辉石+斜长石+石英+金红石,其中的石榴子石、石英和角闪石中含有大量金红石出溶体,说明这些矿物的初始成分具有高Ti含量。角闪岩相退变质矿物组合为低Ti角闪石+斜长石+斜黝帘石+石英+金红石。利用Ti在石英中的含量(TitaniQ)温度计计算得到峰期麻粒岩相变质温度为803～924℃,后期角闪岩相退变质温度为555～732℃。样品中的锆石具有明显的核边结构,核部为典型岩浆型锆石,具有高的Th/U值,强烈富集HREE,明显的正Ce异常和负Eu异常,206Pb/238U年龄为(89.3±0.6)Ma,代表含榴斜长角闪岩原岩结晶年龄。锆石边部呈无环带结构,同核部相比,具有低的Th/U值,低的M-HREE和弱的Eu负异常,为变质峰期生长的锆石,206Pb/238U年龄为(81.1±0.8)Ma,代表麻粒岩相峰期变质年龄。我们认为约81Ma高温麻粒岩相变质作用可能与洋中脊俯冲造成的板片窗导致的软流圈上涌有关。  相似文献   

Geochemical features of the Matomb alluvial rutile from the Neoproterozoic Pan-African belt,Southern Cameroon     

《Chemie der Erde / Geochemistry》2014,74(4):557-570

The Matomb region constitutes an important deposit of detrital rutile. The rutile grains are essentially coarse (> 3 mm), tabular and elongated, due to the short sorting of highly weathered detritus. This study reports the major, trace, and rare-earth element distribution in the bulk and rutile concentrated fractions. The bulk sediments contain minor TiO₂ concentrations (1–2 wt%), high SiO₂ contents (∼77–95 wt%) and variable contents in Al₂O₃, Fe₂O₃, Zr, Y, Ba, Nb, Cr, V, and Zn. The total REE content is low to moderate (86–372 ppm) marked by high LREE-enrichment (LREE/HREE ∼5–25.72) and negative Eu anomalies (Eu/Eu^* ∼0.51–0.69). The chemical index of alteration (CIA) shows that the source rocks are highly weathered, characteristic of humid tropical zone with the development of ferrallitic soils. In the concentrated fractions, TiO₂ abundances exceed 94 wt%. Trace elements with high contents include V, Nb, Cr, Sn, and W. These data associated with several binary diagrams show that rutile is the main carrier of Ti, V, Nb, Cr, Sn, and W in the alluvia. The REE content is very low (1–9 ppm) in spite of the LREE-abundance (LREE/HREE ∼4–40). The rutile concentrated fractions exhibit anomalies in Ce (Ce/Ce^* ∼0.58 to 0.83; ∼1.41–2.50) and Eu (Eu/Eu^* ∼0.42; 1.20–1.64). The high (La/Sm)_N, (La/Yb)_N and (Gd/Yb)_N ratios indicate high REE fractionation.  相似文献   

柴达木盆地北缘鱼卡—铁石观一带金红石矿床的发现及其地质意义   总被引：3，自引：2，他引：1  

王永开  徐永利  郑有业  周宾  吕登  张晓鹏  吴亮  马超  许荣科 《地质通报》2014,33(6):900-911

通过野外地质调查、岩石学、矿相学等研究手段,在柴达木盆地北缘鱼卡及铁石观一带均发现榴辉岩型金红石矿床,其单个矿体长可达千米以上,宽均达几米至几十米不等,金红石物相Ti平均品位可达2.58%,属于高钛榴辉岩的范畴,且其矿床地质特征与大别—苏鲁地区的金红石矿床特征极为相似。鱼卡和铁石观金红石矿床的发现,填补了柴北缘榴辉岩变质带没有金红石矿床的空缺,并暗示柴北缘地区有发现大型榴辉岩矿床的找矿远景。  相似文献   

大阜山金红石矿床含矿岩体的岩石学特征及其地质意义     

刘海艳  周汉文  兰亚萍  李德华 《矿物学报》2010,30(1)

大阜山以赋存金红石矿床而闻名,主体为基性变质岩体,以榴闪岩为主。主要矿物石榴子石、角闪石、斜长石、金红石等主要经历了3个发育期次,不同期次具有不同的产状特征。根据野外地质、岩石学、元素地球化学研究分析,结合区域地质背景资料,认为含矿岩体原岩为辉长岩,具正铕异常,低温中高压环境下变质而成。受扬子板块向华北板块俯冲后快速折返的影响,含矿岩体经历了退变质过程,金红石矿床形成。因此,金红石矿床是变质原岩(辉长岩)在区域变质作用下,经构造演化等综合作用的结果。  相似文献   

华北克拉通兴城早白垩世玄武玢岩锆石、金红石地球化学特征及其地质意义     

何登洋  邱昆峰  张莲  于皓丞  杨泽宇 《岩石矿物学杂志》2020,39(6):735-750

华北克拉通在中生代时期发生大规模的岩石圈减薄，伴生的早白垩世火山岩为研究克拉通破坏提供了窗口，但其中镁铁质火山岩成因和岩浆源区性质的争议，制约了对克拉通破坏机制和中生代岩石圈减薄结束时间的认识。本文用激光剥蚀电感耦合等离子质谱（LA-ICP-MS）方法对兴城玄武玢岩中的锆石、金红石进行了系统的微量元素分析，以揭示岩浆源区性质及其演化，并进一步探讨了华北克拉通中生代岩石圈减薄的机制和结束时间。锆石t_Ti温度计计算结果表明，兴城玄武玢岩锆石结晶温度为695~779℃，平均温度为730℃，说明玄武玢岩可能起源于俯冲带地幔楔交代橄榄岩。微量元素分析结果显示，锆石富集HREE，LREE与HREE分异明显，Nb、Ti亏损，Th、U和Hf相对富集，Ce、Eu呈不同程度的正、负异常；金红石Nb、Ti、Hf等高场强元素呈不同程度富集，Sr明显亏损，无明显的Ce、Eu异常。微量元素特征也显示玄武玢岩岩浆起源于岩石圈地幔交代橄榄岩，后期经历了氧化作用和分离结晶作用。结合区域内相关地质资料，认为兴城玄武玢岩岩浆为古老岛弧型岩浆。华北克拉通中生代岩石圈减薄的结束时间可约束到早白垩世晚期（约105 Ma），高角度俯冲的古太平洋板块回撤为华北克拉通岩石圈减薄的一级动力学机制，热化学侵蚀或拆沉为二级机制。  相似文献   

苏北榴辉岩型金红石资源的综合利用     

徐少康  徐子江 《化工矿产地质》2009,31(3):170-174

金红石和铁铝榴石是中国榴辉岩型金红石资源中可供综合利用的两种重要矿物组分。目前苏北地区众多的选矿企业针对此类型资源的开发,仅选铁铝石榴石,导致佥红石在废弃的尾矿中高度畜集。金红石在尾矿中的含量,一般在3．16％～7．59％之间,最高的接近8％,平均5．24％。尾矿实质上已成为品位极高的人工金红石砂矿。综合利用,不但可大幅度提高企业的经济效益,更重要的是可避免国家宝贵资源的浪费。  相似文献   

Zr-in-rutile thermometry of eclogites from the Karakaya Complex in NW Turkey: Implications for rutile growth during subduction zone metamorphism     

《Chemie der Erde / Geochemistry》2017,77(1):95-104

Eclogites occur as a tectonic slice within a metabasite-phyllite-marble unit of the Karakaya Complex in northwest Turkey. The high-pressure mineral assemblage in eclogite is mainly composed of garnet + omphacite + glaucophane + epidote + quartz. Trace element characteristics of rutile and Zr-in-rutile temperatures were determined for eclogites from the Karakaya Complex. Core-rim analyses of rutile grains yield remarkable trace element zoning with lower contents of Zr, Nb and Ta in the core than in the rim. The variations in Zr, Nb and Ta can be ascribed to growth zoning rather than diffusion effects. The Nb/Ta and Zr/Hf ratios increase with a decrease in Ta and Hf contents, which could be ascribed to the effect of metamorphic dehydration in subduction zones on rutile Nb/Ta differentiation. The rutile grains from eclogites in the Karakaya Complex are dominated by subchondritic Nb/Ta and Zr/Hf ratios. It can be noted that subchondritic Nb/Ta may record rutile growth from local sinks of aqueous fluids from metamorphic dehydration.The Zr contents of all rutile grains range between 81 and 160 ppm with an average of 123 ppm. The Zr-in-rutile thermometry yields temperatures of 559–604 °C with an average temperature of 585 °C for eclogites from the Karakaya Complex. This average temperature suggests growth temperature of rutile before peak pressure during the subduction. However, some rutile grains have higher Zr contents in the outermost rims compared to the core. Zr-in-rutile temperatures of the rims are about 20 °C higher than those of the cores. This suggests that the outermost rims would have grown from a distinct fluid at higher temperatures than that of the cores. Moreover, Zr contents and calculated temperatures in both inclusion rutile and matrix rutile from eclogites are identical, which suggests that eclogites within the Karakaya Complex belong to the same tectonic slice and underwent similar metamorphic evolution.  相似文献   

上扬子盆地西缘晚白垩世物源变化及指示   总被引：1，自引：0，他引：1  

姜磊  刘树根  王自剑  李智武  赖东  何宇  罗强  周政  邓宾 《地质论评》2019,65(2):477-490

对上扬子盆地西缘的上白垩统—古近系剖面开展沉积构造研究、传统重矿物分析、金红石微量元素地球化学研究。研究发现:①晚白垩世晚期,柳嘉剖面出现中酸性岩浆岩指数(ATi)升高和中低级变质岩指数(GZi)升高,宜就剖面出现中酸性岩浆岩指数(ATi)升高;柳嘉剖面富含石榴子石是与宜就剖面最大的不同。②柳嘉剖面和宜就剖面金红石母岩类型均主要为泥质变质岩,以角闪岩相/榴灰岩相为主。晚白垩世晚期,柳嘉剖面麻粒岩相达到最大,为39%,宜就剖面麻粒岩相出现最小值,达到13%,上扬子盆地西缘的麻粒岩相变化趋势的差异是物源差异的一种表现。③上扬子盆地西缘的晚白垩世物源变化揭示出松潘—甘孜褶皱带和龙门山构造带在晚白垩世晚期发生大规模快速隆升剥蚀事件。  相似文献   

我国主要金红石矿床金红石自然颗粒产状及粒度特征   总被引：4，自引：3，他引：1  

徐少康 《化工矿产地质》2001,23(2):101-103,108

我国已知主要金红石矿床有江苏东海榴辉岩型、湖北大阜山榴闪岩型、豫陕交界处八庙—青山角闪片岩型、陕西凤凰尖千枚岩型及山西碾子沟直闪 (片 )岩型 5个 ,前 4者为变质成因 ,后者为变质蚀变成因。变质型矿床 ,金红石自然颗粒主要为单晶、粒度较细、分布均匀 ,随着变质温压降低、粒度有明显变小趋势 ;变质蚀变型矿床 ,金红石自然颗粒主要为集合体、粒度粗、局部富集。其成因前者为变质过程是没有水参与的“干变”及变质温压的改变 ;后者蚀变过程是有水参与的“湿变” ,并且其环境为金红石提供了充分的生长空间。  相似文献